Journals / Turkish Journal of Earth Sciences / 2013 / Cilt: 22 - Sayı: 6

Impact of Pb-Zn mining activity on surficial sediments of Lake Kalimanci(FYR Macedonia)

Pages
996–1009
Publication Date
2013-06-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The geochemistry, environmental factor values, and toxic metal extraction characteristics of Lake Kalimanci sediments represent a serious environmental risk for an extensive area.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The activities of the Sasa mine have led to industrial discharge being released into Lake Kalimanci since the beginning of mining activity in 1954.
📊
Key Findings & Data:In the present study, surficial lake sediments were analyzed using inductively coupled plasma mass spectrometry (ICP-MS), with all geochemistry data processed using Statistica 8.
💡
Conclusion & Impact:The geochemistry, environmental factor values, and toxic metal extraction characteristics of Lake Kalimanci sediments represent a serious environmental risk for an extensive area.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Key words: Pollution · tailings dam failure · toxic metal contamination

Abstract

The activities of the Sasa mine have led to industrial discharge being released into Lake Kalimanci since the beginning of mining activity in 1954. For this reason, an ecological risk assessment is urgently required. In the present study, surficial lake sediments were analyzed using inductively coupled plasma mass spectrometry (ICP-MS), with all geochemistry data processed using Statistica 8. In order to assess the environmental pollution status, 2 environmental factors were established, while for the determination of chemical fractionation of toxic metals a sequential extraction procedure was carried out. Concentrations of As, Mo, Zn, Ni, Co, Pb, Cd, and Cu in surficial Lake Kalimanci sediments were in the ranges of 58.6-77.2, 2.30-4.60, 7056-20,900, 47.4-79.3, 18.8-25.3, 4863-16,300, 46.8-136, and 328-1162 mg/kg, respectively. Based on values of the enrichment factor and geoaccumulation index, the surficial sediment of Lake Kalimanci is strongly polluted in terms of most of the examined metals. The results of the sequential extraction procedure revealed the majority of the investigated toxic metals (Zn, Pb, Ni, Cu, and Cd) to be strongly bonded to the exchangeable fraction and the rest (As and Mo) to the oxidizable fraction. The geochemistry, environmental factor values, and toxic metal extraction characteristics of Lake Kalimanci sediments represent a serious environmental risk for an extensive area.

Özet

The activities of the Sasa mine have led to industrial discharge being released into Lake Kalimanci since the beginning of mining activity in 1954. For this reason, an ecological risk assessment is urgently required. In the present study, surficial lake sediments were analyzed using inductively coupled plasma mass spectrometry (ICP-MS), with all geochemistry data processed using Statistica 8. In order to assess the environmental pollution status, 2 environmental factors were established, while for the determination of chemical fractionation of toxic metals a sequential extraction procedure was carried out. Concentrations of As, Mo, Zn, Ni, Co, Pb, Cd, and Cu in surficial Lake Kalimanci sediments were in the ranges of 58.6-77.2, 2.30-4.60, 7056-20,900, 47.4-79.3, 18.8-25.3, 4863-16,300, 46.8-136, and 328-1162 mg/kg, respectively. Based on values of the enrichment factor and geoaccumulation index, the surficial sediment of Lake Kalimanci is strongly polluted in terms of most of the examined metals. The results of the sequential extraction procedure revealed the majority of the investigated toxic metals (Zn, Pb, Ni, Cu, and Cd) to be strongly bonded to the exchangeable fraction and the rest (As and Mo) to the oxidizable fraction. The geochemistry, environmental factor values, and toxic metal extraction characteristics of Lake Kalimanci sediments represent a serious environmental risk for an extensive area.

🔖

Cite This Article

VRHOVNIK, P., SMUC, N. R., DOLENEC, T., SERAFIMOVSKI, T., DOLENEC, M. (2013). Impact of Pb-Zn mining activity on surficial sediments of Lake Kalimanci(FYR Macedonia). Turkish Journal of Earth Sciences, Cilt: 22 - Sayı: 6, 996–1009. https://ajindex.com/articles/209921

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (12)

  1. Adham, K.G., Hasan, I.F., Taha, N. & Amin, T. 1999. Impact of hazardous exposure to metals in the Nile and Delta Lakes on the Catfish, Clarias Lazera. Environmental Monitoring and Assessment 54, 107–124.
  2. Anju, M. & Banerjee, D. 2011. Associations of cadmium, zinc, and lead in soils from a lead and zinc mining area as studied by single and sequential extractions. Environmental Monitoring and Assessment 176, 67–85.
  3. Arjonilla, M., Forja, J.M. & Gomez-Parra, A. 1994. Sediment analysis does not provide a good measure of heavy metal bioavailability to Cerastoderma glaucum (Mollusca: Bivalvia) in confined coastal ecosystems. Bulletin of Environmental Contamination and Toxicology 52, 810–817.
  4. Audry, S., Schäfer, J., Blanc, G., Bossy, C. & Lavaux, G. 2004. Anthropogenic components of heavy metal (Cd, Zn, Cu, Pb) budgets in the Lot–Garonne fluvial system (France). Applied Geochemistry 19, 269–286.
  5. Belzile, N., Chen, Y.W., Gunn, J.M. & Dixit, S.D. 2004. Sediment trace metal profiles in lakes of Killarney Park, Canada: from regional to continental influence. Environmental Pollution 130, 239–248.
  6. Bibi, M.H., Ahmed, F. & Ishiga, H. 2007. Assessment of metal concentrations in lake sediments of southwest Japan based on sediment quality guidelines. Environmental Geology 52, 625–639.
  7. Birch, G.F. & Taylor, S.E. 2000. The use of size-normalized procedures in the analysis of organic contaminants in estuarine sediments. Hydrobiology 431, 129–133.
  8. Birth, G. 2003. A scheme for assessing human impacts on coastal aquatic environments using sediments. In: Woodcoffe, C.D. & Furness, R.A. (eds), Coastal GIS 2003.
  9. Wollongong University Papers, Center for Maritime Policy 14. Calamano, W., Hong, J. & Förstner, U. 1993. Binding and mobilization of heavy metals in contaminated sediments affected by pH and redox potential. Water Science and Technology 28, 223–235.
  10. Callender, E. 2000. Geochemical effects of rapid sedimentation in aquatic systems: minimal diagenesis and the preservation of historical metal signatures. Journal of Paleolimnology 23, 243– 2 Campbell, P.G.C. 1995. Interactions between trace metals and aquatic organisms: a critique of the free-ion activity model. In: Tessier, A. & Turner, D. (eds), Metal Speciation and Bioavailability in Aquatic Systems. John Wiley and Sons, Chichester, 45–402.
  11. Cappuyns, V., Swennen, R., Vandamme, A. & Niclaes, M. 2006. Environmental impact of the former Pb–Zn mining and smelting in East Belgium. Journal of Geochemical Exploration 88, 6–9.
  12. Chen, K