Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired b-nitroalcohols were obtained.
📌 3 Key Takeaways
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Objective & Hypothesis:Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions.
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Key Findings & Data:Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions.
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Conclusion & Impact:Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired b-nitroalcohols were obtained.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Asymmetric Henry reaction · chiral Schiff base · L-tert-Leucine
Abstract
Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired b-nitroalcohols were obtained.
Özet
Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired b-nitroalcohols were obtained.
KORKMAZ, N., ASTLEY, D., ASTLEY, S. T. (2011). Tridentate ligands derived from L-tert-Leucine for the Cu(II) mediated asymmetric Henry reaction. Turkish Journal of Chemistry, Cilt: 35 - Sayı: 3, 361–374. https://ajindex.com/articles/185369