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Journals / Celal Bayar Üniversitesi Fen Bilimleri Dergisi / 2006 / Cilt: 2 - Sayı: 2

(N-(2-Hidroksi-1-Naftaliden) Histidin) Schiff Bazinin Sentezi ve Kristal Yapı Analizi

İffet ŞAKIYAN
Yusuf ÖZCAN
Semra İDE
Pages
99–106
Publication Date
2006-06-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Molekül içi hidrojen ba [ N-Hketo-amin formundaki yük da l m na ba l olarak kuvvetli naftaliden grubundan azot atomuna proton transferinin oldu unu göstermektedir

📌 3 Key Takeaways

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Objective & Hypothesis:[N-(2-hidroksi-1-naftaliden)histidin] Schiff baz sentezlenerek yap s , IR, UV, 1H NMR spektroskopi metodlar ve Xortorombik ve P212121 uzay grubuna sahiptir.
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Key Findings & Data:Kristalografik parametreleri ise a=6.133(5), b=7.168(5), c=33.639(5)Å , V=1478.8(2) Å3 birim hücre bilgilerini içerir.
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Conclusion & Impact:Molekül içi hidrojen ba [ N-Hketo-amin formundaki yük da l m na ba l olarak kuvvetli naftaliden grubundan azot atomuna proton transferinin oldu unu göstermektedir
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Histidin Schiff baz · Hidroksinaftaldehit · X-I nlar kristalografi

Özet

[N-(2-hidroksi-1-naftaliden)histidin] Schiff baz sentezlenerek yap s , IR, UV, 1H NMR spektroskopi metodlar ve Xortorombik ve P212121 uzay grubuna sahiptir. Kristalografik parametreleri ise a=6.133(5), b=7.168(5), c=33.639(5)Å , V=1478.8(2) Å3 birim hücre bilgilerini içerir. Ayd nlat lan yap n n do rulu unun bir ölçüsü olan R faktörleri ise R=0.0394 , wR=0.0784 olarak belirlenmi tir. Bu tip Schiff bazlar sahip olduklar tautomerik formlara ba l olarak fotokromik veya termokromik karakter gösterirler. Daha önceki çal mam zda inceledi imiz treonin Schiff baz nda gözlenen enol-imin tautomerli inin aksine histidin Schiff baz n n kat fazda daha çok keto-amin tautomerli ini tercih etti i görülmü tür. Molekül içi hidrojen ba [ N-Hketo-amin formundaki yük da l m na ba l olarak kuvvetli naftaliden grubundan azot atomuna proton transferinin oldu unu göstermektedir

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Cite This Article

ŞAKIYAN, İ., ÖZCAN, Y., İDE, S. (2006). (N-(2-Hidroksi-1-Naftaliden) Histidin) Schiff Bazinin Sentezi ve Kristal Yapı Analizi. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, Cilt: 2 - Sayı: 2, 99–106. https://ajindex.com/articles/35358

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