Furthermore, the excimer emissions through intramolecular interactions in solution and in solid state were investigated by fluorescence spectroscopy and the theoretical calculations were performed in detail using DFT.
📌 3 Key Takeaways
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Objective & Hypothesis:Phenoxy- and naphthoxy-substituted bisphenol-bridged cyclic phosphazenes were synthesized in 2 steps and their thermal, photophysical, and electrochemical properties were investigated.
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Key Findings & Data:The structures of the cyclic phosphazene compounds were determined by ESI-MS mass spectrometry and 1H, 13C, and 31P NMR spectroscopies.
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Conclusion & Impact:Furthermore, the excimer emissions through intramolecular interactions in solution and in solid state were investigated by fluorescence spectroscopy and the theoretical calculations were performed in detail using DFT.
Phenoxy- and naphthoxy-substituted bisphenol-bridged cyclic phosphazenes were synthesized in 2 steps and their thermal, photophysical, and electrochemical properties were investigated. The structures of the cyclic phosphazene compounds were determined by ESI-MS mass spectrometry and 1H, 13C, and 31P NMR spectroscopies. The photophysical studies of phenoxy- and naphthoxy-substituted bridged cyclophosphazenes were investigated by means of absorption and fluorescence spectroscopies in different solvents. Thermal and electrochemical properties of the target compounds were also studied. Furthermore, the excimer emissions through intramolecular interactions in solution and in solid state were investigated by fluorescence spectroscopy and the theoretical calculations were performed in detail using DFT.
ÇOŞUT, B., AKSOY, B. T., TÜMAY, S. O., ŞENOCAK, A., YEŞİLOT, S. (2020). Synthesis, optical, and structural properties of bisphenol-bridged aromatic cyclic phosphazenes∗. Turkish Journal of Chemistry, Cilt: 44 - Sayı: 1, 48–63. https://ajindex.com/articles/184179
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