Journals / Uludağ Üniversitesi Mühendislik Fakültesi Dergisi / 2026 / Cilt: 23 Sayı: 2

Investigation of Biological Treatability of Produced Water Generated from Oil and Gas Fields

PETROL VE DOĞAL GAZ ÜRETİM ATIKSULARININ BİYOLOJİK ARITILABİLİRLİĞİNİN İNCELENMESİ

Recep Kaya(Ulusal Membran Teknolojileri Araştırma Merkezi (MEM-TEK), İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul ** Çevre Mühendisliği Bölümü, İnşaat Fakültesi, İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul)
Hale Özgün(Ulusal Membran Teknolojileri Araştırma Merkezi (MEM-TEK), İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul ** Çevre Mühendisliği Bölümü, İnşaat Fakültesi, İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul)
Börte Köse-mutlu(Ulusal Membran Teknolojileri Araştırma Merkezi (MEM-TEK), İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul ** Çevre Mühendisliği Bölümü, İnşaat Fakültesi, İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul)
M. Evren Erşahin(Ulusal Membran Teknolojileri Araştırma Merkezi (MEM-TEK), İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul ** Çevre Mühendisliği Bölümü, İnşaat Fakültesi, İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul)
Mahmut Altınbaş(Ulusal Membran Teknolojileri Araştırma Merkezi (MEM-TEK), İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul ** Çevre Mühendisliği Bölümü, İnşaat Fakültesi, İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul)
Sema Sayılı(Türkiye Petrolleri Anonim Ortaklığı, Soğütözü, Çankaya, Ankara)
Pelin Hoşhan(Türkiye Petrolleri Anonim Ortaklığı, Soğütözü, Çankaya, Ankara)
Doğa Atay(Türkiye Petrolleri Anonim Ortaklığı, Soğütözü, Çankaya, Ankara)
Esra Eren(Türkiye Petrolleri Anonim Ortaklığı, Soğütözü, Çankaya, Ankara)
Cumali Kınacı(Ulusal Membran Teknolojileri Araştırma Merkezi (MEM-TEK), İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul ** Çevre Mühendisliği Bölümü, İnşaat Fakültesi, İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul)
İsmail Koyuncu(Ulusal Membran Teknolojileri Araştırma Merkezi (MEM-TEK), İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul ** Çevre Mühendisliği Bölümü, İnşaat Fakültesi, İstanbul Teknik Üniversitesi, Maslak, Sarıyer, İstanbul)
Pages
13–28
Publication Date
2018-08-31
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Determination of the inert characterization and biological treatability of the produced water is very critical for the selection of the most appropriate treatment method.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Produced water is co-produced during oil and gas production and the oil/water mixture is pumped out of the well to the surface.
📊
Key Findings & Data:Average COD removal efficiency of 68% was achieved in the SBR treating produced water from oil and natural gas field.
💡
Conclusion & Impact:Determination of the inert characterization and biological treatability of the produced water is very critical for the selection of the most appropriate treatment method.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Ardışık kesikli reaktör · biyolojik arıtılabilirlik · inert KOİ

Abstract

Produced water is co-produced during oil and gas production and the oil/water mixture is pumped out of the well to the surface. Produced water contains various organic and inorganic components and thus, should be treated properly before its discharge. Physical, chemical and biological methods are used for the treatment of produced water. The aim of this study was to determine the biological treatability of produced water originated from oil and natural gas fields. Within this concept, produced water from oil and natural gas field, and from natural gas field was treated by sequencing batch reactors (SBR). Because of the high salinity content of the produced water from natural gas field, biological treatability of the samples from this field was very low. Average COD removal efficiency of 68% was achieved in the SBR treating produced water from oil and natural gas field. Non-biodegradable (inert) fractions of the produced water were also determined in the study. Biodegradable COD constituted 86% of total COD in the produced water. The rest part of the total COD was found as inert (particulate and soluble) COD. Determination of the inert characterization and biological treatability of the produced water is very critical for the selection of the most appropriate treatment method.

Özet

Üretim atıksuyu petrol ve doğalgaz üretimi sırasında oluşarak petrol ve doğalgazın yeraltından pompalanması ile birlikte yüzeye çıkmaktadır. Üretim atıksuyu, içerisinde birçok organik ve inorganik bileşik içeren ve bu nedenle deşarjı öncesinde uygun şekilde arıtılması gereken bir atıksu türüdür. Üretim atıksularının arıtılmasında fiziksel, kimyasal ve/veya biyolojik yöntemler kullanılmaktadır. Bu çalışmada, petrol ve doğalgaz üretim atıksularının biyolojik olarak arıtılabilirliğinin ortaya konması amaçlanmıştır. Bu kapsamda; petrol ve doğalgaz üretimi ve sadece doğalgaz üretimi yapan sahalardan elde edilen üretim atıksuyu ardışık kesikli reaktör (AKR) sisteminde arıtılmıştır. Doğalgaz üretim sahasından alınan atıksuyun yüksek tuzluluk içeriğinden dolayı, biyolojik arıtılabilirliğinin düşük seviyede olduğu görülmüştür. Petrol ve doğalgaz üretim sahasından alınan üretim atıksuyunda ise ortalama KOİ giderim verimi %68 seviyesine ulaşmıştır. Petrol ve doğalgaz üretim atıksuyunun biyolojik olarak arıtılamayacak (inert) fraksiyonları da çalışma kapsamında belirlenmiş tir. Üretim atıksuyunda %86 oranında biyolojik olarak giderilebilen KOİ içeriği olduğu saptanmış ve geri kalan kısmın inert partiküler ve inert çözünmüş KOİ olduğu tespit edilmiştir. Üretim atıksuyunda inert karakterizayonun ve biyolojik arıtılabilirliğinin belirlenmesi, en uygun arıtma prosesi seçiminde yol gösterici olması bakımından oldukça önemlidir.

🔖

Cite This Article

Kaya, R., Özgün, H., Köse-mutlu, B., Erşahin, M. E., Altınbaş, M., Sayılı, S., Hoşhan, P., Atay, D., Eren, E., Kınacı, C., Koyuncu, İ. (2018). Investigation of Biological Treatability of Produced Water Generated from Oil and Gas Fields. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Cilt: 23 Sayı: 2, 13–28. https://doi.org/10.17482/uumfd.357454

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (34)

  1. Adewumi, M.A., Erb, J.E., Watson, R.W. (1992) Design considerations for a cost effective treatment of stripper oil well producedwater, ProducedWater: Technological/Environmental Issues and Solutions, Plenum Publishing Corp., New York. doi: 10.1007/978-1-4615-2902-6
  2. Ahmadun, F.R., Pendashteh, A., Abdullah, L.C., Biak, D.R.A., Madaeni, S.S., Abidin, Z.Z. (2009) Review of technologies for oil and as produced water treatment, Journal of Hazardous Materials, 170, 530–551 doi: 10.1016/j.jhazmat.2009.05.044
  3. API (1997). Oil and Gas Waste Management – Preliminary Results from API Survey, American Petroleum Institute.
  4. AWWA (2005). Standard methods for the examination of water and wastewater. American Public Health Association (APHA): Washington, DC, USA.
  5. Barrufet, M., Burnett, D., Mareth, B. (2005) Modeling and operation of oil removal and desalting oilfield brines with modular units, SPE Annual Technical Conference and Exhibition, Dallas, Texas, USA.
  6. Campos J.C., Borges R.M.H., Oliveira Filho A.M., Nobrega R. and Sant’Anna Jr. G.L. (2002) Oilfield wastewater treatment by combined microfiltration and biological processes. Water Research, 36:95–104. doi: 10.1016/S0043-1354(01)00203-2
  7. Dfaz, M.P., Grigson, S.J.W., Peppiat, C.J., Burgess, G. (2000) Isolation and characterization of novel hydrocarbon-degrading euryhaline consortia from crude oil and mangrove sediments, Marine Biotechnology 2 522–532. doi: 10.1007/s101260000037
  8. Doyle, D.H., Brown, A.B. (2000) Produced water treatment and hydrocarbon removal with organoclay, SPE Annual Technical Conference and Exhibition, Dallas, Texas, USA. doi:10.2118/63100-MS
  9. Dyke, C.A. (1992) Reducing aqueous boron concentrations with reverse osmosis membranes operating at a high pH, US Patent No. 5,250,185.
  10. Ezechi, E. H., Sapari, N., Menyechi, E. J., Ude, C. M., Olisa, E. (2017) Treatment of produced water in a floating carrier bioreactor. Environmental Engineering Research, 22, 210-215. doi: 10.4491/eer.2016.123
  11. Freire, D.D.C., Cammarota, M.C., Sant’Anna, G.L. (2001) Biological treatment of oil field wastewater in a sequencing batch reactor, Environmental Technology 22, 1125–1135. doi: 10.1080/09593332208618203
  12. Garbutt, C.F. (1997) Innovative treating processes allow steam flooding with poor quality oilfield water, SPE Annual Technical Conference and Exhibition, San Antonio, Texas, USA, 5–8 October. doi: 10.2118/38799-MS
  13. Garbutt, C.F. (1999) Water treatment process for reducing the hardness of an oilfield produced water, US Patent No. 5,879,562.
  14. Hansen BR, Davies SRH. (1994) Review of potential technologies for the removal of dissolved components from produced water. Chemical Engineering Research and Design 72:176–88.
  15. Hommel, R.K. (1990) Formation and physiological role of biosurfactants produced by hydrocarbon-utilizing microorganisms, Biodegradation 1 107–119. doi: 10.1007/978-94-011-3452-1_3
  16. Jimenez, S., Mico, M. M., Arnaldos, M., Medina, F., Contreras, S. (2018) State of the art of produced water treatment. Chemosphere, 192, 186-208. doi: 10.1016/j.chemosphere.2017.10.139
  17. Kayaalp, N., Ersahin, M. E., Ozgun, H., Koyuncu, I., & Kinaci, C. (2010) A new approach for chemical oxygen demand (COD) measurement at high salinity and low organic matter samples. Environmental Science and Pollution Research, 17(9), 1547-1552. doi: 10.1007/s11356-010-0341-z
  18. Kose Mutlu, B., Ersahin, M.E., Ozgun, H., Kaya, R., Kinaci, C., Koyuncu, I. (2017) Influence of powdered and granular activated carbon system as a pre-treatment alternative on membrane filtration of produced water, Journal of Chemical Technology and Biotechnology, 92(2), 283-291. doi: 10.1002/jctb.4996
  19. Kose, B., Ozgun, H., Ersahin, M.E., Dizge, N., Koseoglu-Imer, D.Y., Atay, B., Kaya, R., Altınbas, M., Sayili, S., Hoshan, P., Atay, D., Eren, E., Kinaci, C., Koyuncu, I. (2012) Performance evaluation of a submerged membrane bioreactor for the treatment of brackish oil and natural gas field produced water, Desalination, 285, 295-300. doi: 10.1016/j.desal.2011.10.016
  20. Mondal S. and Wickramasinghe S.R. (2008) Produced water treatment by nanofiltration and reverse osmosis membranes. Journal of Membrane Science 322:162–170. doi: 10.1016/j.memsci.2008.05.039
  21. Morrow L.R., Martir W.K., Aghazeynali H., WrightnD.E. (1999) Process of treating produced water with ozone, US Patent No. 5,868,945.
  22. Neff J.M., Sour T.C., Maciolek N. (1989) Fate and Effects of Produced Water Discharges in Nearshore Marine Waters, American Petroleum Institute, Washington, DC. American Petroleum Institute Publication No. 4472. doi: 10.1007/978-1-4615-2902-6_29
  23. Orhon D., Artan, N. (1994) Modelling of Activated Sludge Systems, Technomic Publishing Co. Inc., Lanchester, Basel, Switzerland. doi: 10.1111/j.1747-6593.1995.tb01620.x
  24. Ozgun, H., Ersahin, M.E., Erdem, S., Atay, B., Sayili, S., Eren, E., Hoshan, P., Atay, D., Altinbas, M., Kinaci, C., Koyuncu, I. (2013a) Comparative evaluation for characterization of produced water generated from oil, gas and oil-gas production fields, Clean-Soil Air Water, 41(12), 1175-1182. doi: 10.1002/clen.201200204
  25. Ozgun, H., Ersahin, M.E., Erdem, S., Atay, B., Kose, B., Kaya, R., Altinbas, M., Sayili, S., Hoshan, P., Atay, D., Eren, E., Kinaci, C., Koyuncu, I. (2013b) Effects of the pre-treatment alternatives on the treatment of oil-gas field produced water by nanofiltration and reverse osmosis membranes, Journal of Chemical Technology and Biotechnology, 88, 1576-1583. doi: 10.1002/jctb.4007
  26. Öztürk, İ., Yetilmezsoy, K., Ekdal, A., Cüceloğlu, G., Güven, H. (2016) Çevre Mühendisleri için İstatistik ve Deneysel Tasarım, İSTAÇ A.Ş., İstanbul, Türkiye.
  27. Piemonte, V., Di Paola, L., Prisciandaro, M. (2016) Two phase partitioning bioreactor applied to produced water treatment. Journal of Water Reuse and Desalination, 6(2), 274-279. doi: 10.1080/19443994.2016.1148222
  28. Qiao, X., Zhang, Z., Yu, J., Ye, X., (2008) Performance Characteristics of A Hybrid Membrane Pilot-Scale Plant for Oilfield-Produced Wastewater, Desalination 225, 113–122. doi: 10.1016/j.desal.2007.04.092
  29. Stephenson MT. (1992) Components of produced water: a compilation of industry studies. Journal of Petroleum Technology 44:548–603. doi: 10.2118/23313-PA
  30. Stoll, Z.A., Forrestal, C., Ren, Z.J., Xu, P. (2015) Shale gas produced water treatment using innovative microbial capacitive desalination cell. Journal of Hazardous Materials, 283, 847-855. doi: 10.1016/j.jhazmat.2014.10.015
  31. Tao, F.T., Curtice, S., Hobbs, R.D., Sides, J.L., Wieser, J.D., Dyke, C.A., Tuohey, D., Pilger, P.F. (1993) Reverse osmosis process successfully converts oil field brine into freshwater, Oil and Gas Journal 91 (1993) 88–91.
  32. Tellez GT, Nirmalakhandan N, Gardea-Torresdey JL. (1995) Evaluation of biokinetic coefficients in degradation of oilfield produced water under varyingsalt concentrations. Water Research 29:1711–8. doi: 10.1016/0043-1354(94)00328-5
  33. Wei, N., Wang, X.H., Li, F.K., Zhang, Y.J., Guo, Y. (2003) Treatment of high-salt oil field produced water by composite microbial culture, Urban Environment & Urban Ecology 16 10–12.
  34. Yang, Z.G., Zhang, N.S. (2005) Treatment of produced wastewater by flocculation settlement-Fenton oxidation–adsorption method, Journal of Xi’an Shiyou University Natural Science Edition 20 50–53