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Journals / Turkish Journal of Chemistry / 2021 / Cilt: 45 - Sayı: 1

Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry

Turgut KELES
Dilek UNLUER
Zekeriya BİYİKLİOGLU
Yasemin UNVER
Pages
17–25
Publication Date
2021-02-17
DOI
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

Voltammetric characterizations of n-TY-Co, n-TY-Cu, and n-TY-Mn revealed that while n-TY-Co, n-TY-Cu, and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co, n-TY-Cu, and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-(diethylamino)-2-formylphenoxy] substituents.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:3-[5-(diethylamino)-2-formylphenoxy]phthalonitrile (n-TY-CN), metallophthalocyanines n-TY-Co, n-TY-Cu, and n-TY-Mn bearing [5-(diethylamino)-2-formylphenoxy] groups at nonperipheral positions were prepared for the first time.
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Key Findings & Data:These compounds were characterized with IR, NMR (only for n-TY-CN), mass and UV-vis (except n-TY-CN) spectroscopy.
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Conclusion & Impact:Voltammetric characterizations of n-TY-Co, n-TY-Cu, and n-TY-Mn revealed that while n-TY-Co, n-TY-Cu, and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co, n-TY-Cu, and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-(diethylamino)-2-formylphenoxy] substituents.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Synthesis · diethylamino · phthalocyanine

Abstract

3-[5-(diethylamino)-2-formylphenoxy]phthalonitrile (n-TY-CN), metallophthalocyanines n-TY-Co, n-TY-Cu, and n-TY-Mn bearing [5-(diethylamino)-2-formylphenoxy] groups at nonperipheral positions were prepared for the first time. These compounds were characterized with IR, NMR (only for n-TY-CN), mass and UV-vis (except n-TY-CN) spectroscopy. Voltammetric characterizations of n-TY-Co, n-TY-Cu, and n-TY-Mn revealed that while n-TY-Co, n-TY-Cu, and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co, n-TY-Cu, and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-(diethylamino)-2-formylphenoxy] substituents.

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Cite This Article

KELES, T., UNLUER, D., BİYİKLİOGLU, Z., UNVER, Y. (2021). Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry. Turkish Journal of Chemistry, Cilt: 45 - Sayı: 1, 17–25. https://ajindex.com/articles/201328

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