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Journals / Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi / 2006 / Cilt: 22 Sayı: 1

THE INVESTIGATIONS OF THE REACTIONS OF 1-AMINO-5-BENZOYL-4- PHENYL-1H-PYRIMIDINE-2-THIONE WITH CARBONYL REACTIVES

1-AMİNO-5-BENZOİL-4-FENİL-1H-PİRİMİDİN-2-TİYON’UN, BAZI KARBONİL REAKTİFLERİYLE REAKSİYONLARININ İNCELENMESİ

Zülbiye Önal(ERCİYES ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA PR.)
Pages
256–261
Publication Date
2006-02-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The structures of these compounds were determined by the IR, 1 H- NMR spectroscopic data and elemental analysis.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-thione 1 was obtained by starting from 4-benzoyl-5-phenyl-2,3- furandione and acetophenonthiosemicarbazone.
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Key Findings & Data:In this study, the investigations were extended to reactions of 1 with ethylacetoacetate, benzalacetophenon, cyanoaceticacid, benzyl, benzoin and acetylchloride.
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Conclusion & Impact:The structures of these compounds were determined by the IR, 1 H- NMR spectroscopic data and elemental analysis.
🔬Design:Makale
📍Scope:Comprehensive Sample
⚙️Variables:Pirimidin-2-tiyon · Ketimin · Amit

Abstract

The 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-thione 1 was obtained by starting from 4-benzoyl-5-phenyl-2,3- furandione and acetophenonthiosemicarbazone. In this study, the investigations were extended to reactions of 1 with ethylacetoacetate, benzalacetophenon, cyanoaceticacid, benzyl, benzoin and acetylchloride. Thus, some new pyrimidine derivatives (1a-e) were synthesized. The structures of these compounds were determined by the IR, 1 H- NMR spectroscopic data and elemental analysis.

Özet

1-Amino-5-benzoil-4-fenil-1H-pirimidin-2-tiyon 1 bileşiği, 4-benzoil-5-fenil-2,3-furandion bileşiğinin, asetofenontiyosemikarbazon ile reaksiyonu sonucu elde edilmiştir [1,2]. Bu çalışmada 1 bileşiğinin, etilasetoasetat, benzalasetofenon, siyanoasetik asit, benzil, benzoin ve asetilklorür gibi reaktiflerle reaksiyonları araştırıldı. Böylece yeni pirimidin türevi bileşikler (1a-e) elde edildi. Elde edilen bileşiklerin yapıları elementel analiz, IR, 1 H-NMR spektrumları yardımıyla aydınlatıldı.

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Cite This Article

Önal, Z. (2006). THE INVESTIGATIONS OF THE REACTIONS OF 1-AMINO-5-BENZOYL-4- PHENYL-1H-PYRIMIDINE-2-THIONE WITH CARBONYL REACTIVES. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, Cilt: 22 Sayı: 1, 256–261. https://ajindex.com/articles/1267372

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