Journals / Turkish Journal of Chemistry / 2006 / Cilt: 30 - Sayı: 3

Solvent-Free Preparation of Primary Carbamates

Pages
269–276
Publication Date
2006-03-01
DOI
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

Herein, we describe a simple and efficient method for the conversion of compounds containing a hydroxyl group to primary carbamates at room temperature with excellent yield and purity, and without any epimerization, in the absence of solvent.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Herein, we describe a simple and efficient method for the conversion of compounds containing a hydroxyl group to primary carbamates at room temperature with excellent yield and purity, and without any epimerization, in the absence of solvent.
📊
Key Findings & Data:Herein, we describe a simple and efficient method for the conversion of compounds containing a hydroxyl group to primary carbamates at room temperature with excellent yield and purity, and without any epimerization, in the absence of solvent.
💡
Conclusion & Impact:Herein, we describe a simple and efficient method for the conversion of compounds containing a hydroxyl group to primary carbamates at room temperature with excellent yield and purity, and without any epimerization, in the absence of solvent.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Solvent-free · N-unsubstituted carbamates · isocyanic acid

Abstract

Herein, we describe a simple and efficient method for the conversion of compounds containing a hydroxyl group to primary carbamates at room temperature with excellent yield and purity, and without any epimerization, in the absence of solvent.

Özet

Herein, we describe a simple and efficient method for the conversion of compounds containing a hydroxyl group to primary carbamates at room temperature with excellent yield and purity, and without any epimerization, in the absence of solvent.

🔖

Cite This Article

MODARRESI-ALAM, A. R. (2006). Solvent-Free Preparation of Primary Carbamates. Turkish Journal of Chemistry, Cilt: 30 - Sayı: 3, 269–276. https://ajindex.com/articles/217999

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References (19)

  1. A. Dibenedetto, M. Aresta, C. Fragale and M. Narracci, Green Chemistry 4, 439–443 (2002) and references therein. S.P. Gupte, A.B. Shivarkar and R.V. Chaudhari, J. Chem. Soc. Chem. Commun. 2620-2621 (2001).
  2. J. Mindl, O. Hrab´ık, V. Strba and J. Kav´alek, Collect. Czech. Chem. Commun. 65, 1262-1272 (2000). G. Motolcsy (ed.), M. Nadasy and V. Andriska, ”Pesticide Chemistry”, pp. 90, Academiai Kiado, Budapest, A. Thompson, Pesticide Outlook 13, 84-86 (2002).
  3. L.L. Martin, L. Davis, J.T. Klein, P. Nemoto, G.E. Olsen, G.M. Bores, F. Camacho, W.W. Petko, D.K. Rush, D. Selk, C.P. Smith, H.M. Vargas, J.T. Wilson, R.C. Effland and D.M. Fink, Bioorg. Med. Chem. Lett. 7, 162 (1997). D. Feldman and A. Barbalata, ”Synthetic Polymers, Technology, Properties, Applications”, pp. 273, Chapman and Hall, London, 1996. W.T. Greene and P.G.M. Wuts, ”Protective Groups in Organic Synthesis”, pp. 327 and 403, Wiley, New York, 2nd ed., 1991.
  4. Y. Ichikawa, M. Osada, I.I. Ohtani and M. Isobe, J. Chem. Soc. Perkin Trans. 1, 1449-1455 (1997).
  5. P. Kocovsky, Tetrahedron Lett. 27, 5521-5524 (1986).
  6. S. Raucher and D.S. Jones, Synth. Commun. 15, 1025 (1985).
  7. R. Graf, Ber. 96, 56-67 (1963).
  8. R. Fuks and M.A. Hartemink, Bull. Chim. Belg. 82, 23 (1973).
  9. B. Loev and M.F. Kormendy, J. Org. Chem. 28, 3421-3426 (1963).
  10. A.R. Modarresi-Alam, H. Keykha, F. Khamooshi and H.A. Dabbagh, Tetrahedron 60, 1525-1530 (2004).
  11. A.R. Modarresi-Alam and F. Khamooshi, Synth. Commun. 34, 129-135 (2004). K. Tanaka, ”Solvent-Free Organic Synthesis”, Wiley-VCH GmbH & Co. KgaA, Morlenbach, 2003.
  12. G. Nagendrappa, Resonance 7, 64-77 (2002).
  13. R.S. Varma, Green Chemistry 1, 43-55 (1999).
  14. R.S. Varma, Tetrahedron 58, 1235-1255 (2002).
  15. K. Tanaka and F. Toda, Chem. Rev. 100, 1025-1074 (2000).
  16. J.H. Clark and D.J. Macquarrie, Chem. Soc. Rev. 25, 303-310 (1996).
  17. J.D Moore, R.H. Herpel, J.R. Lichtsinn, D.L. Flynn and P.R. Hanson, Org. Lett. 5, 105-107 (2003) and references therein. T. Oshikawa and M. Yamashita, Bull. Chem. Soc. Jpn. 62, 3177-3181 (1989). R.C. Weast and D.R. Lide, ”Handbook of Chemistry and Physics”, 70thEd., CRC Press, Florida, 1989-, C-194. H.G. Ashburn, A.R. Collett and C.L. Lazzell, J. Am. Chem. Soc. 60, 2933 (1938).
  18. A. Lachowics, T. Prot, J. Borycki, A. Wylon and B. Siepracka, Pol. PL 140, 593, 30 May 1987, Appl. 250,719, Dec 1984, Chem. Abstr. 111: 96303. E.J. Eisenbraun, J.W. Burnham, J.D. Wearer and T.E. Webb, Ann. N. Y. Acad. Sci. 214, 204-215 (1973).
  19. G.K. Trifonova and L.D. Zaitsea, Veterinariya (Moscow) 2, 10