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Journals / Journal of the Turkish Chemical Society Section A: Chemistry / 2026 / Volume: 4 Issue: 3

ALLYLATION OF ARYL GRIGNARD REAGENTS IN THE PRESENCE OF TRANSITION METAL CATALYSIS AND ORGANIC CATALYSIS

Melike Kalkan(ANKARA ÜNİVERSİTESİ, FEN FAKÜLTESİ, KİMYA BÖLÜMÜ)
Pages
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Publication Date
2017-08-18
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

However, donor cosolvents resulted in decrease in the yield and change of the regioselectivity.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The allylation yield and regioselectivity of phenyl Grignard reagent in THF was investigated in the presence of complexed transition metals and also uncomplexed or complexed transition metal salts.
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Key Findings & Data:Additionally, the effect of Lewis acids and Lewis baseson the yield and the regioselectivity of the allylic arylation was also observed.
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Conclusion & Impact:However, donor cosolvents resulted in decrease in the yield and change of the regioselectivity.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Allylic arylation · Transition metal salts/complexes · Organic catalyst

Abstract

The allylation yield and regioselectivity of phenyl Grignard reagent in THF was investigated in the presence of complexed transition metals and also uncomplexed or complexed transition metal salts. Additionally, the effect of Lewis acids and Lewis baseson the yield and the regioselectivity of the allylic arylation was also observed. Neither P-containing ligands for transition metal complexes, nor transition metal salts did make a difference on the yield and a : g product ratio and gave the is a -product as the main product. However, donor cosolvents resulted in decrease in the yield and change of the regioselectivity.

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Cite This Article

Kalkan, M. (2017). ALLYLATION OF ARYL GRIGNARD REAGENTS IN THE PRESENCE OF TRANSITION METAL CATALYSIS AND ORGANIC CATALYSIS. Journal of the Turkish Chemical Society Section A: Chemistry, Volume: 4 Issue: 3. https://doi.org/10.18596/jotcsa.318333

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