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Journals / Sakarya University Journal of Science / 2026 / Volume: 22 Issue: 3

Hydrothermal synthesis and characterization of one dimensional (1D) 5-nitroisophthalate Cu(II) and Cd(II)-coordination polymers

Bir boyutlu (1D) 5-nitroisoftalat Cu(II) ve Cd(II)-koordinasyon polimerlerinin hidrotermal sentezi ve karakterizasyonu

Mürsel Arıcı
Pages
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Publication Date
2018-06-01
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

X-ray analysis results showed that 5-nip acted as a bridging ligand in both complexes and 1D chains of the complexes occurred.

📌 3 Key Takeaways

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Objective & Hypothesis:Two new one dimensional (1D) Cu(II) and Cd(II)-coordination polymers, namely {[Cu(µ-5-nip)(1-meim) 2 (H 2 O)]∙2H 2 O} n ( 1 ) and {[Cd(µ 3 -5-nip)(1-meim)(H 2 O)]∙H 2 O} n ( 2 ), (5-nip= 5-nitroisophthalate, 1-meim= 1-methylimidazole) were synthesized by hydrothermal method with 5-nitroisophthalic acid and 1-methylimidazole.
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Key Findings & Data:X-ray analysis results showed that 5-nip acted as a bridging ligand in both complexes and 1D chains of the complexes occurred.
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Conclusion & Impact:Moreover, thermal, photoluminescence and optic properties were studied in detail.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:5-nitroisophthalate ligand · coordination polymer · hydrothermal synthesis

Abstract

Two new one dimensional (1D) Cu(II) and Cd(II)-coordination polymers, namely {[Cu(µ-5-nip)(1-meim) 2 (H 2 O)]∙2H 2 O} n ( 1 ) and {[Cd(µ 3 -5-nip)(1-meim)(H 2 O)]∙H 2 O} n ( 2 ), (5-nip= 5-nitroisophthalate, 1-meim= 1-methylimidazole) were synthesized by hydrothermal method with 5-nitroisophthalic acid and 1-methylimidazole. They were characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. X-ray analysis results showed that 5-nip acted as a bridging ligand in both complexes and 1D chains of the complexes occurred. In the complexes, 5-nip ligand displayed two different coordination modes. 2D and 3D supramolecular structures of the complexes were generated through O−H···O hydrogen bonding and π··· π interactions. Moreover, thermal, photoluminescence and optic properties were studied in detail.

Özet

5-nitroisoftalik asit (5-nipH 2 ) ve 1-metilimidazol (1-meim) ligantları ile iki yeni 1D Cu(II) ve Cd(II) koordinasyon polimeri, {[Cu(µ-5-nip)(1-meim) 2 (H 2 O)]∙2H 2 O} n ( 1 ) ve {[Cd(µ 3 -5-nip)(1-meim)(H 2 O)]∙H 2 O} n ( 2 ) hidrotermal yöntemle sentezlendi ve yapıları elementel analiz, IR spektroskopisi ve tek kristal X-ışınları kırınım yöntemiyle aydınlatıldı. X-ışınları analiz sonuçlarına göre 5-nitroisoftalat ligantı her iki komplekste de köprü ligantı olarak hareket etmiş ve komplekslerin bir boyutlu yapısı meydana gelmiştir. Her iki komplekste de 5-nip ligantının farklı bağlanma biçimi sergilediği tespit edilmiştir. Komplekslerin 2D ve 3D supramoleküler yapıları O−H···O hidrojen bağları ve π···π etkileşimleri ile oluşmuştur. 2 kompleksinde, D4 su kümesi bulunmaktadır. Ayrıca, komplekslerin termal, fotolüminesans ve optik özellikleri de detaylı şekilde çalışılmıştır .

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Cite This Article

Arıcı, M. (2018). Hydrothermal synthesis and characterization of one dimensional (1D) 5-nitroisophthalate Cu(II) and Cd(II)-coordination polymers. Sakarya University Journal of Science, Volume: 22 Issue: 3. https://doi.org/10.16984/saufenbilder.325582

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