Journals / Academic Platform Journal of Engineering and Smart Systems / 2026 / Volume: 6 Issue: 1

Production and Characterization of α-MnO2/Graphene/CNT Nanocomposite Electrodes for Li-O2 Batteries

Li-O2 Piller için α-MnO2/Grafen/KNT Nanokompozit Elektrotlarının Üretimi ve Karakterizasyonu

Miraç Alaf(BİLECİK ŞEYH EDEBALİ ÜNİVERSİTESİ)
Ubeyd Toçoğlu(SAKARYA ÜNİVERSİTESİ)
Hatem Akbulut(SAKARYA ÜNİVERSİTESİ)
Pages
—
Publication Date
2018-01-31
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The electrochemical characterization was carried out in ECC-air test cells.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, of α-MnO 2 /Graphene/CNT nanocomposites were produced and characterized as electrode for Li-O 2 batteries.
📊
Key Findings & Data:Graphene was produced with Hummer method and carbon nano tubes were added to graphene as spacers between layers. α - MnO 2 nanorods were synthesized and α-MnO 2 /Graphene/CNT nanocomposites were fabricated by vacuum filtration technique as a paper electrode. α - MnO 2 nanorods were added to composite at three different rates and electrodes were characterized by FESEM and XRD.
💡
Conclusion & Impact:The electrochemical characterization was carried out in ECC-air test cells.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Graphene · α-MnO2 nanorods · composite

Abstract

In this study, of α-MnO 2 /Graphene/CNT nanocomposites were produced and characterized as electrode for Li-O 2 batteries. Graphene was produced with Hummer method and carbon nano tubes were added to graphene as spacers between layers. α - MnO 2 nanorods were synthesized and α-MnO 2 /Graphene/CNT nanocomposites were fabricated by vacuum filtration technique as a paper electrode. α - MnO 2 nanorods were added to composite at three different rates and electrodes were characterized by FESEM and XRD. The electrochemical characterization was carried out in ECC-air test cells.

Özet

Bu çalışmada Li-O 2 pilleri için elektrot malzemesi α - MnO 2 /Grafen/KNT nanokompozitleri üretilmiş ve karakterize edilmiştir. Grafen Hummer metodu ile üretilmiş ve tabakalar arası boşluk yapıcı olarak karbon nano tüp ilavesi yapılmıştır. α - MnO 2 nano çubuklar sentezlenerek α - MnO 2 /Grafen/KNT nanokompozitleri vakum filtrasyon yöntemi ile kağıt halinde elektrot olarak üretilmiştir. Üç farklı oranda ilave edilen α - MnO 2 nano çubukları ile elektrotların yapısal karakterizasyonu FESEM, XRD kullanılarak ve elektrokimyasal karakterizasyonu da ECC-hava test hücreleri ile yapılmıştır.

🔖

Cite This Article

Alaf, M., Toçoğlu, U., Akbulut, H. (2018). Production and Characterization of α-MnO2/Graphene/CNT Nanocomposite Electrodes for Li-O2 Batteries. Academic Platform Journal of Engineering and Smart Systems, Volume: 6 Issue: 1. https://doi.org/10.21541/apjes.349419

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (14)

  1. D. Capsoni, M. Bini, S. Ferrari, E. Quartarone, and P. Mustarelli, “Recent advances in the development of Li-air batteries,” J. Power Sources, vol. 220, pp. 253–263, 2012.
  2. N. Nitta, F. Wu, J. T. Lee, and G. Yushin, “Li-ion battery materials: Present and future,” Mater. Today, vol. 18, no. 5, pp. 252–264, 2015.
  3. M. J. Song and M. W. Shin, “Fabrication and characterization of carbon nanofiber@mesoporous carbon core-shell composite for the Li-air battery,” Appl. Surf. Sci., vol. 320, pp. 435–440, 2014.
  4. A. Kraytsberg and Y. Ein-Eli, “Review on Li-air batteries - Opportunities, limitations and perspective,” J. Power Sources, vol. 196, no. 3, pp. 886–893, 2011.
  5. J. Liu, R. Younesi, T. Gustafsson, K. Edström, and J. Zhu, “Pt/α-MnO2 nanotube: A highly active electrocatalyst for Li-O2 battery,” Nano Energy, vol. 10, pp. 19–27, 2014.
  6. W. Xiao, Z. Wang, H. Guo, X. Li, J. Wang, S. Huang, and L. Gan, “Fe2O3 particles enwrapped by graphene with excellent cyclability and rate capability as anode materials for lithium ion batteries,” Appl. Surf. Sci., vol. 266, pp. 148–154, 2013.
  7. Y. Wen, C. Huang, L. Wang, and D. Hulicova-Jurcakova, “Heteroatom-doped graphene for electrochemical energy storage,” Chinese Sci. Bull., vol. 59, no. 18, pp. 2102–2121, 2014.
  8. G. Gnana kumar, Z. Awan, K. Suk Nahm, and J. Stanley Xavier, “Nanotubular MnO2/graphene oxide composites for the application of open air-breathing cathode microbial fuel cells,” Biosens. Bioelectron., vol. 53, pp. 528–534, 2014.
  9. H. Zhou, X. Yang, J. Lv, Q. Dang, L. Kang, Z. Lei, Z. Yang, Z. Hao, and Z. H. Liu, “Graphene/MnO2 hybrid film with high capacitive performance,” Electrochim. Acta, vol. 154, pp. 300–307, 2015.
  10. Y. Wimalasiri and L. Zou, “Carbon nanotube/graphene composite for enhanced capacitive deionization performance,” Carbon N. Y., vol. 59, pp. 464–471, 2013.
  11. L. Zhang, F. Zhang, G. Huang, J. Wang, X. Du, Y. Qin, and L. Wang, “Freestanding MnO2@carbon papers air electrodes for rechargeable Li-O2 batteries,” J. Power Sources, vol. 261, pp. 311–316, 2014.
  12. R. S. Kalubarme, C. H. Ahn, and C. J. Park, “Electrochemical characteristics of graphene/manganese oxide composite catalyst for Li-oxygen rechargeable batteries,” Scr. Mater., vol. 68, no. 8, pp. 619–622, 2013.
  13. D. A. Tompsett, S. C. Parker, and M. S. Islam, “Surface properties of α-MnO 2: relevance to catalytic and supercapacitor behaviour,” J. Mater. Chem. A, vol. 2, no. 37, pp. 15509–15518, 2014.
  14. D. A. Tompsett, S. C. Parker, and M. S. Islam, “Surface properties of α-MnO 2: relevance to catalytic and supercapacitor behaviour,” J. Mater. Chem. A, vol. 2, no. 37, pp. 15509–15518, 2014.