Journals / Turkish Journal of Earth Sciences / 2013 / Cilt: 22 - Sayı: 3

The key role of micromorphology in studies of the genesis of clay minerals and their associations in soils and its relevance to advances in the philosophy of soil science

Pages
376–390
Publication Date
2013-03-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Micromorphology is especially useful for indicating the nature of aggregates in situ in soils.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Micromorphological observations from 3 different published works have been studied to aid understanding of aggregation and of colloids, both unique to soils.
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Key Findings & Data:Saprolites in Hong Kong included ‘veins’ of different thicknesses and colours.
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Conclusion & Impact:Micromorphology is especially useful for indicating the nature of aggregates in situ in soils.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Aggregates · microaggregates · macroaggregates

Abstract

Micromorphological observations from 3 different published works have been studied to aid understanding of aggregation and of colloids, both unique to soils. Saprolites in Hong Kong included ‘veins’ of different thicknesses and colours. Optical mineralogy identified them as infill from the neogenesis of clays in rock fractures. The common thicker infills resulted from weathering. Dark infill contained comminuted primary minerals whereas thin pale infill originated hydrothermally. Scanning electron microscopy (SEM) showed that the size, shape, and mineralogy of the kaolin minerals formed in infill depended on the types of cracks in the saprolites and on drying. Energy-dispersive X-ray spectroscopy analyses showed Fe and/or Mn in dark-coloured infill from comminution of primary minerals upon brecciation, or else beside pale infill in tuff, showing seasonal drying in tuff but not in granite. Pale infill gave predominantly large tubular halloysite in granite but large platy kaolinite in tuff, except that hydrothermal kaolin gave small particles. In dark infill, kaolin particles were also small and were kaolinite and halloysite mixtures. The effect of impurity Fe and Mn in constraining kaolin mineral crystallinity in infills simulates some of the effects of impure soil environments. Long-term cultivation of soils in Australia led to environmental scanning electron microscope images of large microaggregates indicating their breakdown and loss. Transmission electron micrographs of ultrathin sections showed that microaggregates of clay size, comprising clay minerals and oxides covering other materials, including organic matter, were predominant in virgin soil but were broken down to fine clay particles that blocked pores in cultivated soils. SEM showed a web of biological origin in long-term irrigated sandy New Zealand soil that surrounded macroaggregates but only became closely attached on drying. The nature of the macroaggregates was affected strongly by their history of drying, even during preparation for analyses. Micromorphology is especially useful for indicating the nature of aggregates in situ in soils.

Özet

Micromorphological observations from 3 different published works have been studied to aid understanding of aggregation and of colloids, both unique to soils. Saprolites in Hong Kong included ‘veins’ of different thicknesses and colours. Optical mineralogy identified them as infill from the neogenesis of clays in rock fractures. The common thicker infills resulted from weathering. Dark infill contained comminuted primary minerals whereas thin pale infill originated hydrothermally. Scanning electron microscopy (SEM) showed that the size, shape, and mineralogy of the kaolin minerals formed in infill depended on the types of cracks in the saprolites and on drying. Energy-dispersive X-ray spectroscopy analyses showed Fe and/or Mn in dark-coloured infill from comminution of primary minerals upon brecciation, or else beside pale infill in tuff, showing seasonal drying in tuff but not in granite. Pale infill gave predominantly large tubular halloysite in granite but large platy kaolinite in tuff, except that hydrothermal kaolin gave small particles. In dark infill, kaolin particles were also small and were kaolinite and halloysite mixtures. The effect of impurity Fe and Mn in constraining kaolin mineral crystallinity in infills simulates some of the effects of impure soil environments. Long-term cultivation of soils in Australia led to environmental scanning electron microscope images of large microaggregates indicating their breakdown and loss. Transmission electron micrographs of ultrathin sections showed that microaggregates of clay size, comprising clay minerals and oxides covering other materials, including organic matter, were predominant in virgin soil but were broken down to fine clay particles that blocked pores in cultivated soils. SEM showed a web of biological origin in long-term irrigated sandy New Zealand soil that surrounded macroaggregates but only became closely attached on drying. The nature of the macroaggregates was affected strongly by their history of drying, even during preparation for analyses. Micromorphology is especially useful for indicating the nature of aggregates in situ in soils.

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Cite This Article

CHURCHMAN, G. J. (2013). The key role of micromorphology in studies of the genesis of clay minerals and their associations in soils and its relevance to advances in the philosophy of soil science. Turkish Journal of Earth Sciences, Cilt: 22 - Sayı: 3, 376–390. https://ajindex.com/articles/213190

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References (11)

  1. Bruns, M.A. 2002. Bacteria. In: Lal, R. (ed). Encyclopedia of Soil Science. Marcel Dekker, New York, 94-99.
  2. Campbell, S.D.G., Koor, N.P., Franks, C.A.M. & W.W.L. Shum. 1998. Geological assessment of slopes in areas close to major landslides on Hong Kong Island. In: Li, K.S., Kay, J.N. & Ho, K.K.S. (eds). Slope Engineering in Hong Kong. Balkema, Rotterdam, 121-128.
  3. Chenu, C. 1989. Influence of a fungal polysaccharide, scleroglucan, on clay microstructures. Soil Biology and Biochemistry 21, 299-305. Chenu C. & Plante A.F. 2006. Clay-sized organo-mineral complexes in a cultivation chronosequence: revisiting the concept of the ‘primary organo-mineral complex’. European Journal of Soil Science 57, 596-607.
  4. Churchman, G.J. 2000. The alteration and formation of soil minerals by weathering. In: Summer, M.E. (ed.) Handbook of Soil Science, CRC Press, Boca Raton, F3-F76. Churchman, G.J. 2010a. The philosophical status of soil science. Geoderma 157, 214-221.
  5. Churchman, G.J. 2010b. Is the geological concept of clay minerals appropriate for soil science? A literature-based and philosophical analysis. Physics and Chemistry of the Earth 35, 927-940.
  6. Churchman, G.J. & Carr. R.M. 1975. The definition and nomenclature of halloysites. Clays and Clay Minerals 23, 382-388.
  7. Churchman, G.J., Foster, R.C., D’Acqui, L.P., Janik, L.J., Skjemstad, J.O., Merry, R.H. & Weissmann, D.A. 2010a. Effect of land-use history on the potential for carbon sequestration in an Alfisol. Soil & Tillage Research 109, 23-35.
  8. Churchman, G.J. & Lowe, D.J. 2012. Alteration, formation, and occurrence of minerals in soils. In: Huang, P.M., Li, Y. & Sumner, M.E. (eds). Handbook of Soil Sciences. 2nd edition. Vol. 1: Properties and Processes. CRC Press, Taylor & Francis, Boca Raton, Florida, 20.1-20.72. Churchman, G.J., Pontifex, I.R. & McClure, S.G. 2010b. Factors affecting the formation and characteristics of halloysites or kaolinites in granitic and tuffaceous saprolites in Hong Kong. Clays and Clay Minerals 58, 220-237.
  9. Churchman, G.J., Slade, P.G., Self, P.G. & Janik, L.J. 1994. Nature of interstratified kaolin-smectites in some Australian soils. Australian Journal of Soil Research 32, 805-822.
  10. Churchman, G.J. & Tate, K.R. 1986. Effect of slaughterhouse effluent and water irrigation upon aggregation in seasonally dry New Zealand soil under pasture. Australian Journal of Soil Research 24, 505-516.
  11. Foster, R.C. 1994. & Microorganisms and soil aggregates. In: Pankhurst, C.E., Doube, B.M., Gupta, V.V.S.R.