SavedAdd your journal

Journals / Turkish Journal of Chemistry / 2021 / Cilt: 45 - Sayı: 1

Synthesis and characterization of novel 4-benzyloxyphenyl 4-[4-(n-dodecyloxy) benzoyloxy]benzoate liquid crystal

Emine BALKANLİ
Fatih CAKAR
Hale OCAK
Ozlem CANKURTARAN
Belkiz BİLGİN ERAN
Pages
71–81
Publication Date
2021-02-17
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Flory-Huggins interaction parameter and weight fraction activity coefficient at infinite dilution were researched for BDBB.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Liquid crystal (LC) compound 4-Benzyloxyphenyl 4-[4-(n-dodecyloxy)benzoyloxy]benzoate (BDBB) was prepared and characterized.
📊
Key Findings & Data:Acetate and alcohol isomers were used to examine LC selectivity via the IGC technique at temperatures between 333.2 K and 483.2 K.
💡
Conclusion & Impact:Flory-Huggins interaction parameter and weight fraction activity coefficient at infinite dilution were researched for BDBB.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Inverse gas chromatography · liquid crystals · thermodynamics

Abstract

Liquid crystal (LC) compound 4-Benzyloxyphenyl 4-[4-(n-dodecyloxy)benzoyloxy]benzoate (BDBB) was prepared and characterized. Inverse gas chromatography (IGC) was to be a beneficial analysis method for the research of thermodynamic characteristics of the new LC. Acetate and alcohol isomers were used to examine LC selectivity via the IGC technique at temperatures between 333.2 K and 483.2 K. The retention diagrams of n-heptane, n-octane, n-nonane, n-decane, undecane, dodecane, tridecane, n-butyl acetate, isobutyl acetate, ethyl acetate, n-propylbenzene, isopropylbenzene, ethylbenzene, chlorobenzene, and toluene on BDBB were plotted with temperatures of 483.2-493.2 K. Flory-Huggins interaction parameter and weight fraction activity coefficient at infinite dilution were researched for BDBB.

🔖

Cite This Article

BALKANLİ, E., CAKAR, F., OCAK, H., CANKURTARAN, O., ERAN, B. B. (2021). Synthesis and characterization of novel 4-benzyloxyphenyl 4-[4-(n-dodecyloxy) benzoyloxy]benzoate liquid crystal. Turkish Journal of Chemistry, Cilt: 45 - Sayı: 1, 71–81. https://ajindex.com/articles/201334

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (4)

  1. Achten R, 2004, LIQ CRYST, V31, P1167, DOI 10.1080/02678290410001724755 Ahmed NHS, 2018, LIQ CRYST, V45, P1487, DOI 10.1080/02678292.2018.1449025 Ansari DM, 2004,
  2. POLYMER, V45, P1823, DOI 10.1016/j.polymer.2004.01.018 Antoine C, 1888, CR ACAD SCI, V107, P681 Balamurugan S, 2011, LIQ CRYST, V38, P1199, DOI 10.1080/02678292.2011.602124 Bolvari AE, 1989, INVERSE GAS CHROMATO. Bubnov A, 2018, LIQ CRYST, V45, P561, DOI 10.1080/02678292.2017.1359858 Cakar F, 2014, LIQ CRYST, V41, P1323, DOI 10.1080/02678292.2014.919672 Collings PJ., 1997, INTRO LIQUID CRYSTAL CRUICKSHANK AJ, 1966, T FARADAY SOC, V62, P2341, DOI 10.1039/tf9666202341 Danner, 1989, PHYS THERMODYNAMIC P. Erol I, 2016, LIQ CRYST, V43, P142, DOI 10.1080/02678292.2015.1067334 Goodby JW, 2014, HDB LIQUID CRYSTALS, P133 Kong XX, 1998, CHEM MATER, V10, P3352, DOI 10.1021/cm9803152 Korkut SE, 2018, J CHEM ENG DATA, V63, P1146, DOI 10.1021/acs.jced.7b00490 Lee GS, 2000, J AM CHEM SOC, V122, P12151, DOI 10.1021/ja0028222 Littlewood BA, 1970, GAS CHROMATOGRAPHY. Muhammad K, 2011, LIQ CRYST, V38, P333, DOI 10.1080/02678292.2010.547610 Naoum MM, 2015, LIQ CRYST, V42, P1627, DOI 10.1080/02678292.2015.1081298 Ocak H, 2016, J MOL LIQ, V223, P861, DOI 10.1016/j.molliq.2016.09.002 Ocak H, 2015, CHEM COMMUN, V51, P7512, DOI 10.1039/c5cc01592h Ozerol EA, 2019,
  3. CHEMISTRYSELECT, V4, P9006, DOI 10.1002/slct.201901550 Ozturk E, 2018, J MOL LIQ, V265, P24, DOI 10.1016/j.molliq.2018.05.080 Shen D, 2000, J AM CHEM SOC, V122, P1593, DOI 10.1021/ja993572w SMIDSROD O, 1969,
  4. MACROMOLECULES, V2, P272, DOI 10.1021/ma60009a012 TSCHIERSKE C, 1989, J PRAKT CHEM, V331, P365, DOI 10.1002/prac.19893310225 Voelkel A, 2009, J CHROMATOGR A, V1216, P1551, DOI 10.1016/j.chroma.2008.10.096 Wilderbeek HTA, 2003, LIQ CRYST, V30, P93, DOI 10.1080/0267829021000001746 Yaws CL, YAWS HDB VAPOR PRESS.