Journals / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 6

Optimization of sugarcane bagasse activation to achieve adsorbent with high affinity towards phenol

Pages
1720–1735
Publication Date
2018-12-01
DOI
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

All the evidence showed that the mechanisms involved in phenol adsorption were ion-exchange, electrostatic, and physical adsorption.

📌 3 Key Takeaways

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Objective & Hypothesis:Sugarcane bagasse as an agricultural/industrial biomass was converted into a low-cost activated carbon via an acid activation procedure under optimized conditions.
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Key Findings & Data:The optimized activated carbon produced under temperature of 550 \textdegree C and impregnation ratio of 1.5 showed a micromesoporous structure with specific surface area and pore volume of 972.5 m$^{2}$/g and 0.43 cm$^{3}$/g, respectively.
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Conclusion & Impact:All the evidence showed that the mechanisms involved in phenol adsorption were ion-exchange, electrostatic, and physical adsorption.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Phenol · adsorption · sugarcane bagasse

Abstract

Sugarcane bagasse as an agricultural/industrial biomass was converted into a low-cost activated carbon via an acid activation procedure under optimized conditions. Phosphoric acid was applied as a cost-effective and environmentally friendly chemical activator. The optimized activated carbon produced under temperature of 550 \textdegree C and impregnation ratio of 1.5 showed a micromesoporous structure with specific surface area and pore volume of 972.5 m$^{2}$/g and 0.43 cm$^{3}$/g, respectively. The adsorption capacity of the produced AC towards phenol was measured and, after only 30 min, the removal percentage reached over 95%. The greatest affinity towards phenol was obtained at pH of 4 justified by the pH$_{pzc}$ of the sorbent and speciation of phenol in solution. Under the intermediate concentration range, the Dubinin--Radushkevich isotherm was the best-fit model for describing the equilibrium data. The apparent adsorption energy was equal to 10.94 kJ/mol. All the evidence showed that the mechanisms involved in phenol adsorption were ion-exchange, electrostatic, and physical adsorption.

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Cite This Article

MOHTASHAMI, S., KOLUR, N. A., KAGHAZCHI, T., ASADI-KESHEH, R., SOLEIMANI, M. (2018). Optimization of sugarcane bagasse activation to achieve adsorbent with high affinity towards phenol. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 6, 1720–1735. https://ajindex.com/articles/184474

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