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Journals / Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2026 / Cilt: 14 Sayı: 1

Synthesis and Characterization of Conducting Copolymers of 4- aminobenzo-15-crown-5 with thiophene-3-carbaldehyde with 3,4- ethylenedioxythiophene

4' (N-(Tiyofen-3-il metilen) benzenamin)-15-taç-5 eter ile 3,4-etilendioksitiyofen İletken Kopolimerinin Sentezi ve Karakterizasyonu

Elif Şahin Işgın
Ertuğrul Şahmetlioğlu
Ersen Turaç
İbrahim Demir
Pages
50–56
Publication Date
2012-06-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Characterization of the copolymer was performed by cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR),thermal gravimetric analysis (TGA), scanning electron microscopy (SEM) methods

📌 3 Key Takeaways

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Objective & Hypothesis:In this study a new 4’ (N-(Thiophen-3-yl methylene) benzenamine-15-crown-5 ether (TAE) monomer was synthesized by condensation reaction between 4-aminobenzo-15crown-5 with thiophene-3-carbaldehyde.
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Key Findings & Data:Electrically conducting copolymer of TAE with 3,4-ethylenedioxythiophene (EDOT) was achieved by electrochemical methods.
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Conclusion & Impact:Characterization of the copolymer was performed by cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR),thermal gravimetric analysis (TGA), scanning electron microscopy (SEM) methods
🔬Design:Makale
📍Scope:Comprehensive Sample
⚙️Variables:İletken polimerler · 4-etilendioksitiyofen · tiyofen

Abstract

In this study a new 4’ (N-(Thiophen-3-yl methylene) benzenamine-15-crown-5 ether (TAE) monomer was synthesized by condensation reaction between 4-aminobenzo-15crown-5 with thiophene-3-carbaldehyde. Electrically conducting copolymer of TAE with 3,4-ethylenedioxythiophene (EDOT) was achieved by electrochemical methods. Characterization of the copolymer was performed by cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR),thermal gravimetric analysis (TGA), scanning electron microscopy (SEM) methods

Özet

Bu kondenzasyon tepkimesi ile yeni bir 4’ (N-(Tiyofen-3-il metilen) benzenamin)-15-taç-5 eter (TAE) monomeri sentezlendi. TAE’nin 3,4-etilendioksitiyofen (EDOT) elektriksel olarak iletken kopolimeri elektrokimyasal yöntem ile sentezlendi. Kopolimerin karakterizasyonu; dönüşümlü voltametri (CV), Fourier transform infrared spektroskopi (FTIR), termal gravimetrik ısıl analizi (TGA), taramalı elektron mikroskopi (SEM) yöntemleri ile yapıldı

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Cite This Article

Işgın, E. Ş., Şahmetlioğlu, E., Turaç, E., Demir, İ. (2012). Synthesis and Characterization of Conducting Copolymers of 4- aminobenzo-15-crown-5 with thiophene-3-carbaldehyde with 3,4- ethylenedioxythiophene. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt: 14 Sayı: 1, 50–56. https://ajindex.com/articles/1263926

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References (14)

  1. . Boehme, J.L., Mudigonda, D.S.K. ve Ferraris, J.P., Electrochromic Properties of Laminate Devices Fabricated from Polyaniline, Poly(ethylenedioxythiophene), and Poly(N-methylpyrrole), Chemistry of Materials,13, 4469-4472, (2001).
  2. . Schwendeman, I., Hickman, R., Sonmez, G., Schottland, P., Zong, K., Welsh, D.M. ve Reynolds, J.R., Enhanced contrast Dual Polymer Electrochromic Devices, Chemistry of Materials, 14, 3118-3122, (2002).
  3. . Pages, H., Topart, P. ve Lemordant, D., Wide band electrochromic displays based on thin conducting polymer films, Electrochimica Acta, 46, 2137-2143, (2001).
  4. . Argun, A.A., Cirpan, A., Reynolds, J.R. The First Truly All-Polymer Electrochromic Devices, Advanced Materials, 15, 1338-1341, (2003).
  5. . Shinbo, T., Yamaguchi, T., Nishimura, K., Kikkawa,M., Sugiura, M., Enantiomer-selective membrane electrode for amino acid methyl esters, Analytica Chimica Acta, 193, 367-371, (1987).
  6. . Blasius, E., Janzen, K.P., M.J.S., Dunitz, J.D., Haffner, K., Heilbronner, E., Ito, S. Lehn, J.M., Niedenzu, K., Raymond, K.N., Rees, C.W., Schafer, K., Wittig, G.(Eds), Topics in Current Chemistry I, Springer, New York, 1961.
  7. . Roncali, J., Molecular Engineering of the Band Gap of p-Conjugated Systems: Facing Technological Applications, Macromolecular Rapid Communications, 28 1761-1775, (2007).
  8. . Lukovskaya, E.V., Bobyleva, A.A., Fedorova, O.A., Fedorov, Y.V., Anisimov, A.V., Didane, Y., Brisset, H. ve Fages, F., Novel crown-containing 3-styryl derivatives of oligothiophenes: synthesis, structure, and optical and electrochemical characteristics, Russian Chemical Bulletin, 58(7), 1509-1515, (2009).
  9. . Casanovas, J., Rodriguez-Roper, F., Zanuy, D., Aleman, C., Microscopic details of the sensing ability of 15-crown-5-ether functionalized poly(bithiophene), Polymer, 51(18), 4267-4272, (2010).
  10. . Celebi, S., Baran, D., Balan, A., Toppare, L., Enhancing electrochromic and kinetic properties of poly(2,3-bis(4-tert-butylphenyl)-5,8-di(1H-pyrrol-2-yl) quinoxaline) by copolymerization, Electrochimica Acta, 5(7), 2373-2376, (2010).
  11. . Yildiz, E., Camurlu, P., Tanyeli, C., Akhmedov, I., Toppare, L., A soluble conducting polymer of 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine and its multichromic copolymer with EDOT, Journal of Electroanalaytical Chemistry, 612, 247-256, (2008).
  12. . Yigitsoy, B., Varis, S., Tanyeli, C., Akhmedov, I.M., Toppare, L., Electrochromic properties of a novel low band gap conductive copolymer, Electrochimica Acta, 52, 6561–6568, (2007).
  13. . Demir, I., Şahmetlioğlu, E., Gokcen, Y., Synthesis, electrochemical and antibactarial activity of some novel N4O2 ligand derivatives, Russian Journal of General Chemistry, 78(7), 1458-1462, (2008).
  14. . Lukovskaya, E.V., Bobyleva, A.A., Fedorova, O.A., Fedorov, Y.V., Anisimov, A.V., Didane, Y., Brisset, H. ve Fages, F., Novel crown-containing 3-styryl derivatives of oligothiophenes: synthesis, structure, and optical and electrochemical characteristics, Russian Chemical Bulletin, 58(7), 1509-1515, (2009).