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Journals / Turkish Journal of Chemistry / 2006 / Cilt: 30 - Sayı: 5

Dichloride[1-(2,4,6-trimethylbenzyl)-3- (biphenyl-2-ylmethyl)-imidazolidin-2-ylidine (η6 -hexamethylbenzene)]ruthenium

Dichloride[1-(2,4,6-trimethylbenzyl)-3-(biphenyl-2-ylmethyl)-imidazolidin- 2-ylidine (h6-hexamethylbenzene)]ruthenium

Hakan ARSLAN
Donald Van DERVEER
İsmail ÖZDEMİR
Sedat YAŞAR
Bekir ÇETİNKAYA
Pages
535–541
Publication Date
2006-05-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The single crystal X-ray structure of the imidazolidin ruthenium complex, C38H46N2Cl2Ru, was determined.
📊
Key Findings & Data:The complex is an orthorhombic space group Pbca with a = 17.3586(32) Å, b = 14.4447(27) Å, c = 27.4325(52) Å, and V = 6878.466(4) Å3 with Z = 8 for Dcalc = 1.357 g/cm3.
💡
Conclusion & Impact:The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Arenes · carbenes · imidazole

Abstract

The single crystal X-ray structure of the imidazolidin ruthenium complex, C38H46N2Cl2Ru, was determined. The complex is an orthorhombic space group Pbca with a = 17.3586(32) Å, b = 14.4447(27) Å, c = 27.4325(52) Å, and V = 6878.466(4) Å3 with Z = 8 for Dcalc = 1.357 g/cm3. It exhibits the expected 3-legged piano stool geometry. There is one coordination bond of the ruthenium atom with the electrons of the h6-hexamethylbenzene, 2 symmetrical Ru-Cl bonds, and one Ru-C bond involving the imidazole ring. The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral.

Özet

The single crystal X-ray structure of the imidazolidin ruthenium complex, C38H46N2Cl2Ru, was determined. The complex is an orthorhombic space group Pbca with a = 17.3586(32) Å, b = 14.4447(27) Å, c = 27.4325(52) Å, and V = 6878.466(4) Å3 with Z = 8 for Dcalc = 1.357 g/cm3. It exhibits the expected 3-legged piano stool geometry. There is one coordination bond of the ruthenium atom with the electrons of the h6-hexamethylbenzene, 2 symmetrical Ru-Cl bonds, and one Ru-C bond involving the imidazole ring. The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral.

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Cite This Article

ARSLAN, H., DERVEER, D. V., ÖZDEMİR, İ., YAŞAR, S., ÇETİNKAYA, B. (2006). Dichloride[1-(2,4,6-trimethylbenzyl)-3- (biphenyl-2-ylmethyl)-imidazolidin-2-ylidine (η6 -hexamethylbenzene)]ruthenium. Turkish Journal of Chemistry, Cilt: 30 - Sayı: 5, 535–541. https://ajindex.com/articles/185428

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