SavedAdd your journal

Journals / Turkish Journal of Chemistry / 2008 / Cilt: 32 - Sayı: 3

A Hydrogen Ion-Selective Poly(Vinyl Chloride) Membrane Electrode Based on Calix[4]arene as a Perchlorate Ion-Selective Electrode

Esin CANEL
Sevcan ERDEN
Ayça DEMİREL ÖZEL
Sahahabuddin MEMON
Pages
323–332
Publication Date
2008-03-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The selectivity coefficients of some anions were calculated by the matched potential method.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:A hydrogen ion-selective electrode was prepared using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracyanometoxy-calix[4]arene and the possibility of its use as a perchlorate ion-selective electrode was investigated using its characteristic of becoming perchlorate sensitive in acidic regions.
📊
Key Findings & Data:The electrode of the optimum characteristic had a composition of 1% ionophore, 66% o-NPOE, and 33% PVC.
💡
Conclusion & Impact:The selectivity coefficients of some anions were calculated by the matched potential method.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Calix[4]arene · perchlorate · PVC membrane ion-selective electrode

Abstract

A hydrogen ion-selective electrode was prepared using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracyanometoxy-calix[4]arene and the possibility of its use as a perchlorate ion-selective electrode was investigated using its characteristic of becoming perchlorate sensitive in acidic regions. The electrode of the optimum characteristic had a composition of 1% ionophore, 66% o-NPOE, and 33% PVC. This electrode exhibited a linear response over the range 1.0 \times 10-1-1.0 \times 10-5 M of perchlorate with a slope of 48.7 \pm 0.5 mV per p[ClO4]. The effects of the pH and the membrane composition were also investigated. The lifetime of the electrode was at least 4 months and its response time was 10-15 s. The selectivity coefficients of some anions were calculated by the matched potential method.

Özet

A hydrogen ion-selective electrode was prepared using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracyanometoxy-calix[4]arene and the possibility of its use as a perchlorate ion-selective electrode was investigated using its characteristic of becoming perchlorate sensitive in acidic regions. The electrode of the optimum characteristic had a composition of 1% ionophore, 66% o-NPOE, and 33% PVC. This electrode exhibited a linear response over the range 1.0 \times 10-1-1.0 \times 10-5 M of perchlorate with a slope of 48.7 \pm 0.5 mV per p[ClO4]. The effects of the pH and the membrane composition were also investigated. The lifetime of the electrode was at least 4 months and its response time was 10-15 s. The selectivity coefficients of some anions were calculated by the matched potential method.

🔖

Cite This Article

CANEL, E., ERDEN, S., ÖZEL, A. D., MEMON, S. (2008). A Hydrogen Ion-Selective Poly(Vinyl Chloride) Membrane Electrode Based on Calix[4]arene as a Perchlorate Ion-Selective Electrode. Turkish Journal of Chemistry, Cilt: 32 - Sayı: 3, 323–332. https://ajindex.com/articles/185034

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (23)

  1. M.J. Berrocal, A.Cruz, I.H.A. Badr and L.G. Bachas, Anal. Chem. 72, 5295-5299 (2000).
  2. R.S. Hutchins and L.G. Bachas, Anal. Chem. 67, 1654-1660 (1995).
  3. S.B. Park, W. Matuszewski, M.E. Meyerhoff, Y.H. Liu and K.M. Kadish, Electroanal. 3, 909-916 (1991).
  4. N.A. Chaniotakis, K. Jurkschat and A. R¨uhlemann, Anal. Chim. Acta 282, 345-352 (1993).
  5. K. Perdikaki, I. Tsagkatakis, N.A. Chaniotakis, R. Altmann, K. Jurkschat and G. Reeske, Anal. Chim. Acta, 197-204 (2002).
  6. N.A. Chaniotakis, J.K. Tsagkatakis, K. Jurkschat and R. Willem, React. Funct. Polym. 34, 183-188 (1997).
  7. G.E. Andredakis, E.A. Moschou, K. Matthaiou, G.E. Froudakis and N.A. Chaniotakis, Anal. Chim. Acta, 273-280 (2001).
  8. W. Simon, W.E. Morf and C. Ammann, in “Calcium Binding Proteins and Calcium Function” (Ed: R. H. Wassermann), Elsevier North-Holland, New York, 1977.
  9. J.D. Kruse-Jarres, Med. Prog. Technol. 13, 107-130 (1988).
  10. U. Oesch, D. Ammann and W. Simon, Clin. Chem. 32, 1448-1459 (1986). J. Janata and R.J. Huber, in “Ion-Selective Electrodes in Analytical Chemistry”, Vol. 2 (Ed: H. Fresiser), Plenum Press, New York, 1980.
  11. Y. Alifragis, G. Konstantinidis, A. Georgakilas and N. Chaniotakis. Electroanal. 17, 527-531 (2005).
  12. F.P. Schmidtchen and M. Berger, Chem. Rev. 97, 1609-1646 (1997).
  13. P.D. Beer and P.A. Gale, Angew. Chem. Int. Ed. 40, 486-516 (2001). R. Martinez-M´a˜nez and F. Sancen˜on, Chem. Rev. 103, 4419-4476 (2003).
  14. M.M.G. Antonisse and D.N. Reinhoudt, Electroanal. 11(14), 1035-1048 (1999).
  15. P. Buhlmann, E. Pretsch and E. Bakker, Chem. Rev. 98, 1593-1688 (1998).
  16. P.A. Gale, J.L. Sessler, V. Kr´al and V. Lynch, J. Am. Chem. Soc. 118, 5140-5141 (1996).
  17. P.A. Gale, Z. Chen, M.G.B. Drew, J.A. Heath and P.D. Beer, Polyhedron 17, 405-412 (1998).
  18. J. Lizondo-Sabater, M.J. Segui, J.M. Lloris, R. Martinez-M´a˜nez, T. Pardo, F. Sancen˜on and J. Sotoi, Sens. Actuators B 101, 20-27 (2004).
  19. G. McMahon, S. O’Malley, K. Nolan and D. Diamond, Arkivoc (vii) 23-31 (2003). V.V. Egorov and Y.V. Sin’kevich, Talanta 48, 23-38 (1999). D. Kuruo˘glu, E. Canel, S. Memon, M. Yildiz and E. Kılı¸c, Anal. Sci. 19, 217-221 (2003).
  20. A. Demirel, A. Do˘gan, E. Canel, S. Memon, M. Yılmaz and E. Kılı¸c, Talanta 62, 123-129 (2004). W. Wr´oblewski, E. Malinowska and Z. Brz´ozka, Electroanal. 8, 75-78 (1996).
  21. S.M. Lim, H.J. Chung, K.J. Paeng, C.H. Lee, H.N. Choi and W.Y. Lee, Anal. Chim. Acta 453, 81-88 (2002).
  22. P.A. Gale, J.L. Sessler, W.E. Allen, N.A. Tvermoes and V. Lynch, Chem. Commun. 665-666 (1997).
  23. H. James, G. Carmack and H. Fre