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Journals / Selçuk Üniversitesi Fen Fakültesi Fen Dergisi / 2026 / Volume: 45 Issue: 1

Conversion of CO2 to Organic Products in the Presence of Metal Chlorides with Substituted Perimidine Ligants

Sübstitüe Perimidin Ligantları ile Metal Klorürlerin Varlığında CO2’in Organik Ürünlere Dönüşümü

Emine Aytar(Harran Üniversitesi)0000-0001-7572-8088
Veli Kasım(Harran Üniversitesi)
Pages
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Publication Date
2019-04-30
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The in situ system of L 2 ligant bearing the quinoline-2-carboxaldehyde and ZnCI 2 showed superior activity (90.4% yield and 99.4% selectivity).

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, substituted perimidine ligant systems ( L 1 and L 2 ) derived from 2-pyridinecarboxaldehyde/quinoline-2-carboxaldehyde and 1,8-diaminonaphthalene has been synthesized.
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Key Findings & Data:The structures of these compounds were characterized by means of NMR ( 1 H and 13 C) spectra, FT-IR spectra, UV-Vis spectra, mass spectra, melting point measurements, as well as elemental analysis (C, H, N).
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Conclusion & Impact:The in situ system of L 2 ligant bearing the quinoline-2-carboxaldehyde and ZnCI 2 showed superior activity (90.4% yield and 99.4% selectivity).
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Catalysts · CO2 fixation · Epoxide

Abstract

In this study, substituted perimidine ligant systems ( L 1 and L 2 ) derived from 2-pyridinecarboxaldehyde/quinoline-2-carboxaldehyde and 1,8-diaminonaphthalene has been synthesized. The structures of these compounds were characterized by means of NMR ( 1 H and 13 C) spectra, FT-IR spectra, UV-Vis spectra, mass spectra, melting point measurements, as well as elemental analysis (C, H, N). The obtained and fully chatacterized compounds ( L 1 and L 2 ) and metal salts (ZnCI 2 ve CuCI 2 ) were used together as insutu catalytic system and investigated their activity. The in situ system of L 2 ligant bearing the quinoline-2-carboxaldehyde and ZnCI 2 showed superior activity (90.4% yield and 99.4% selectivity).

Özet

Bu çalışmada 2-piridinkarboksaldehit/Kinolin-2-karboksaldehit ve 1,8-diaminonaftalenden yola çıkılarak sübstitüe perimidin ligant sistemleri ( L 1 ve L 2 ) sentezlendi. Bu bileşiklerin yapıları 1 H ve 13 C-NMR Spektroskopisi, FT-IR, UV Spektroskopisi, Kütle Spektroskopisi, Elementel Analiz ve Erime Noktası Ölçümü yöntemleri ile aydınlatıldı. Elde edilen bileşikler ( L 1 ve L 2 ) ve metal tuzları (ZnCI 2 ve CuCI 2 ) birlikte kullanılarak insutu sistemi ile CO 2 ’in halkalı karbonatlara dönüşüm reaksiyolarında katalizör olarak katalitik etkileri araştırıldı. Kinolin-2-karboksaldehit sübstitüenti içeren L 2 ligantı ve ZnCI 2 ’ün oluşturduğu in situ sistemi %90.4 verim ve %99.4 seçicilikle en aktif katalizör sistemi olarak tespit edildi.

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Cite This Article

Aytar, E., Kasım, V. (2019). Conversion of CO2 to Organic Products in the Presence of Metal Chlorides with Substituted Perimidine Ligants. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, Volume: 45 Issue: 1. https://ajindex.com/articles/1542501

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