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Journals / Turkish Journal of Chemistry / 2015 / Cilt: 39 - Sayı: 5

Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples

ZEID ABDULLAH ALOTHMAN
ERKAN YILMAZ
MOHAMED HABİLA
MUSTAFA SOYLAK
Pages
1038–1049
Publication Date
2015-12-04
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work.
📊
Key Findings & Data:Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined.
💡
Conclusion & Impact:The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:EDTA modified activated carbon cloth · metal · preconcentration

Abstract

The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work. It was used for preconcentration-separation of lead(II), cobalt(II), and nickel(II) at trace levels as an adsorbent. Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined. The preconcentration factor was 50. The detection limits for Pb(II), Co(II), and Ni(II) were 4.39, 0.99 and 0.91 $\mu $g L$^{-1}$, respectively. The adsorption capacity for Pb(II), Co(II), and Ni(II) ions was found as 11.0, 11.2, and 10.2 mg g$^{-1}$, respectively. The validation of the method was performed by the analysis of certified reference materials (SPS-WW2 wastewater and BCR-146R sewage sludge amended soil (industrial origin)). The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.

Özet

The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work. It was used for preconcentration-separation of lead(II), cobalt(II), and nickel(II) at trace levels as an adsorbent. Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined. The preconcentration factor was 50. The detection limits for Pb(II), Co(II), and Ni(II) were 4.39, 0.99 and 0.91 $\mu $g L$^{-1}$, respectively. The adsorption capacity for Pb(II), Co(II), and Ni(II) ions was found as 11.0, 11.2, and 10.2 mg g$^{-1}$, respectively. The validation of the method was performed by the analysis of certified reference materials (SPS-WW2 wastewater and BCR-146R sewage sludge amended soil (industrial origin)). The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.

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Cite This Article

ALOTHMAN, Z. A., YILMAZ, E., HABİLA, M., SOYLAK, M. (2015). Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples. Turkish Journal of Chemistry, Cilt: 39 - Sayı: 5, 1038–1049. https://ajindex.com/articles/184559

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