Journals / Turkish Journal of Physics / 2012 / Cilt: 36 - Sayı: 3

Gamma irradiation effect on the optical properties and refractive index dispersion of dye doped polystyrene films

Pages
377–384
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The most significant result of the present study is to determine the optical constants and optical band gap of the film.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this work, we have studied the effect of the gamma irradiation on the optical properties and optical constants of Polystyrene doped by methylene blue (mb) with thickness in the range 0.11 + 5 mm.
📊
Key Findings & Data:The samples have been investigated via transmittance and reflectance spectra, and characterized in the wavelength range 300-900 nm.
💡
Conclusion & Impact:The most significant result of the present study is to determine the optical constants and optical band gap of the film.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Polymer · polystyrene · gamma irradiation

Abstract

In this work, we have studied the effect of the gamma irradiation on the optical properties and optical constants of Polystyrene doped by methylene blue (mb) with thickness in the range 0.11 + 5 mm. The samples have been investigated via transmittance and reflectance spectra, and characterized in the wavelength range 300-900 nm. The optical band gap Eg was determined while the optical absorption spectra showed that the absorption mechanism is an indirect allowed transition, which found that optical energy gap Eg decreases after irradiation. The optical constants (refractive index, extinction coefficient, and real and imaginary parts of the dielectric constant) showed clear changes with irradiation. The oscillator energy Eo, dispersion energy Ed and other parameters have been determined by the Wemple-DiDomenico method. The most significant result of the present study is to determine the optical constants and optical band gap of the film.

Özet

In this work, we have studied the effect of the gamma irradiation on the optical properties and optical constants of Polystyrene doped by methylene blue (mb) with thickness in the range 0.11 + 5 mm. The samples have been investigated via transmittance and reflectance spectra, and characterized in the wavelength range 300-900 nm. The optical band gap Eg was determined while the optical absorption spectra showed that the absorption mechanism is an indirect allowed transition, which found that optical energy gap Eg decreases after irradiation. The optical constants (refractive index, extinction coefficient, and real and imaginary parts of the dielectric constant) showed clear changes with irradiation. The oscillator energy Eo, dispersion energy Ed and other parameters have been determined by the Wemple-DiDomenico method. The most significant result of the present study is to determine the optical constants and optical band gap of the film.

🔖

Cite This Article

ALWAN, J. T. (2012). Gamma irradiation effect on the optical properties and refractive index dispersion of dye doped polystyrene films. Turkish Journal of Physics, Cilt: 36 - Sayı: 3, 377–384. https://ajindex.com/articles/378087

References (11)

  1. L. H. Sperling, Introduction to physical polymer science, (4th ed. John Wiley & Sons, Inc., New Jersey. 2006)
  2. T. Sharma, S. Aggarwal, S. Kumar, V. K. Mittal, P. C. Kalsi and V. K. Manchanda, J. Mater. Sci., 42, (2007),
  3. A. A. Saeed, Ph.D. Thesis, Physics Department, College of Science, Baghdad University, Baghdad, Iraq, 2000.
  4. Z.A. Al-Ramadhann, M.Sc Thesis, Physics Department, College of Science, Al- Al-Mustansiriyah University, Baghdad, Iraq, 1996
  5. M. Maebayashi, T. Matsuoka, S. Koda, R. Hashitani, T. Nishio and S. Kimura, Elsevier, Polymer, 45, (2004), 7563. O. BaoLi, L. DuXin, Sci. China. Ser. B-Chem., 50, (2007), 385. T. J. Alwan, Malaysian Polymer Journal (MPJ), 5, (2010), 204. Susilawati and A. Doyan, American Journal of Applied Sciences, 6, (2009), 2071.
  6. J. P. Harmon, E. Biagtan, G. T. Schueneman, and E. P. Goldberg, American Chemical Society, 620, (1996), 302. T. Kojima, N. Morishita, H. Itoh, S. Biramontri, Applied Radiation and Isotopes, 47, (1996), 457. J. Tauc, Amorphous and Liquid Semiconductors, (Plenum Press, New York. 1979).
  7. N. Mott and E. Davis, Electronic Process in Non- Crystalline Materials, (2ndEdition,
  8. University Press, Oxford. ). S. M. Sze., Semiconductor Devices physics and Technology, (John Wiley & Sons, Inc., 3ed, Canada. 2007).
  9. A. A. Abdel-Fattah, H. M. Abdel-Hamid and R. M. Radwan, Nuclear Instru. Method phys. Res., B196, (2002),
  10. A. S. Zleetni and S. K. Arshak, Thick Films Sensor, 2, (2002), 174. E. Saion, S. Susilawati, A. Doyan, S. Z. Abidin, Z. Azmi, A. Zulkfli, A. R. MohdZaki, K. Z. H. Dahlan and T. Karni, Journal of Applied Sciences, 5, (2005), 1825. J. Pankov, Optical Processes in Semiconductors, (Prentice-Hall, New Jersey. 1971).
  11. M. Didomenico, S. H. Wemple, Journal of Applied Physics, 40, (1969), 720. A. K. Wolaton, T. S. Moss, Proceedings of the Royal Society, 81, (1963), 5091. P. A. Lee, G. Said, R. Davis, T. H. Lim, Journal of the Physics and Chemistry of Solids, 30, (1969), 2719. Y. Fahrettin, E. Hilmi, Optica Applicata, XXXV, (2005), 69. M. A. Omar, Elementary Solid State Physics, (Addison-Wesley. 1993).