AI Summary & Key Takeaways
AI InsightThe activation energies of dimethoate, diazinon, chlorpyrifos and methidathion were calculated as 42.02, 42.18, 42.01 and 41.08 J/mol, respectively.
📌 3 Key Takeaways
Abstract
In this study, drying kinetics of chlorpyrifos, diazinon, dimethoate and methidathion pesticides on grape samples were determined. Grapes were dried under two conditions: by sunlight (for 21 days) and in a ventilated oven at different temperatures (at 50 °C for 72 hrs, at 60 °C for 60 hrs, at 70 °C for 48 hrs, at 80°C for 36 hrs). During sun drying, half-lives of chlorpyrifos, diazinon and methidathion were 5.64, 6.42 and 5.25 days, respectively. The data for dimethoate did not fit 0th,, 1st and 2nd order kinetics. During oven-drying, the pesticides followed the first order kinetic model. When the temperature increased, degradation of pesticides raised. The activation energies of dimethoate, diazinon, chlorpyrifos and methidathion were calculated as 42.02, 42.18, 42.01 and 41.08 J/mol, respectively.
Özet
Bu çalışmada üzümlerde bulunan chlorpyrifos, diazinon, dimethoate ve methidathion pestisitlerinin kurutma kinetikleri belirlenmiştir. Güneşte ve farklı sıcaklılarda (50°C’de 72 saat, 60°C’de 60 saat, 70°C’de 48 saat, 80°C’de 36 saat süre ile) hava akımlı etüvde kurutma işlemi olmak üzere iki farklı kurutma işlemi uygulanmıştır. Güneşte kurutma işleminde chlorpyrifos, diazinon ve methidathion pestisitlerinin yarılanma ömürleri sırasıyla 5.64, 6.42 ve 5.25 gün olarak bulunmuştur. Dimethoate verileri 0., 1. ve 2. derece kinetik uyumu göstermemiştir. Sıcaklık yükseldikçe pestisitlerin parçalanması artmıştır. Dimethoate, diazinon, chlorpyrifos ve methidathionun aktivasyon enerjileri sırasıyla 42.02, 42.18, 42.01 ve 41.08 J/mol olarak hesaplanmıştır.