Journals / Turkish Journal of Chemistry / 2009 / Cilt: 33 - Sayı: 2

Water-Gas Shift Reaction over Bimetallic Pt-Ni/Al2O3 Catalysts

Pages
249–256
Publication Date
2009-02-01
DOI
—
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

The results indicate that Pt-Ni/Al2O3 catalysts are highly selective and active for water-gas shift reactions under idealized conditions.

📌 3 Key Takeaways

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Objective & Hypothesis:The water-gas shift (WGS) activity of bimetallic Pt-Ni/Al2O3 catalysts was investigated in the temperature range 200-450 °C using an idealized feed composition consisting of 3% CO and 6%-10% H2O.
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Key Findings & Data:The effects of the Ni content, space velocity, and H2O/CO ratio on the catalytic performance of the catalysts were studied.
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Conclusion & Impact:The results indicate that Pt-Ni/Al2O3 catalysts are highly selective and active for water-gas shift reactions under idealized conditions.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Water-gas shift · Pt-Ni · CO removal

Abstract

The water-gas shift (WGS) activity of bimetallic Pt-Ni/Al2O3 catalysts was investigated in the temperature range 200-450 °C using an idealized feed composition consisting of 3% CO and 6%-10% H2O. The effects of the Ni content, space velocity, and H2O/CO ratio on the catalytic performance of the catalysts were studied. An increase in the Ni content and H2O/CO ratio shifted the carbon monoxide conversion--temperature curve toward lower reaction temperatures. No detectable methane formation was observed in the catalytic reaction tests. The results indicate that Pt-Ni/Al2O3 catalysts are highly selective and active for water-gas shift reactions under idealized conditions.

Özet

The water-gas shift (WGS) activity of bimetallic Pt-Ni/Al2O3 catalysts was investigated in the temperature range 200-450 °C using an idealized feed composition consisting of 3% CO and 6%-10% H2O. The effects of the Ni content, space velocity, and H2O/CO ratio on the catalytic performance of the catalysts were studied. An increase in the Ni content and H2O/CO ratio shifted the carbon monoxide conversion--temperature curve toward lower reaction temperatures. No detectable methane formation was observed in the catalytic reaction tests. The results indicate that Pt-Ni/Al2O3 catalysts are highly selective and active for water-gas shift reactions under idealized conditions.

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Cite This Article

ÇAĞLAYAN, B. S., AKSOYLU, A. E. (2009). Water-Gas Shift Reaction over Bimetallic Pt-Ni/Al2O3 Catalysts. Turkish Journal of Chemistry, Cilt: 33 - Sayı: 2, 249–256. https://ajindex.com/articles/184970

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