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Journals / Politeknik Dergisi / 2020 / Cilt: 23 Sayı: 4

Low Concentration NO Gas Detection Of SnO2 And Zn0.50Sn0.50O Sensors

İrmak Karaduman Er(CANKIRI KARATEKIN UNIVERSITY)0000-0003-3786-3865
Tuğba Çorlu(Süleyman Demirel University)0000-0003-3786-3865
Memet Ali Yıldırım(ERZİNCAN BİNALİ YILDIRIM ÜNİVERSİTESİ)0000-0003-3786-3865
Aytunç Ateş(ANKARA YILDIRIM BEYAZIT UNIVERSITY)0000-0003-3786-3865
Selim Acar(Gazı University)0000-0003-3786-3865
Pages
1189–1196
Publication Date
2020-12-01
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The measurement results showed that the sensitivity of the sensors changed depending on the doping and producing cycles.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, the gas sensing properties of SnO 2 and Zn 0.50 Sn 0.50 O samples produced by Succession Ionic Layer Adsorption and Reaction ( SILAR) method with different SILAR cycles against NO gas were investigated.
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Key Findings & Data:Electrical characterization of the produced sample at different temperatures (35 °C-135 °C) and different gas concentrations (50 ppb-25 ppm) were performed.
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Conclusion & Impact:The measurement results showed that the sensitivity of the sensors changed depending on the doping and producing cycles.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Gas sensing · SILAR method · NO gas

Abstract

In this study, the gas sensing properties of SnO 2 and Zn 0.50 Sn 0.50 O samples produced by Succession Ionic Layer Adsorption and Reaction ( SILAR) method with different SILAR cycles against NO gas were investigated. Electrical characterization of the produced sample at different temperatures (35 °C-135 °C) and different gas concentrations (50 ppb-25 ppm) were performed. The working temperature was found at 105 ° C. The sensors were proved to have acceptable responses towards 50 ppb NO gas. Zn 0.50 Sn 0.50 O sensor exhibited improved sensing performance at working temperature of 105 ° C compared to SnO 2 sensor.. The ,responses of SnO 2 sensors for the 50 ppb NO gas concentration, sensitivities of 1.74%, 2.15% and 3.37% were obtained for 20, 30 and 40 cycles, respectively. On the other hand, the,responses of Zn 0.50 Sn 0.50 O sensors for the 50 ppb NO gas concentration sensitivities of 3.01%, 3.74% and 4.16% were obtained for 20, 30 and 40 cycles, respectively. The measurement results showed that the sensitivity of the sensors changed depending on the doping and producing cycles.

Özet

In this study, the gas sensing properties of SnO 2 and Zn 0.50 Sn 0.50 O samples produced by Succession Ionic Layer Adsorption and Reaction ( SILAR) method with different SILAR cycles against NO gas were investigated. Electrical characterization of the produced sample at different temperatures (35 °C-135 °C) and different gas concentrations (50 ppb-25 ppm) were performed. The working temperature was found at 105 ° C. The sensors were proved to have acceptable responses towards 50 ppb NO gas. Zn 0.50 Sn 0.50 O sensor exhibited improved sensing performance at working temperature of 105 ° C compared to SnO 2 sensor.. The ,responses of SnO 2 sensors for the 50 ppb NO gas concentration, sensitivities of 1.74%, 2.15% and 3.37% were obtained for 20, 30 and 40 cycles, respectively. On the other hand, the,responses of Zn 0.50 Sn 0.50 O sensors for the 50 ppb NO gas concentration sensitivities of 3.01%, 3.74% and 4.16% were obtained for 20, 30 and 40 cycles, respectively. The measurement results showed that the sensitivity of the sensors changed depending on the doping and producing cycles.

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Cite This Article

Er, İ. K., Çorlu, T., Yıldırım, M. A., Ateş, A., Acar, S. (2020). Low Concentration NO Gas Detection Of SnO2 And Zn0.50Sn0.50O Sensors. Politeknik Dergisi, Cilt: 23 Sayı: 4, 1189–1196. https://doi.org/10.2339/politeknik.621181

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References (19)

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  11. 3, 2025–2036, (2019).[5] Karaduman I., Barin Ö., Yıldız D.E., Acar S., Atomik Tabaka Biriktirme Metodu ile Üretilen HfO2 Tabanlı Sensörlerin Hidrojen Gaz Algılama Özelliklerinin İncelenmesi, Journal of Polytechnic, 2016
  12. 19 (3): 223-229. [6] Kumar V., Singh K., Sharma J., Kumar A., Vij A., Thakur A., Zn-doped SnO2 nanostructures: structural, morphological and spectroscopic properties, J Mater. Scı.-Mater. El., 28
  13. 24, 18849–18856, (2017).[7] Saadeddin I., Hilal H.S., Pecquenard B., Marcus J., Mansouri A., Labrugere C., Subramanian M.A., Campet G., Simultaneous doping of Zn and Sb in SnO2 ceramics: Enhancement of electrical conductivity, Solid State Sci., 8
  14. 1, 7-13, (2006). [8] Guan Y., Wang D., Zhou X., Sun P., Wang H., Ma J., Lu G., Hydrothermal preparation and gas sensing properties of Zn-doped SnO2 hierarchical architectures, Sens. Actuators B, 191, 45-52, (2014).[9] Gupta P., Sharma S.K., A study of oxygen gas sensing in Zn-doped SnO2 nanostructures, Mater. Res. Express, 4, 065010, (2017).[10] Singh D., Singh Kundu V., Maan A. S., Structural, morphological and gas sensing study of zinc doped tin oxide nanoparticles synthesized via hydrothermal technique, J. Mol. Struct., 1115, 250-257, (2016). [11] Galioglu S., Karaduman I., Çorlu T., Akata B., Yıldırım M. A., Ateş A., Acar S., Zeolite A coated Zn1−XCuXO MOS sensors for NO gas detection, J. Mater. Sci.: Mater. Elektron, 29
  15. 2, 1356-1368, (2018).[12] Çorlu T., Karaduman I., Galioglu S., Akata B., Yıldırım M.A., Ates A., Acar S., Low level NO gas sensing properties of Cu doped ZnO thin films prepared by SILAR method, Mater. Lett., 212, 292–295 (2018).[13] Karunakaran M., Maheswari S., Kasirajan K., Dinesh Raj S., Chandramohan R., Structural and Optical Properties of Mn-Doped ZnO Thin Films Prepared by SILAR Method, International Letters of Chemistry, Physics and Astronomy, 73, 22-30, (2017). [14] Karaduman Er I., Çağırtekın A.O., Çorlu T., Yıldırım M.A., Ateş A., Acar S., Low-level NO gas sensing properties of Zn1−xSnxO nanostructure sensors under UV light irradiation at room temperature, Bull. Mater. Sci., 42
  16. 32 (2019).[15] Vermaa M., Dwivedib P. K., Das B., Structure–property correlation of pure and Sn-doped ZnO nanocrystalline materials prepared by co-precipitation, Journal of Experimental Nanoscience, 10
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  18. 10, 1331-1337, (2011). [18] Zhou Q., Chen W., Xu L., Kumar R., Gui Y., Zhao Z., Tang C., Zhu S., Highly sensitive carbon monoxide (CO) gas sensors based on Ni and Zn doped SnO2 nanomaterials, Ceram. Int. 44, 4392–4399, (2018).[19] Zheng L., Xu T., Li G., Q Yin, Influence of thickness on oxygen-sensing properties of TiO2 thin films on Al2O3, J. Appl. Phys., Part 1 41, 4655-4658, (2002).[20] Hossein-Babari F., Orvatinia M., Analysis of thickness dependence of the sensitivity in thin film resistive gas sensors, Sens. Actuators B 89, 256-261, (2003).[21] Christoulakis S., Suchea M., Koudoumas E., Katharakis M., Katsarakis N., Kiriakidis G., Thickness influence on surface morphology and ozone sensing properties of nanostructured ZnO transparent thin films grown by PLD, Appl. Surf. Sci., 252, 5351-5354, (2006).[22] Çorlu T., Karaduman I.,Yildirim M.A., Ateş A.,Acar S., Effect of Doping Materials on the Low-Level NO Gas Sensing Properties of ZnO Thin Films, J. Electron. Mater., 46
  19. 7, 3995–4002, (2017). [23] Huang H., Tian S., Xu J., Xie Z., Zeng D., Chen D., Shen G., Needle-like Zn-doped SnO2 nanorods with enhanced photocatalytic and gas sensing properties, Nanotechnology, 23, 105502, (2012).