SavedAdd your journal

Journals / Bor Dergisi / 2017 / Cilt: 2 - Sayı: 2

Synthesis and characterization of Multi-Functional Material MoBP3O12

Gülşah ÇELİK GÜL
Figen KURTULUŞ
Halil GÜLER
Pages
71–74
Publication Date
2017-09-25
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The indexed powder X-ray diffraction (XRD) data with POWD program, fourier transform infrared spectroscopy (FTIR) spectrum and thermal analysis of MoBP3O12 are also given in the paper.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:New metal borophosphate compound MoBP3O12, as a potential candidate of nonlinear optical material, was obtained by hydrothermal method.
📊
Key Findings & Data:The title compound was synthesized from the mixture of MoO3, B2O3, and (NH4)2HPO4 with the molar ratio 1:0.5:3, by heating at 200 °C for 3 days.
💡
Conclusion & Impact:The indexed powder X-ray diffraction (XRD) data with POWD program, fourier transform infrared spectroscopy (FTIR) spectrum and thermal analysis of MoBP3O12 are also given in the paper.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Borophosphate compounds · Hydrothermal synthesis · X-ray diffraction

Abstract

New metal borophosphate compound MoBP3O12, as a potential candidate of nonlinear optical material, was obtained by hydrothermal method. The title compound was synthesized from the mixture of MoO3, B2O3, and (NH4)2HPO4 with the molar ratio 1:0.5:3, by heating at 200 °C for 3 days. The powder X-ray diffraction data was indexed in tetragonal system with the refined unit cell parameters, a = b = 5.302 (8), c = 21.538 (4) Å and Z = 1. Stoichiometric chemical analysis of molybdenum was done by inductively coupled plasma atomic emission spectroscopy (ICP-AES) and boron content was analysed by spectrophotometric azomethine H method. The indexed powder X-ray diffraction (XRD) data with POWD program, fourier transform infrared spectroscopy (FTIR) spectrum and thermal analysis of MoBP3O12 are also given in the paper.

🔖

Cite This Article

GÜL, G. Ç., KURTULUŞ, F., GÜLER, H. (2017). Synthesis and characterization of Multi-Functional Material MoBP3O12. Bor Dergisi, Cilt: 2 - Sayı: 2, 71–74. https://ajindex.com/articles/252089

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (16)

  1. Becker P., Borate materials in nonlinear optics, Adv. Mater., 10, 979‒992, 1998
  2. Chen C., Lin Z., Wang Z., The development of new borate-based UV nonlinear optical crystals, Appl. Phys. B, 80, 1‒25, 2005
  3. Aka G., Brenier A., Self-frequency conversion in non-linear laser crystals, Optic Mater., 22, 89‒94, 2003
  4. Chen C., Wu Y., Li R., Growth of large Mo18O52 single crystals by a vapor phase method, J. Crys. Growth, 99, 708‒715, 1990
  5. Fan T. Y., Huang C. E., Hu B. Q., Eckhardt R. C., Fan Y. X., Bayer R. L., Feigelson R. S., Second harmonic generation and accurate index of refraction measurements in flux-grown KTiOPO4, Appl. Optics, 26, 2391‒2394, 1987
  6. Harrison W. T. A., Gier T. E., Stucky G. D., The synthesis and Ab initio structure determination of Zn4O(BO3)2, a microporous, zinc borate constructed of “sused” subunits, of three- and five-membered rings, Ange. Chem. Inter. Ed., 32, 724‒761, 1993
  7. Wells A. F., Structural Inorganic Chemistry, 4th ed. Oxford University Press, Oxford, 1975
  8. Bell R. J., Carnevale A., A structural model for B2O3 glass, Philos. Mag. B, 43, 389‒413, 1981
  9. Rulmont A., Almou M., Vibrational spectra of metaborates with infinite chain structure: LiBO2, CaB2O4, SrB2O4, Spectrochim. Acta Part A, 45, 603‒610, 1989
  10. Kniep R., Engelhardt H., Hauf C., A first approach to borophosphate structural chemistry, Chem. Mater., 10, 2930‒2934, 1998
  11. Levesseur A., Olazcuaga R., Kbala M., Zahir M., Hagenmuller P., Couzi M., Etudes electrique et Raman des verres des systemes B2O3·M2O·M3PO4 (M=Li, Na), Solid State Ion., 2, 205‒213, 1981
  12. Shi Y., Liang J. K., Zhang H., Liu Q. L., Chen X. L., Yang J. L., Zhuang W. D. et al., Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5, J. Solid State Chem., 135, 43‒51, 1998
  13. Goetzman K., Karlheinz D., Dieter H. N., Ralfh G., Patent CA C09K015, 1996
  14. Bulur E., Goeksu H. Y., Wieser A., Figel M., Oezer A. M., Thermoluminescent properties of fluorescent materials used in commercial lamps, Rad. Pro. Dosi., 65, 373‒379, 1996
  15. Tanabe R., Sugimato N., Ho S., Manabe T., Patent CA Section 57 (Ceramics) CODEN: JKXXXAF, ICS: C03C008-08; C03C008-14, 95-274456, 23 Oct., 1995
  16. Kniep R., Gozel G., Eisenmann B., Rohr C., Asbrand M., Kızılyallı M., Borophosphate - Eine stiefmütterlich behandelte verbindungsklasse: Die kristallstrukturen von MII[BPO5] (MII=Ca, Sr) und Ba3[BP3O12], Ange. Chem. Inter. Ed., 33, 749‒750, 1994