Journals / Journal of Thermal Engineering / 2026 / Volume: 9 Issue: 4

Freeze-drying kinetics and diffusion modeling of hawthorn

Khaled Ali Hagıg(Department of Energy Systems Engineering, Karabük University, Karabük, 78050, Türkiye)0000-0001-5359-5608
Bahadır Acar(Department of Energy Systems Engineering, Karabük University, Karabük, 78050, Türkiye)0000-0001-8540-7368
Edip Taşkesen(Department of Energy Systems Engineering, Karabük University, Karabük, 78050, Türkiye)0000-0002-3052-9883
Mehmet Özkaymak(Department of Energy Systems Engineering, Karabük University, Karabük, 78050, Türkiye)0000-0002-4575-8988
Pages
—
Publication Date
2023-08-04
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Results show that the root mean square error was 0.011063, the highest determination coefficient was 0.9987, the least chi-square was 1.959x10-4, and the effective diffusivity was 2.33742x10-10m2/s.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:This study tests freeze-drying (FD) technology (Scanvac Coolsafe model, Labogene brand) to preserve hawthorn fruit.
📊
Key Findings & Data:First, 100g hawthorn slices were frozen and then freeze-dried.
💡
Conclusion & Impact:Results show that the root mean square error was 0.011063, the highest determination coefficient was 0.9987, the least chi-square was 1.959x10-4, and the effective diffusivity was 2.33742x10-10m2/s.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Drying Kinetics · Freeze-drying · Kinetic Drying Model

Abstract

This study tests freeze-drying (FD) technology (Scanvac Coolsafe model, Labogene brand) to preserve hawthorn fruit. First, 100g hawthorn slices were frozen and then freeze-dried. Kinet-ic models were applied, and hawthorn’s moisture ratio and weight loss were noted after every two hours during the 14-hour freeze-drying process. Matlab program is used to perform a to-tal of eight kinetic drying models. Results show that the root mean square error was 0.011063, the highest determination coefficient was 0.9987, the least chi-square was 1.959x10-4, and the effective diffusivity was 2.33742x10-10m2/s. The diffusion approach is the best among the eight models.

🔖

Cite This Article

Hagıg, K. A., Acar, B., Taşkesen, E., Özkaymak, M. (2023). Freeze-drying kinetics and diffusion modeling of hawthorn. Journal of Thermal Engineering, Volume: 9 Issue: 4. https://doi.org/10.18186/thermal.1327094

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (25)

  1. References [1] Kowalski R, Kowalski G, Kalwa K, Sujka M. Essential oil composition of hawthorn crataegus monogyna inflorescence. Chem Nat Compd 2018;54:995997. [CrossRef] [2] Ozcan M, Haciseferogulları H, Marakoglu T, Arslan D. Hawthorn (Crataegus spp.) fruit: some physical and chemical properties. J Food Eng 2005;69:409413. [CrossRef]
  2. Zhang Z, Chang Q, Zhu M, Huang Y, Ho W-K-K, Chen Z-Y. Characterization of Antioxidants Present in Hawthorn Fruits. J. Nutr. Biochem 2001;12:144152. [CrossRef]
  3. Ammon H-P-T, Handel M. Crataegus, toxicology and pharmacology. Part II: Pharmacodynamics. Planta Med 1981;43:209239. [CrossRef]
  4. Zhang Z, Ho W-K-K, Huang Y, Chen Z-Y. Hypocholesterolemic activity of hawthorn fruit is mediated by regulation of cholesterol-7α-hydroxylase and acyl CoA: Cholesterol acyltransferase. Food Res Int 2002;35:885891. [CrossRef] [6] Marques L-G, Freire J-T. Analysis of freeze-drying of tropical fruits. Dry Technol 2005;23:21692184. [CrossRef]
  5. Kırmacı V, Usta H, Menlik T. An experimental study on freeze-drying behavior of strawberries. Dry Technol 2008;26:15701576. [CrossRef]
  6. Moraga G, Talens P, Moraga M-J, Martinez N-N. Implication of water activity and glass transition on the mechanical and optical properties of freeze-dried apple and banana slices. J Food Eng 2011;106;212219. [CrossRef]
  7. Kopjar M, Pilizota V, Hribar J, Simcic M, Zlatic E, Tiban N-N. Influence of trehalose addition and storage conditions on the quality of strawberry cream filling. J Food Eng 2011;106:212219.
  8. Zaichick V, Zaichick S. A search for losses of chemical elements during freeze-drying of biological materials. J Rad Nuc Chem 1997;218:249253. [CrossRef]
  9. Oetjen G, Haseley P. Freeze-drying. Weinheim: Wiley-VCH Press: 2004. [CrossRef]
  10. Kochs M, Körber C, Nunner B, Heschel I. The influence of the freezing process on vapour transport during sublimation in vacuum-freeze-drying. Int J Heat Mass Transf 1991;34:23952408. [CrossRef]
  11. Acar B, Sadikoglu H, Ozkaymak M. Freeze Drying of Saffron (Crocus Sativus L.). Dry. Technol 2011;29:16221627. [CrossRef]
  12. Liapis A-I, Pikal M-J, Bruttini R. Research and development needs and opportunities in freeze drying. Dry Technol 1996;14:12651300. [CrossRef] [15] Sadikoglu H, Ozdemir M, Seker M. Freeze-drying of pharmaceutical products: Research and development needs. Dry Technol 2006;24:849861. [CrossRef]
  13. Sadikoglu H, Liapis A-I. Mathematical modelling of the primary and secondary drying stages of bulk solution freeze-drying in trays: parameter estimation and model discrimination by comparison of theoretical results with experimental data. Dry Technol 1997;15:791810. [CrossRef] [17] Acar B, Sadikoglu H, Doymaz I. Freeze-drying kinetics and diffusion modeling of saffron (crocus sativus L.). J Food Process Preserv 2015:29;142149. [CrossRef]
  14. Ishwaya S-P, Anandharamakrishnan C. Spray-freeze-drying approach for soluble coffee processing and its effect on quality characteristics. J Food Eng 2015;149:171180. [CrossRef]
  15. Wang J, Li Y-Z, Chen R-R, Bao J-Y, Yang G-M. Comparison of volatiles of banana powder dehydrated by vacuum belt drying, freeze-drying and air-drying. Food Chem 2007;104:15161521. [CrossRef]
  16. Jiang H, Zhang M, Mujumdar A-S. Physico-chemical changes during different Stages of MFD/FD banana chips. J Food Eng 2010;101:140145. [CrossRef]
  17. Khampakool A, Soisungwan S, Park S-H. Potential application of infrared assisted freeze drying (IRAFD) for banana snacks: Drying kinetics, energy consumption, and texture. Food Sci Tech 2019;99:355363. [CrossRef]
  18. Maskan M. Drying, shrinkage and rehydration characteristics of kiwifruits during hot air and microwave drying. J Food Eng 2001;48:177182. [CrossRef] [23] Maskan M. Microwave/air and microwave finish drying of banana. J Food Eng 2000;44:7178. [CrossRef]
  19. Sadikoglu H, Liapis A-I, Grosser O-K. Optimal control of the primary and secondary drying stages of bulk solution freeze drying in trays. Dry Technol 1998;16:399431. [CrossRef]
  20. Menges H-O, Ertekin C. Mathematical modeling of thin layer drying of golden apples. J Food Eng 2006;77:119125. [CrossRef] [26] Rayaguru K, Routray W, Mohanty S-N. Mathematical modeling and quality parameters of air-dried betel leaf (piper betle L.). J Food Process Preserv 2011;35:394401. [CrossRef]
  21. Sadikoglu H, Ozdemir M, Seker M. Optimal control of the primary drying stage of freeze drying of solutions in vials using variational calculus. Dry Technol 2003;21:13071331. [CrossRef]
  22. Senadeera W, Bhandari B-R, Young G, Wijesinghe B. Influence of shapes of selected vegetable materials on drying kinetics during fluidized bed drying. J Food Eng 2003;58:277283. [CrossRef]
  23. Souret F-F, Weathers P-J. The growth of saffron (Crocus sativus L.) in aeroponics and hydroponics. J Herbs Spices Med Plants 2000;7:2535. [CrossRef]
  24. Tapaneyasin R, Devahastin S, Tansakul A. Drying methods and quality of shrimp dried in a jet-spouted bed dryer. J Food Process Eng 2005;28:3552. [CrossRef] [31] Vega-Galvez A, Miranda M, Bilbao-Sainz C, Uribe E, Lemus-Mondaca R. Freeze-drying kinetics and diffusion modeling of saffron (crocus sativus L.). J Food Process Preserv 2008;32:972986. [CrossRef] [32] Crank J. The mathematics of Diffusion. Great Britain: Oxford University Press: 1975.
  25. Zogzas N-P, Maroulis Z-B, Marinos-Kouris D. Moisture diffusivity data compilation in foodstuffs. Dry Technol 1996;14:22252253. [CrossRef]