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Journals / Journal of the Turkish Chemical Society Section A: Chemistry / 2018 / Volume: 5 Issue: 3

Syntheses and Spectroscopic Characterization on New [O–3-phenyl-1-propyl-(4-methoxyphenyl)dithiophosphonato] Ni(II), Cd(II) and Hg(II) Complexes

Ertuğrul Gazi Sağlam(FACULTY OF SCIENCE AND LETTERS)0000-0002-7719-3934
Ahmet Ebinç(INSTITUTE OF SCIENCE)
Pages
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Publication Date
2018-09-01
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The magnetic susceptibility of the pyridine nickel complex was measured to confirm the hybridization patterns and the geometry.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, four new dithiophosphonic acid complexes, namely, trans- bis-[ O– 3-phenyl-1-prop yl- (4-methoxyphenyl) dithiophosphonato ] nickel (II), {Bis-pyridine-bis-(O–3–phenylpropyl (4-methoxyphenyl) dithiophosphonato ]} nickel (II), bis-{bis-( O– 3-phenyl-1-prop yl- (4-methoxyphenyl) dithiophosphonato ] cadmium (II)} and bis - { bis - ( O– 3 - phenyl – 1 - prop yl- ( 4-methoxyphenyl ) dithiophosphonato ] mercury (II)} were syntheszed.
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Key Findings & Data:The complexes were of the general structure [Ni(L) 2 ] and [M(µ-L) 2 (L) 2 ], M= Cd 2+ and Hg 2+ .
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Conclusion & Impact:The magnetic susceptibility of the pyridine nickel complex was measured to confirm the hybridization patterns and the geometry.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Dithiophosphonic acid · Dithiophosphonato metal complexes · Lawesson Reagent

Abstract

In this study, four new dithiophosphonic acid complexes, namely, trans- bis-[ O– 3-phenyl-1-prop yl- (4-methoxyphenyl) dithiophosphonato ] nickel (II), {Bis-pyridine-bis-(O–3–phenylpropyl (4-methoxyphenyl) dithiophosphonato ]} nickel (II), bis-{bis-( O– 3-phenyl-1-prop yl- (4-methoxyphenyl) dithiophosphonato ] cadmium (II)} and bis - { bis - ( O– 3 - phenyl – 1 - prop yl- ( 4-methoxyphenyl ) dithiophosphonato ] mercury (II)} were syntheszed. The complexes were of the general structure [Ni(L) 2 ] and [M(µ-L) 2 (L) 2 ], M= Cd 2+ and Hg 2+ . The nickel(II) complex was capable of coordinating two moles of pyridine per mole as many four-coordinated nickel(II) complex do leading to the six-coordinated complex, [Ni(L) 2 (Py) 2 ]. All the compounds were characterized by elemental analysis; MS; FTIR and Raman spectroscopies. The [ Ni( L ) 2 ], [Cd(µ-L) 2 (L) 2 ] and [Hg(µ-L) 2 (L) 2 ] were also investigated by 1 H-, 13 C- and 31 P-NMR. The magnetic susceptibility of the pyridine nickel complex was measured to confirm the hybridization patterns and the geometry.

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Cite This Article

Sağlam, E. G., Ebinç, A. (2018). Syntheses and Spectroscopic Characterization on New [O–3-phenyl-1-propyl-(4-methoxyphenyl)dithiophosphonato] Ni(II), Cd(II) and Hg(II) Complexes. Journal of the Turkish Chemical Society Section A: Chemistry, Volume: 5 Issue: 3. https://doi.org/10.18596/jotcsa.468027

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