SavedAdd your journal

Journals / Politeknik Dergisi / 2021 / Cilt: 24 - Sayı: 3

Synthesis, Characterization and Thermal Properties of Oxo Methacrylate-Containing Polymer/Clay Nanocomposites

NEVİN ÇANKAYA
Pages
1017–1022
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

It is thought that this newly synthesized synthetic polymer/clay nanocomposites with natural clay content will serve different areas due to its environmentally friendly-biodegradable properties.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, synthesis and characterization of polymer/clay based nanocomposites was performed using 2-(4-methoxyphenyl amino)-2-oxoethyl methacrylate (MPAEMA) and organoclay.
📊
Key Findings & Data:The amount of organoclay in nanocomposites synthesized by in situ polymerization method was determined as 3% and 5%.
💡
Conclusion & Impact:It is thought that this newly synthesized synthetic polymer/clay nanocomposites with natural clay content will serve different areas due to its environmentally friendly-biodegradable properties.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:polymer/clay nanocomposite · organoclay · thermal stability

Abstract

In this study, synthesis and characterization of polymer/clay based nanocomposites was performed using 2-(4-methoxyphenyl amino)-2-oxoethyl methacrylate (MPAEMA) and organoclay. The amount of organoclay in nanocomposites synthesized by in situ polymerization method was determined as 3% and 5%. FTIR, XRD, and SEM were used as characterization techniques. It was determined from XRD and SEM results that the morphology of nanocomposites exfoliated. Then, the thermal properties of nanocomposites were investigated using the TGA/DTA/DTG simultaneous system. In thermal analysis, it was seen that the thermal stability increased when the clay amount increased. It is thought that this newly synthesized synthetic polymer/clay nanocomposites with natural clay content will serve different areas due to its environmentally friendly-biodegradable properties.

Özet

In this study, synthesis and characterization of polymer/clay based nanocomposites was performed using 2-(4-methoxyphenyl amino)-2-oxoethyl methacrylate (MPAEMA) and organoclay. The amount of organoclay in nanocomposites synthesized by in situ polymerization method was determined as 3% and 5%. FTIR, XRD, and SEM were used as characterization techniques. It was determined from XRD and SEM results that the morphology of nanocomposites exfoliated. Then, the thermal properties of nanocomposites were investigated using the TGA/DTA/DTG simultaneous system. In thermal analysis, it was seen that the thermal stability increased when the clay amount increased. It is thought that this newly synthesized synthetic polymer/clay nanocomposites with natural clay content will serve different areas due to its environmentally friendly-biodegradable properties.

🔖

Cite This Article

ÇANKAYA, N. (2021). Synthesis, Characterization and Thermal Properties of Oxo Methacrylate-Containing Polymer/Clay Nanocomposites. Politeknik Dergisi, Cilt: 24 - Sayı: 3, 1017–1022. https://ajindex.com/articles/340518

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (13)

  1. Kurt A., Çağlayan Z. and Bektaş H.S., “Preparation of poly(methyl methacrylate)/clay nanocomposites and investigation of some physical properties”, Sigma Journal of Engineering and Natural Sciences, 32: 71-80, (2014)
  2. Utracki L.A., Sepehr M. and Boccaleri E., “Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs)”, Polymers for Advanced Technologies, 18: 1-37, (2007)
  3. Krishna S.V. and Pugazhenthi G., “Properties and thermal degradation kinetics of polystyrene/organoclay nanocomposites synthesized by solvent blending method: Effect of processing conditions and organoclay loading”, Journal of Applied Polymer Science, 120: 1322–1336, (2011)
  4. Wang W.S., Liang C.K., Chen Y.C., et al., “Transparent and flame retardant PMMA/clay nanocomposites prepared with dual modified organoclay”, Polymers for Advanced Technologies, 23: 625-631, (2012)
  5. Hu Y.H., Chen C.Y. and Wang C.C., “Viscoelastic properties and thermal degradation kinetics of silica/PMMA nanocomposites”, Polymer Degradation and Stability, 84: 545-553, (2004)
  6. Yalçınkaya S.E., Yıldız N., Saçak M. and Çalımlı A., “Preparation of polystyrene/montmorillonite nanocomposites: Optimization by response surface methodology (RSM)”, Turk J. Chem. 34: 581-592, (2010)
  7. Wang Y. and Chen W.C., “Dielectric probing of relaxation behaviors in PMMA/organoclay nanocomposites: Effect of organic modification”, Composite Interfaces, 17: 803-829, (2010)
  8. Flieger M., Kantorova M., Prell A., Rezanka T. and Votruba J. “Biodegradable plastics from renewable sources”, Folia Microbiol. 48(1): 27-44, (2003)
  9. Dimitry O.I.H., Mansour N. A. and Saad A.L.G., “Influence of organic modifier loading on particle dispersion of biodegradable polycaprolactone/montmorillonite nanocomposites”, World Academy of Science, Engineering and Technology: International Journal of Chemical, Molecular, Nuclear, Materials and Metallurgical Engineering 10(2): 283-297, (2016)
  10. Çankaya N. and Şahin R., “Chitosan/clay bionanocomposites: Structural, antibacterial, thermal and swelling properties”, Cellulose Chemistry and Technology, 53(5-6): 537-549, 2019
  11. Liu P., “Polymer modified clay minerals: A review”, Applied Clay Science, 38: 64–76, (2007)
  12. Ray S.S. and Okamoto M., “Polymer/layered silicate nanocomposites: A review from preparation to processing”, Progress in Polymer Science, 28: 1539-1641, (2003)
  13. Kurt A. and Yilmaz P., “Thermal decomposition kinetics of benzofuran derived polymer/organos