Material and Methods: Riedel-de Haen and Merck salts were used to investigate the solubility and phase equilibria of the Na2(H2PO2)2 -Ba(H2PO2)2-H2O ternary water–salt system at room temperature Results: It was determined that the Na 2 (H 2 PO 2 ) 2 -Ba(H 2 PO 2 ) 2 -H 2 O ternary water-salt system belongs to the simple eutonic system type and the compositions corresponding to the eutonic point, expressed as mass %, were 50.73, 0.53 and 48.74 (w/w %) for Na 2 (H 2 PO 2 ) 2 , Ba(H 2 PO 2 ) 2 and H 2 O, respectively
📌 3 Key Takeaways
🎯
Objective & Hypothesis:Objective: In this study, the solubility, density, conductivity and phase equilibria of the Na 2 (H 2 PO 2 ) 2 -Ba(H 2 PO 2 ) 2 -H 2 O ternary system located in the structure of the N a + , B a 2+ , ( H 2 P O 2 ) - // H 2 O quaternary reciprocal water-salt system were investigated using physicochemical analysis methods.
📊
Key Findings & Data:Objective: In this study, the solubility, density, conductivity and phase equilibria of the Na 2 (H 2 PO 2 ) 2 -Ba(H 2 PO 2 ) 2 -H 2 O ternary system located in the structure of the N a + , B a 2+ , ( H 2 P O 2 ) - // H 2 O quaternary reciprocal water-salt system were investigated using physicochemical analysis methods.
💡
Conclusion & Impact:Material and Methods: Riedel-de Haen and Merck salts were used to investigate the solubility and phase equilibria of the Na2(H2PO2)2 -Ba(H2PO2)2-H2O ternary water–salt system at room temperature Results: It was determined that the Na 2 (H 2 PO 2 ) 2 -Ba(H 2 PO 2 ) 2 -H 2 O ternary water-salt system belongs to the simple eutonic system type and the compositions corresponding to the eutonic point, expressed as mass %, were 50.73, 0.53 and 48.74 (w/w %) for Na 2 (H 2 PO 2 ) 2 , Ba(H 2 PO 2 ) 2 and H 2 O, respectively
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Na2(H2PO2)2-Ba(H2PO2)2-H2O Ternary Water-Salt System · Isothermic System · Density
Abstract
Objective: In this study, the solubility, density, conductivity and phase equilibria of the Na 2 (H 2 PO 2 ) 2 -Ba(H 2 PO 2 ) 2 -H 2 O ternary system located in the structure of the N a + , B a 2+ , ( H 2 P O 2 ) - // H 2 O quaternary reciprocal water-salt system were investigated using physicochemical analysis methods. Material and Methods: Riedel-de Haen and Merck salts were used to investigate the solubility and phase equilibria of the Na2(H2PO2)2 -Ba(H2PO2)2-H2O ternary water–salt system at room temperature Results: It was determined that the Na 2 (H 2 PO 2 ) 2 -Ba(H 2 PO 2 ) 2 -H 2 O ternary water-salt system belongs to the simple eutonic system type and the compositions corresponding to the eutonic point, expressed as mass %, were 50.73, 0.53 and 48.74 (w/w %) for Na 2 (H 2 PO 2 ) 2 , Ba(H 2 PO 2 ) 2 and H 2 O, respectively
Erge, H., Turan, H., Kul, A. R. (2016). Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Natural Science and Discovery, Cilt: 2 Sayı: 3, 56–61. https://doi.org/10.20863/nsd.277898
Özdek U. 2009. NaCl-Ba(H2PO2)2-H2O Üçlü Su-Tuz Sisteminin Oda Sıcaklığında İzotermik Yöntemle Çözünürlüğünün ve Faz Dengelerinin Araştırılması (unpublished master’s thesis). YYÜ, Fen Bilimleri Enstitüsü, Van.
Alişoğlu V. 1973. Potasyum ve Manganın Bromür ve Sülfatlarını İhtiva Eden Karşılıklı Su-Tuz Sisteminin Fizikokimyasal Araştırılması (doctoral thesis). Bakü.
Erge H, Adıgüzel V, Alişoğlu V. Study of the solubility İn Na–Ba–Cl–H2O, Na–Ba–H2PO2–H2O, Na–Cl–H2PO2–H2O, and Ba–Cl–H2PO2–H2O ternaries, and İn Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary system at 0 ◦C. Elsevier. 2013; 344:13–18.
Aliev VA, Velieva SM, 1985. Sodium chloride manganese-hypophosphate-water system at 20-degrees-c. Zr. Neorg. Khim. 1985; 30:798-800.
Adıgüzel V, Erge H, Alişoğlu V, Necefoğlu H. Study of the solubility, viscosity and density in Na+, Zn2+/Cl H2O, Na+ Zn2+ (H2PO2) H2O, Na+, Cl/(H2PO2) H2O, and Zn2+, Cl/(H2PO2) H2O ternary systems, and in Na+, Zn2+/Cl, (H2PO2) //H2O reciprocal quaternary system at 273.15 K. Elsevier. 2014; 75:35–44.
Erge H, Adıgüzel V, Kul AR, Karatay O, Yenigün A. BaCl2- Ba(H2PO2)2- H2O üçlü sisteminin 00C ve +250C'de çözünürlüğünün ve faz dengelerinin araştırılması. 25. Ulusal Kimya Kongresi, 27 Haziran-2 Temmuz 2011, Erzurum, Türkiye.
Gülensoy H. Kompleksometrinin esasları ve kompleksometrik titrasyonlar kitabı, Türkiye Kimya Derneği Yayınları. 2003; 255: 126-131.
Erge H, Adıgüzel V, Kul AR, Alişoğlu V. Na2Cl2/BaCl2/ Ba(H2PO2)2/ H2O sisteminin fizikokimyasal analizi. Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2008; 1: 33-36.
Adıgüzel V, Erge H, Alişoğlu V, Necefoğlu H. Study of the solubility, viscosity and density in Na+, Zn2+/Cl H2O, Na+ Zn2+ (H2PO2) H2O, Na+, Cl/(H2PO2) H2O, and Zn2+, Cl/(H2PO2) H2O ternary systems, and in Na+, Zn2+/Cl, (H2PO2) //H2O reciprocal quaternary system at 273.15 K. Elsevier. 2014; 75:35–44.