Journals / Eurasian Journal of Science Engineering and Technology / 2026 / Volume: 7 Issue: 2

Efficient preconcentration and determination of dye molecules from aqueous solutions via solid phase extraction using malus domestica leave based bioadsorbent

Pages
—
Publication Date
2026-07-30
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Owing to its simplicity, low cost, and high extraction efficiency, the developed technique offers a promising analytical approach for the preconcentration and spectrophotometric determination of azo dyes in aquatic sample monitoring applications.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The extensive use of azo dyes in industrial processes poses a significant threat to aquatic environments due to their toxicity and persistence.
📊
Key Findings & Data:In this study, Malus domestica leaves were evaluated as an environmentally friendly, low-cost, and natural bio-adsorbent for the separation, preconcentration, and determination of the azo dye Drimaren Red CL-5B using a column solid-phase extraction (SPE) method.
💡
Conclusion & Impact:Owing to its simplicity, low cost, and high extraction efficiency, the developed technique offers a promising analytical approach for the preconcentration and spectrophotometric determination of azo dyes in aquatic sample monitoring applications.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Solid phase extraction · Bio-adsorbent · Malus domestica leaves

Abstract

The extensive use of azo dyes in industrial processes poses a significant threat to aquatic environments due to their toxicity and persistence. In this study, Malus domestica leaves were evaluated as an environmentally friendly, low-cost, and natural bio-adsorbent for the separation, preconcentration, and determination of the azo dye Drimaren Red CL-5B using a column solid-phase extraction (SPE) method. Parameters affecting the extraction efficiency, such as solution pH, initial dye concentration, sample volume, eluent type, and the interfering ions and dyes were optimized. Quantitative dye recovery (up to 98%) was achieved at pH 2. Surface charges resulted a strong electrostatic interaction between the bio-adsorbent surface and dye molecules above the pHₚzc value of 3.35. The adsorption tendency of dye on the adsorbent surface was linear in the concentration range of 5–35 ppm, while the saturation of active adsorption sites was observed after this level. Dye molecules effectively desorbed from surface by using 5 mL of 1 M HCl in ethanol. High selectivity of the method was demonstrated in the presence of common inorganic ions and co-existing dyes. Owing to its simplicity, low cost, and high extraction efficiency, the developed technique offers a promising analytical approach for the preconcentration and spectrophotometric determination of azo dyes in aquatic sample monitoring applications.

🔖

Cite This Article

Sürme, Y., Kaya, Ö. (2026). Efficient preconcentration and determination of dye molecules from aqueous solutions via solid phase extraction using malus domestica leave based bioadsorbent. Eurasian Journal of Science Engineering and Technology, Volume: 7 Issue: 2. https://doi.org/10.55696/ejset.1917426

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (13)

  1. S. Dutta, B. Gupta, S. K. Srivastava and A. K. Gupta, "Recent advances on the removal of dyes from wastewater using various adsorbents: A critical review," Materials Advances, 2, 4497-4531, 2021. https://doi.org/10.1039/d1ma00354b
  2. E. Pagalan Jr, M. Sebron, S. Gomez, S. J. Salva, R. Ampusta, A. J. Macarayo, C. Joyno, A. Ido and R. Arazo, "Activated carbon from spent coffee grounds as an adsorbent for treatment of water contaminated by aniline yellow dye," Industrial Crops and Products, 145, 111953, 2020. https://doi.org/10.1016/j.indcrop.2019.111953
  3. M. W. Zhang, K. Y. A. Lin, C. F. Huang and S. Tong, "Enhanced degradation of toxic azo dye, amaranth, in water using Oxone catalyzed by MIL-101-NH2 under visible light irradiation," Separation and Purification Technology, 227, 115632, 2019. https://doi.org/10.1016/j.seppur.2019.05.074
  4. P. Barciela, A. Perez-Vazquez and M. A. Prieto, “Azo dyes in the food industry: Features, classification, toxicity, alternatives, and regulation,” Food and Chemical Toxicology, 178, 113935, 1–12, 2023. https://doi.org/10.1016/j.fct.2023.113935
  5. V. Vaiano and I. D. Marco, “Removal of azo dyes from wastewater through heterogeneous photocatalysis and supercritical water oxidation,” Separations, 10, 230, 1–24, 2023. https://doi.org/10.3390/separations10040230
  6. A. K. D. Alsukaibi, “Various approaches for the detoxification of toxic dyes in wastewater,” Processes, 10, 1968, 1-27, 2022. https://doi.org/10.3390/pr10101968
  7. S. Benkhaya, S. M'rabet, and A. El Harf, “Classifications, properties, recent synthesis and applications of azo dyes,” Heliyon, 6, E03271, 1-26, 2020. https://doi.org/10.1016/j.heliyon.2020.e03271
  8. D. Özkır, “The Electrochemical Variation of a Kind of Protein Staining and Food Dye as a New Corrosion Inhibitor on Mild Steel in Acidic Medium,” International Journal of Electrochemistry, 1, 5743952, 1–11, 2019. https://doi.org/10.1155/2019/5743952
  9. V. Katheresan, J. Kansedo, and S. Y. Lau, "Efficiency of various recent wastewater dye removal methods: A review," Journal of Environmental Chemical Engineering, 6(4), 4676-4697, 2018. https://doi.org/10.1016/j.jece.2018.06.060.
  10. Sürme Y, Kahve Yıldırım G. Ultrasound-assisted d-SPE of Fast Green FCF on chitin bio-adsorbent prior to spectrophotometric determination,” Eurasian Journal of Science Engineering and Technology, 6, 89–94. 2025. https://doi.org/10.55696/ejset.1732523.
  11. E. Rápó, and S. Tonk, "Factors affecting synthetic dye adsorption; desorption studies: A review of results from the last five years (2017–2021)," Molecules, 26 (17), 5419-5450, 2021. https://doi.org/10.3390/molecules26175419.
  12. Q. Wang, Y. Wang, and L. Chen, “A green composite hydrogel based on cellulose and clay as efficient absorbent of colored organic effluent,” Carbohydr. Polym., 210, 314–321, 2019. https://doi.org/10.1016/j.carbpol.2019.01.080.
  13. A. T. Bişgin, Y. Sürme, M. Uçan and İ. Narin, “Separation, preconcentration and spectrophotometric determination of rhodamine b in industrial, cosmetic and water samples by cloud point and solid phase extraction,” J Anal Chem., 73, 452–458, 2018. https://doi.org/10.1134/S1061934818050040.