Journals / Uludağ Üniversitesi Mühendislik Fakültesi Dergisi / 2021 / Cilt: 26 - Sayı: 2

Investigation of the Effects of Linear Alkyl Benzene Sulphonic Acid Modification on the Temperature Susceptibility and Viscoelastic Behaviour of Bitumen

LİNEER ALKİL BENZEN SULFONİK ASİT MODİFİKASYONUNUN BİTÜMÜN SICAKLIK HASSASİYETİ VE VİSKOELASTİK DAVRANIŞINA ETKİLERİNİN İNCELENMESİ

Pages
493–508
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

According to the results, it is seen that the use of LABSA significantly reduces the temperature susceptibility and improves the bitumen's elastic behaviour.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:It is known that, alkyl benzene derived amphiphiles are used in the asphalt industry due to their retarding properties of asphaltene precipitation, but studies on this subject are limited.
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Key Findings & Data:In addition, the performance of the samples after short-term and long-term aging was also examined, so that the effects of LABSA content against aging were studied.
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Conclusion & Impact:According to the results, it is seen that the use of LABSA significantly reduces the temperature susceptibility and improves the bitumen's elastic behaviour.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Lineer alkil benzen sülfonik asit · Bitüm modifikasyonu · Sıcaklık hassasiyeti

Abstract

It is known that, alkyl benzene derived amphiphiles are used in the asphalt industry due to their retarding properties of asphaltene precipitation, but studies on this subject are limited. Within the scope of this study, the utilization of linear alkyl benzene sulfonic acid (LABSA) surfactant with bitumen was evaluated by penetration and softening point tests together with dynamic shear rheometer investigations. Considering the penetration index and complex shear modulus values of the samples produced with different LABSA contents, temperature sensitivity and viscoelastic behaviours were investigated. In addition, the performance of the samples after short-term and long-term aging was also examined, so that the effects of LABSA content against aging were studied. According to the results, it is seen that the use of LABSA significantly reduces the temperature susceptibility and improves the bitumen's elastic behaviour. Additionally, LABSA modification increased the aging resistance of the bitumen. Utilization of LABSA at the rate of 2% of bitumen weight provided the best results in terms of temperature sensitivity and elastic performance among the samples.

Özet

Alkil benzen’den türetilmiş amfifillerin, asfalten çökelmesini geciktirici özellikleri sebebiyle, asfalt endüstrisinde kullanıldığı bilinmektedir, ancak bu konuda yapılmış çalışmalar kısıtlıdır. Çalışma kapsamında, deterjan endüstrisinde kullanılan lineer alkil benzen sülfonik asit (LABSA) sürfaktanının bitüm ile kullanımı, penetrasyon ve yumuşama noktası deneyi ile dinamik kayma reometresi kullanılarak incelenmiştir. Farklı LABSA içerikleri ile üretilmiş numunelerin penetrasyon indeksi ve kompleks kayma modül değerleri göz önünde bulundurularak sıcaklık hassasiyeti ve viskoelastik davranışları araştırılmıştır. Ayrıca, numunelerin kısa dönem ve uzun dönem yaşlanma sonrasındaki performansları da incelenerek LABSA içeriğinin yaşlanmaya karşı etkileri irdelenmiştir. Elde edilen sonuçlara göre, LABSA kullanımının sıcaklık hassasiyetini belirgin özellikte azalttığı ve bitüme elastik davranış kazandırdığı görülmektedir. Bitüm ağırlığının %2’si oranında LABSA kullanımı, sıcaklık hassasiyeti ve elastik performans açısından en uygun sonuçları vermektedir. Bununla birlikte, LABSA modifikasyonunun bitümün yaşlanmaya karşı direncini arttırmaktadır.

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Cite This Article

ÖZDEMİR, D. K. (2021). Investigation of the Effects of Linear Alkyl Benzene Sulphonic Acid Modification on the Temperature Susceptibility and Viscoelastic Behaviour of Bitumen. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Cilt: 26 - Sayı: 2, 493–508. https://ajindex.com/articles/329709

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References (10)

  1. Ahmadi, M. ve Chen, Z. (2021) Comprehensive molecular scale modeling of anionic surfactant-asphaltene interactions. Fuel, 288, 119729. https://doi.org/10.1016/j.fuel.2020.119729
  2. Alhreez, M. ve Wen, D. (2018) Controlled releases of asphaltene inhibitors by nanoemulsions, Fuel, 234, 538-548. https://doi.org/10.1016/j.fuel.2018.06.079
  3. Barth, E.J. (1962)
  4. Bitumen Science and Technology, Gordon and Breach, New York. Bonemazzi, F. ve Giavarini, C. (1999). Shifting the bitumen structure from sol to gel, Journal of Petroleum Science and Engineering, 22(1-3), 17-24. https://doi.org/10.1016/S0920-4105(98)00052-7
  5. Chang, C. L. ve Fogler, H. S. (1994) Stabilization of asphaltenes in aliphatic solvents using alkylbenzene-derived amphiphiles. 2. Study of the asphaltene-amphiphile interactions and structures using Fourier transform infrared spectroscopy and small-angle X-ray scattering techniques, Langmuir, 10(6), 1758-1766.
  6. Dolganova, I. O. Dolganov, I. M. Bunaev, A. A. ve Pasyukova, M. A. (2019) Nature of highly viscous component in the alkylbenzene sulfonic acid technology and its influence on the process efficiency, Petroleum & Coal, 61(1), 25-31. García, A. Aguiar-Moya, J. P. Salazar-Delgado, J. Baldi-Sevilla, A. ve Loría-Salazar, L. G. (2019) Methodology for estimating the modulus of elasticity of bitumen under different aging conditions by AFM, Road Materials and Pavement Design, 20(1), 332-346. https://doi.org/10.1080/14680629.2019.1588152
  7. Goual, L. ve Firoozabadi, A. (2004) Effect of resins and DBSA on asphaltene precipitation from petroleum fluids. AIChE journal, 50(2), 470-479. https://doi.org/10.1002/aic.10041
  8. Goual, L. ve Sedghi, M. (2015) Role of ion-pair interactions on asphaltene stabilization by alkylbenzenesulfonic acids. Journal of colloid and interface science, 440, 23-31. https://doi.org/10.1016/j.jcis.2014.10.043
  9. Hashmi, S. M. Zhong, K. X. ve Firoozabadi, A. (2012) Acid–base chemistry enables reversible colloid-to-solution transition of asphaltenes in non-polar systems, Soft Matter, 8(33), 8778-8785. doi: 10.1039/C2SM26003D Hosseini-Moghadam, S. M. A. Zahedi-Nejad, A. Bahrami, M., Torkaman, M. ve Ghayyem, M. A. (2021) Experimental and Modeling Investigations of Temperature Effect on Chemical Inhibitors of Asphaltene Aggregation. Journal of Petroleum Science and Engineering, 108858. https://doi.org/10.1016/j.petrol.2021.108858
  10. Hu, Y. F. ve Guo, T. M. (2005) Effect of the structures of ionic liquids and alkylbenzene-derived amphiphiles on the inhibition