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Journals / Turkish Journal of Chemistry / 2014 / Cilt: 38 - Sayı: 6

N -bridged dimers of tetrapyrroles complexed by transition metals: syntheses, characterization methods, and uses as oxidation catalysts

N-bridged dimers of tetrapyrroles complexed by transition metals: syntheses, characterization methods, and uses as oxidation catalysts

Ümit İŞCİ
Fabienne DUMOULİN
Alexander B. SOROKİN
Vefa AHSEN
Pages
923–949
Publication Date
2014-06-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Finally, their uses and importance of oxidation catalysts are reviewed.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:N-bridged dimers of tetrapyrroles complexed by transition metals have been known for nearly four decades, and gained renewed attention when their powerful oxidation properties were recently evidenced.
📊
Key Findings & Data:This article is a state of the art review of the reported complexes and of their synthetic methods.
💡
Conclusion & Impact:Finally, their uses and importance of oxidation catalysts are reviewed.
🔬Design:Review & Systematic Survey
📍Scope:Comprehensive Sample
⚙️Variables:Tetrapyrrole · porphyrin · phthalocyanine

Abstract

N-bridged dimers of tetrapyrroles complexed by transition metals have been known for nearly four decades, and gained renewed attention when their powerful oxidation properties were recently evidenced. This article is a state of the art review of the reported complexes and of their synthetic methods. Beyond classical chemistry characterization tools, specific methods appropriate to their structure are used and are presented in detail. Finally, their uses and importance of oxidation catalysts are reviewed.

Özet

N-bridged dimers of tetrapyrroles complexed by transition metals have been known for nearly four decades, and gained renewed attention when their powerful oxidation properties were recently evidenced. This article is a state of the art review of the reported complexes and of their synthetic methods. Beyond classical chemistry characterization tools, specific methods appropriate to their structure are used and are presented in detail. Finally, their uses and importance of oxidation catalysts are reviewed.

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Cite This Article

İŞCİ, Ü., DUMOULİN, F., SOROKİN, A. B., AHSEN, V. (2014). N -bridged dimers of tetrapyrroles complexed by transition metals: syntheses, characterization methods, and uses as oxidation catalysts. Turkish Journal of Chemistry, Cilt: 38 - Sayı: 6, 923–949. https://ajindex.com/articles/184669

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References (25)

  1. Eichhorn, H. J. Porphyrins Phthalocyanines 2000, 4, 88–102. de la Torre, G.; V´azquez, P.; Agull´o-L´opez, F.; Torres, T. Chem. Rev. 2004, 104, 3723–3750. de la Torre, G.; Claessens, C.; Torres, T. Chem. Commun. 2007, 2000–2015.
  2. Garcia, J.; Gonzalez, A.; Gouloumis, A.; Maya, E. M.; Perez, M. D.; Rey, B. D.; Vazquez, P.; Torres, T. Turk. J. Chem. 1998, 22, 23–31.
  3. Liu, M. O.; Tai, C. H.; Sain, M. Z.; Hua, A. T.; Chou, F. J. Photochem. Photobiol. A: Chem. 2004, 165, 131–136. de Saja, J. A.; Rodr´ıguez-M´endez, M. L. Adv. Coll. Interf. Sci. 2005, 116, 1–11.
  4. Costas, M. Coord. Chem. 2011, 225, 2912–2932.
  5. Sorokin, A. B. Chem. Rev. 2013, 113, 8152–8191.
  6. Sorokin, A. B.; Kudrik, E. V. Catal. Today 2011, 159, 37–46.
  7. Aviv-Harel, I.; Gross, Z. Chem. Eur. J. 2009, 15, 8382–8394.
  8. Goldberg, D. P. Acc. Chem. Res. 2007, 40, 626–634.
  9. Rodriguez-Morgade, M. S.; Stuzhin, P. A. J. Porphyrins Phthalocyanines 2004, 8, 1129–1165.
  10. Floris, B.; Donzello, M. P.; Ercolani. C. In The Porphyrin Handbook Vol 18; Kadish, K. M.; Smith, K. M.; Guilard, R., Eds. Elsevier Science: San Diego, CA, USA, 2003, pp. 1–62.
  11. Summerville, D. A.; Cohen, I. A. J. Am. Chem. Soc. 1976, 98, 1747–1752.
  12. Schick, G. A.; Findsen, E. W.; Bocian, D. F. Inorg. Chem. 1982, 21, 2885–2887.
  13. Scheidt, R. W.; Summerville, D. A.; Cohen, A. I. J. Am. Chem. Soc. 1976, 98, 6623–6628.
  14. Schick, G. A.; Bocian, D. F. J. Am. Chem. Soc. 1983, 105, 1830–1838.
  15. Bocian, D. F.; Findsen, E. W.; Hofmann, J. A.; Schick, G. A.; English, D. R.; Hendrickson, D. N.; Suslick, K. S. Inorg. Chem. 1984, 23, 800–807.
  16. Wagner, W. D.; Nakamoto, K. J. Am. Chem. Soc. 1988, 110, 4044–4045.
  17. Li, M.; Shang, M.; Ehlinger, N.; Schulz, C. E.; Scheidt, W. R. Inorg. Chem. 2000, 39, 580–583.
  18. Kudrik, E. V.; Afanasiev, P.; Alvarez, L. X.; Dubourdeaux, P.; Clemancey, M.; Latour, J. M.; Blondin, G.; Bouchu, D.; Albrieux, F.; Nefedov, S. E.; et al. Nature Chem. 2012, 4, 1024–1029.
  19. Kadish, K. M.; Rhodes, R. K.; Bottomley, L. A.; Goff, H. M. Inorg. Chem. 1981, 20, 3195–3200.
  20. Kudrik, E. V.; Albrieux, F.; Afanasiev, P.; Sorokin, A. B. J. Porphyrins Phthalocyanines 2013, 17, 791–798.
  21. Li, M.; Scheidt. W. R. J. Porphyrins Phthalocyanines 2014, 18, 380–384.
  22. Tong, C.; Bottomley, L. A. Inorg. Chem. 1996, 35, 5108–5109.
  23. Stuzhin, P. A.; Hamdusha, M.; Homborg, H. Mendeleev Commun. 1997, 7, 196–198.
  24. Ercolani, C.; Jubb, J.; Pennesi, G.; Russo, U.; Trigante, G. Inorg. Chem. 1995, 34, 2535–2541.
  25. Ercolani, C.; Hewage, S.; Heucher, R.; Rowill. G. Inorg. Chem. 1993, 32, 2975–2977. Donzello