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Journals / Turkish Journal of Chemistry / 2005 / Cilt: 29 - Sayı: 4

Synthesis of Novel Proponohydrazides and Their Hydrolysis Reactions

Mustafa SAÇMACI
Emin Saripinar And Yunus AKÇAMUR
Emin SARIPINAR
Yunus AKÇAMUR
Pages
401–407
Publication Date
2005-04-01
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The structures of these new synthesized compounds were determined by 13C NMR, 1H NMR and IR spectroscopic data and elemental analysis.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:4-(4-Methoxybenzoyl)-5-(4-methoxyphenyl)-2,3-furandione 1 reacted with N-aryl substituted phenylhydrazones 3a-h via the p,p'-dimethoxydibenzoylketene intermediate 2 giving the proponohydrazide derivatives 5a-h.
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Key Findings & Data:In addition, compounds 5a-h were converted into corresponding pyrazolone derivatives 7i,j by the reactions of hydrolysis in acidic solution.
💡
Conclusion & Impact:The structures of these new synthesized compounds were determined by 13C NMR, 1H NMR and IR spectroscopic data and elemental analysis.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Furan-2 · 3-dione · Proponohydrazide

Abstract

4-(4-Methoxybenzoyl)-5-(4-methoxyphenyl)-2,3-furandione 1 reacted with N-aryl substituted phenylhydrazones 3a-h via the p,p'-dimethoxydibenzoylketene intermediate 2 giving the proponohydrazide derivatives 5a-h. In addition, compounds 5a-h were converted into corresponding pyrazolone derivatives 7i,j by the reactions of hydrolysis in acidic solution. The structures of these new synthesized compounds were determined by 13C NMR, 1H NMR and IR spectroscopic data and elemental analysis.

Özet

4-(4-Methoxybenzoyl)-5-(4-methoxyphenyl)-2,3-furandione 1 reacted with N-aryl substituted phenylhydrazones 3a-h via the p,p'-dimethoxydibenzoylketene intermediate 2 giving the proponohydrazide derivatives 5a-h. In addition, compounds 5a-h were converted into corresponding pyrazolone derivatives 7i,j by the reactions of hydrolysis in acidic solution. The structures of these new synthesized compounds were determined by 13C NMR, 1H NMR and IR spectroscopic data and elemental analysis.

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Cite This Article

SAÇMACI, M., AKÇAMUR, E. S. A. Y., SARIPINAR, E., AKÇAMUR, Y. (2005). Synthesis of Novel Proponohydrazides and Their Hydrolysis Reactions. Turkish Journal of Chemistry, Cilt: 29 - Sayı: 4, 401–407. https://ajindex.com/articles/382191

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