Journals / Turkish Journal of Chemistry / 2014 / Cilt: 38 - Sayı: 2

Synthesis and characterization of new metallophthalocyanines containing O4S2 mixed-donor substituted macrocyclic groups

Pages
317–327
Publication Date
2014-05-18
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Structures of the new compounds were characterized by IR, 1H NMR, 13C NMR, elemental analysis, and MS spectral data.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:New phthalocyanine compounds containing mixed-donor substituted macrocyclic groups were synthesized.
📊
Key Findings & Data:The complexes of metal phthalocyanines 3--5 were prepared by the reaction of 2 to get dinitrile derivative complexes by means of the corresponding anhydrous metal salts.
💡
Conclusion & Impact:Structures of the new compounds were characterized by IR, 1H NMR, 13C NMR, elemental analysis, and MS spectral data.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Phthalonitrile · cyclotetramerization · dicarbonitrile

Abstract

New phthalocyanine compounds containing mixed-donor substituted macrocyclic groups were synthesized. The complexes of metal phthalocyanines 3--5 were prepared by the reaction of 2 to get dinitrile derivative complexes by means of the corresponding anhydrous metal salts. Structures of the new compounds were characterized by IR, 1H NMR, 13C NMR, elemental analysis, and MS spectral data.

Özet

New phthalocyanine compounds containing mixed-donor substituted macrocyclic groups were synthesized. The complexes of metal phthalocyanines 3--5 were prepared by the reaction of 2 to get dinitrile derivative complexes by means of the corresponding anhydrous metal salts. Structures of the new compounds were characterized by IR, 1H NMR, 13C NMR, elemental analysis, and MS spectral data.

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Cite This Article

KILIÇASLAN, M. B., KANTEKİN, H. (2014). Synthesis and characterization of new metallophthalocyanines containing O4S2 mixed-donor substituted macrocyclic groups. Turkish Journal of Chemistry, Cilt: 38 - Sayı: 2, 317–327. https://ajindex.com/articles/184656

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References (30)

  1. Leznoff, C. C.; Lever, A. B. P. Phthalocyanines: Properties and Applications, vol. 4, VCH Publishers:
  2. New York, NY, USA, 1996.
  3. Kalkan, A.; Bayır, Z. A. Polyhedron 2006, 25, 39–42. Kula¸ c, D.; Bulut, M.; Altındal, A.; ¨ Ozkaya, A. R.; Salih, B.; Bekaro˘ glu, ¨ O. Polyhedron 2007, 26, 5432–5440.
  4. Akdemir, N.; Erdem, G. Synth. React. Inorg. Metal-Org. Nano-Metal Chem. 2005, 35, 819–824.
  5. McKeown, N. B. Phthalocyanine Materials, Synthesis, Structure and Function, Cambridge University Press:
  6. Boston, MA, USA, 1998.
  7. Kadish, K.; Smith, K. M.; Guilard, R. The Porphrin Handbook, vol. 15–20, Academic Press:
  8. San Diego, CA, USA, 200 C ¸ akmak, Y.; Koleman, S.; Duman, S.; Dede, Y.; Dolen, Y.; Kılı¸ c, B.; K¨ osterelli, Z.; Yıldırım, L. T.; Do˘ gan, A. L.; G¨ u¸ c, D. et al. Angew Chem. Int. Ed., 2011, 50, 11937–11941.
  9. Rosenthal, I. Photochem. Photobiol. 1991, 53, 859–870.
  10. Leznoff, C. C.; Lever, A. B. P. Phthalocyanines: Properties and Applications, vol. 3; VCH Publishers:
  11. New York NY, USA, 1993.
  12. De La Torre, G.; Vazquez, P.; Agullo-Lopez, F.; Torres, T. J. Mat. Chem. 1998, 8, 1671–1683.
  13. Yang, F.; Forrest, S. R. Am. Chem. Soc. Nano 2008, 2, 1022–1032.
  14. Forrest, S. R. Chem. Rev. 1997, 97, 1793–1896.
  15. Bilgin, A.; Ertem, B.; G¨ ok, Y. Polyhedron 2005, 24, 117–124.
  16. Leznoff, C. C.; Lever, A. B. P. Phthalocyanines: Properties and Applications, vol. 2; VCH Publishers:
  17. New York, NY, USA, 1993.
  18. Emmelius, M.; Pawlowski, G.; Vollmann, H. W. Angewandte Chemie International Edition 1989, 28, 1445–1471.
  19. Yılmaz, F.; ¨ Ozer, M.; Kani, I.; Bekaro˘ glu, ¨ O. Cataly. Lett. 2009, 130, 642–647.
  20. Yantasee, W.; Lin, Y. H.; Hongsirikarn, K.; Fryxell, G. E.; Addleman, R.; Timchalk, C. Environ. Health. Persp. 2007, 115, 1683–1690.
  21. Barile, F. A. Principles of Toxicology Testing; CRC Press:
  22. Boca Raton, FL, USA, 2008.
  23. Chaabane, R. F. Mat. Sci. Eng. C. 2006, 26, 551–554.
  24. Simon, J.; Andre, J. J. Molecular Semiconductors; Springer: Berlin, Germany, 1985. G¨ opel, W. Philos. Trans. R. Soc. Lond. 1995, 353, 333–354.
  25. Mack, J.; Stillman M. J. Coordination Chem. Rev. 2001, 219–221, 993–1032.
  26. Hayes, B. L. Microwave Synthesis: Chemistry at the Speed of Light; CEM Publishing: Matthews, NC, USA, 2002.
  27. Seven, O.; Dindar, B.; G¨ ultekin, B. Turk. J. Chem. 2009, 33, 123–134.
  28. Shaabani, A.; Moghaddam, R. M.; Maleki, A.; Rezayan, A. H. Dyes Pigments 2007, 74, 279–282.
  29. Wu, L.; Wang, Q.; Bian, Y.; Jiang, J.; Zhang, X. Langmuir 2010, 26, 7489–7497.
  30. Liu, H. W.; Chen, C. F.; Ai, M.; Gong, A. J.; Jiang, J.; Xi, F. Tetrahedro