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AI Summary & Key Takeaways
AI Insight⚡ TL;DR(Too Long; Didn't Read)
These complexes have been identified as active catalysts in Suzuki-Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides.
📌 3 Key Takeaways
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Objective & Hypothesis:Öz The synthesis of 3 benzimidazole-based ionic Pd(II)-NHC complexes (NHC:$N$-heterocyclic carbene) is presented.
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Key Findings & Data:The structures of the complexes are as follows: [NHC-PdBr$_{3}$]$^{-}$[NHC]$^{+}$.
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Conclusion & Impact:These complexes have been identified as active catalysts in Suzuki-Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Anahtar Kelimeler Ionic palladium complex · $N$-heterocyclic carbene · C-C bond formation
Özet
Öz The synthesis of 3 benzimidazole-based ionic Pd(II)-NHC complexes (NHC:$N$-heterocyclic carbene) is presented. The structures of the complexes are as follows: [NHC-PdBr$_{3}$]$^{-}$[NHC]$^{+}$. The ionic palladium(II)-NHC complexes were synthesized in high yields and were fully characterized by nuclear magnetic resonance spectroscopy, X-ray diffraction, LC-MS/MS, and elemental analysis. These complexes have been identified as active catalysts in Suzuki-Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides.
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Cite This Article
YAŞAR, S., AKKOÇ, M., ÖZDEMİR, N., ÖZDEMİR, İ. (2019). Synthesis and catalytic activity of ionic palladium \textit{N}-heterocyclic carbene complexes. Turkish Journal of Chemistry, Cilt: 43 - Sayı: 6, 1622–1633. https://ajindex.com/articles/184197