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Journals / Atmospheric Pollution Research / 2018 / Cilt: 9 - Sayı: 1

Chemical analysis of particulate products of aged 1,3,5- trimethylbenzene secondary organic aerosol in the presence of ammonia

Mingqiang HUANG
Jun XUE
Shunyou CAİ
Xingqiang LİU
Changjin HU
Xuejun GU
Weixiong ZHAO
Li FANG
Weijun ZHANG
Pages
146–155
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Experimental results indicated that NH3 has significantpromotion effect on 135-TMB SOA formation.

📌 3 Key Takeaways

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Objective & Hypothesis:Ammonia (NH3) gas-aging of secondary organic aerosol (SOA) results in the formation of organonitrogencompound is an important class of brown carbon.
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Key Findings & Data:The particulate products of aged 1,3,5-trimethylbenzene (135-TMB) SOA in the presence of NH3 were measured by UVeVis spectrophotometer,attenuated total reflectance-Fourier transform infrared (ATR-FTIR), and aerosol laser time-of-flightmass spectrometer (ALTOFMS) in present study.
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Conclusion & Impact:Experimental results indicated that NH3 has significantpromotion effect on 135-TMB SOA formation.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Özet

Ammonia (NH3) gas-aging of secondary organic aerosol (SOA) results in the formation of organonitrogencompound is an important class of brown carbon. The particulate products of aged 1,3,5-trimethylbenzene (135-TMB) SOA in the presence of NH3 were measured by UVeVis spectrophotometer,attenuated total reflectance-Fourier transform infrared (ATR-FTIR), and aerosol laser time-of-flightmass spectrometer (ALTOFMS) in present study. Experimental results indicated that NH3 has significantpromotion effect on 135-TMB SOA formation. Organic ammonium salts, such as ammonium methylglyoxylate, ammonium 3,5-dimethylbenzoate, which are formed from NH3 reactions with gaseousorganic acids were detected as the principal particulate products of NH3-aged 135-TMB SOA. 4-methylimidazole-2-acetaldehyde,4-methyl- 1H-imidazole and other imidazole products via the heterogeneousreactions between NH3 and dialdehydes of 135-TMB SOA were newly measured. The formation ofimidazole products suggests that some ambient particles contained organonitrogen compounds may become from this mechanism. The results of this study may provide valuable information for discussingSOA aging mechanisms and new route for NH3 deposition.

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Cite This Article

HUANG, M., XUE, J., CAİ, S., LİU, X., HU, C., GU, X., ZHAO, W., FANG, L., ZHANG, W. (2018). Chemical analysis of particulate products of aged 1,3,5- trimethylbenzene secondary organic aerosol in the presence of ammonia. Atmospheric Pollution Research, Cilt: 9 - Sayı: 1, 146–155. https://ajindex.com/articles/351472

References (1)

  1. Andreae, M.O., 2009. A new look at aging aerosols. Science 326, 1493e1494. Andreae, M.O., Ramanathan, V., 2013. Climate's dark forcings. Science 340, 280e281. Atkinson, R., Carter, W.P.L., Winer, A.M., 1981. An experimental protocol for the determination of OH radical rate constants with organics using methyl nitrite photolysis as an OH radical source. J. Air Pollut. Control Assoc. 31, 1090e1092. Atkinson, R., Baulch, D.L., Cox, R.A., Crowley, J.N., Hampson, R.F., Hynes, R.G., Jenkin, M.E., Rossi, M.J., Troe, J., 2004. Evaluated kinetic and photochemical data for atmospheric chemistry: volume I e gas phase reactions of Ox, HOx, NOx and SOx species. Atmos. Chem. Phys. 4, 1461e1738. Babar, Z.B., Park, J.H., Lim, H.J., 2017. Influence of NH3 on secondary organic aerosols from the ozonolysis and photooxidation of a-pinene in a flow reactor. Atmos. Environ. 164, 71e84. Bones, D.L., Henricksen, D.K., Mang, S.A., Gonsior, M., Bateman, A.P., Nguyen, T.B., Cooper, W.J., Nizkorodov, S.A., 2010. Appearance of strong absorbers and fluorophores in limonene-O3 secondary organic aerosol due to NH4 þ-mediated chemical aging over long time scales. J. Geophys. Res. Atmos. 115 (D05203), 1e14. Carlton, A.G., Turpin, B.J., Altieri, K.E., Seitzinger, S., Reff, A., Lim, H.J., Ervens, B., 2007. Atmospheric oxalic acid and SOA production from glyoxal:Results of aqueous photooxidation experiments. Atmos. Environ. 41, 7588e7602. Chang, J.L., Thompson, J.E., 2010. Characterization of colored products formed during irradiation of aqueous solutions containing H2O2 and phenolic compounds. Atmos. Environ. 44, 541e551. Fisseha, R., Dommen, J., Sax, M., Paulsen, D., Kalberer, M., Maurer, R., Ho1€ fler, F., Weingartner, E., Baltensperger, U., 2004. Identification of organic acids in secondary organic aerosol and the corresponding gas phase from chamber experiments. Anal. Chem. 76, 6535e6540. Flores, J.M., Washenfelder, R.A., Adler, G., Lee, H.J., Segev, L., Laskin, J., Laskin, A., Nizkorodov, S.A., Brown, S.S., Rudich, Y., 2014. Complex refractive indices in the near- ultraviolet spectral region of biogenic secondary organic aerosol aged with ammonia. Phys. Chem. Chem. Phys. 16, 10629e10642. Gentner, D.R., Jathar, S.H., Gordon, T.D., Bahreini, R., Day, D.A., Haddad, I.E., Hayes, P.L., Pieber, S.M., Platt, S.M., Gouw, J., Goldstein, A.H., Harley, R.A., Jimenez, J.L., Prev ot, A.S.H., Robinson, A.L., 2017. Review of urban secondary ^ organic aerosol formation from gasoline and diesel motor ve