Journals / Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering / 2018 / Cilt: 19 - Sayı: 3

Preparation and Characterization of Polyester Polyol Modified Bitumen for Pavement Applications

Pages
574–584
Publication Date
2018-09-01
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Also, this study showed that the use of BHET obtained by PET waste as a starting material for polyester polyol synthesis could be an alternative way to utilize plastic waste.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, polymer modified bitumen (PMB) from polyester polyols was prepared by bis(2-hydroxyethyl terephthalate) (BHET) which was obtained by glycolysis of Polyethylene terephthalate (PET) waste.
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Key Findings & Data:POL1, synthesized from BHET and adipic acid (AA), were blended with the bitumen resulting in improved stiffness, rutting resistance and fatigue performance with respect to neat bitumen.
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Conclusion & Impact:Also, this study showed that the use of BHET obtained by PET waste as a starting material for polyester polyol synthesis could be an alternative way to utilize plastic waste.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:PET waste · Polymer modified bitumen

Abstract

In this study, polymer modified bitumen (PMB) from polyester polyols was prepared by bis(2-hydroxyethyl terephthalate) (BHET) which was obtained by glycolysis of Polyethylene terephthalate (PET) waste. The effect of polyester polyol structure on the rheological properties of PMB was investigated. Polyester polyols obtained by the reaction of various polyols and polycarboxylic acids. POL1, synthesized from BHET and adipic acid (AA), were blended with the bitumen resulting in improved stiffness, rutting resistance and fatigue performance with respect to neat bitumen. Also, the synergistic effects of the polyester polyol addition into styrene-butadiene-styrene modified bitumen (SBS-Bitumen) were investigated where this reference mixture contains SBS loading of 3 % according to the weight of bitumen. Although the addition of POL1(1.3:1) into SBS:Bitumen mixture at 3:3:94 weight ratio didn’t alter the high temperature performance grade of PMB, POL1:SBS:Bitumen exhibited higher softening point, elastic recovery and rutting parameter than reference mixture. The early stage promising results of this study indicated the potential benefits of polyester polyol as bitumen modifier. Also, this study showed that the use of BHET obtained by PET waste as a starting material for polyester polyol synthesis could be an alternative way to utilize plastic waste.

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Cite This Article

ARI, G. A., AKYOL, S., YAŞAR, M., SORMAGİR, M., GÜRDAL, S., BAŞKENT, E., CANIAZ, R. O., ÇETİNTAŞ, R., ARCA, S., KOCAMAN, E., KÖSTERELİ, Z. (2018). Preparation and Characterization of Polyester Polyol Modified Bitumen for Pavement Applications. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering, Cilt: 19 - Sayı: 3, 574–584. https://ajindex.com/articles/197058

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References (14)

  1. http://www.eapa.org/userfiles/2/Asphalt%20in%20Figures/2014/AIF_2014_v10.pdf (Erişim tarihi: 20.12.2016)
  2. Izquierdo MA, Navarro FJ, Martínez-Boza FJ, Gallegos C. Novel stable MDI isocyanate-based bituminous foams. Fuel 2011; 90:681-688.
  3. Cuadri AA, García-Morales M, Navarro FJ, Partal P. Effect of transesterification degree and post-treatment on the in-service performance of NCO-functionalized vegetable oil bituminous products. Chem Eng Sci 2014; 111: 126-134.
  4. Izquierdo MA, Navarro FJ, Martínez-Boza FJ, Gallegos C. Bituminous polyurethane foams for building applications: Influence of bitumen hardness. Con Build Mat 2012; 30: 706-713.
  5. Bulatovic VO, Rek V, Markovic KJ. Effect of polymer modifiers on the properties of bitumen. J Elast Plast 2014; 46: 448-469.
  6. Zhu J, Birgisson B, Kringos N. Polymer modification of bitumen: Advances and challenges. Eur Polym J 2014; 54: 18-38. Lu X. 1997. On polymer modified road bitumens (doctoral dissertation), Stockholm: KTH Royal Institute of Technology. Chen JS, Liao MC, Shiah MS. Asphalt modified by styrene-butadiene-styrene triblock copolymer: morphology and model. J Mater Civ Eng 2002; 14: 224-229.
  7. Vargas MA, Chavez AE, Herrera R, Manero O. Asphalt modified by partially hydrogenated SBS tri-block copolymers. Rubber Chem Techn 2005; 78: 620-643.
  8. Şengöz B, Işıkyakar G. Analysis of styrene-butadiene-styrene polymer modified bitumen using fluorescent microscopy and conventional test methods. J Haz Mat 2008; 150: 424-432.
  9. Collins JH, Bouldin MG. Stability of straight and polymer-modified asphalts. Transportation Research Record: J Trans Res Board 1992; 1342: 92-100.
  10. Li Y, Li I, Zhang Y, Zhao S, Xie L, Yao S. Improving the aging resistance of styrene-butadiene-styrene tri-block copolymer and application in polymer modified asphalt. J Appl Polym Sci 2010; 116; 754-761.
  11. Zhang J, Wang J, Wu Y, Wang Y, Wang Y. Evaluation of the improved properties of SBR/weathered coal modified bitumen containing carbon black. Con Build Mat 2009; 23: 2678-2687.
  12. Polacco G, Muscente A, Biondi D, Santini S. Effect of composition on the properties of SEBS modified asphalts. E Poylm J 2006; 42: 1113-1121.
  13. Karahrodi MH, Jazani OM, Paran SMR, Formela K, Saeb MR. Modification of thermal and rheological characteristics of bitumen by waste PET /GTR blends. Con Build Mat 2017; 134: 157-166.
  14. Padhan RK, Gupta AA, Badoni RP, Bhatnagar AK. Poly(ethylene terephthalate) waste derived chemicals as an antistripping additive for bitumen – An environment friendly