Journals / Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2026 / Cilt: 19 Sayı: 1

Tribological and Surface Enhancement of CP Titanium via PVD-Deposited CrCN Thin Films

PVD ile Biriktirilmiş CrCN İnce Filmler Aracılığıyla CP Titanyumun Tribolojik ve Yüzey İyileştirmesi

Emrah Meletlioğlu(atatürk üniversitesi mühendislik fakültesi makine mühendisliği bölümü)0000-0002-6123-1609
Pages
268–276
Publication Date
2026-03-30
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The findings revealed that the CrCN-coated samples demonstrated superior wear resistance, which was attributed to their increased surface hardness and reduced roughness compared to the uncoated specimens.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Commercially pure titanium (CP Ti) has gained significant attention for biomedical applications due to its favorable strength-to-weight ratio and excellent biocompatibility.
📊
Key Findings & Data:Furthermore, a comparative assessment of wear performance was conducted using a pin-on-disk tribometer.
💡
Conclusion & Impact:The findings revealed that the CrCN-coated samples demonstrated superior wear resistance, which was attributed to their increased surface hardness and reduced roughness compared to the uncoated specimens.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:CrCN kaplama · fiziksel buhar biriktirme · tribolojik özellikler

Abstract

Commercially pure titanium (CP Ti) has gained significant attention for biomedical applications due to its favorable strength-to-weight ratio and excellent biocompatibility. Nonetheless, its inherent corrosion resistance remains insufficient for certain functional environments, necessitating surface modifications to enhance its durability. In this context, the present study focused on improving the tribological and surface characteristics of CP Ti by depositing chromium carbonitride (CrCN) films via physical vapor deposition (PVD). The morphological and structural differences between uncoated and coated specimens were analyzed through X-ray diffraction (XRD) and scanning electron microscopy (SEM). Furthermore, a comparative assessment of wear performance was conducted using a pin-on-disk tribometer. The findings revealed that the CrCN-coated samples demonstrated superior wear resistance, which was attributed to their increased surface hardness and reduced roughness compared to the uncoated specimens.

Özet

Ticari olarak saf titanyum (CP Ti), uygun mukavemet-ağırlık oranı ve mükemmel biyouyumluluğu nedeniyle biyomedikal uygulamalarda büyük ilgi görmektedir. Bununla birlikte, doğal korozyon direnci belirli fonksiyonel ortamlar için yetersiz kalmakta ve dayanıklılığını artırmak için yüzey modifikasyonları gerekmektedir. Bu bağlamda, mevcut çalışma, fiziksel buhar biriktirme (PVD) yoluyla krom karbonitrür (CrCN) filmleri biriktirerek CP Ti'nin tribolojik ve yüzey özelliklerini iyileştirmeye odaklanmıştır. Kaplanmamış ve kaplanmış numuneler arasındaki morfolojik ve yapısal farklılıklar, X-ışını difraksiyonu (XRD) ve taramalı elektron mikroskobu (SEM) ile analiz edilmiştir. Ayrıca, pin-on-disk tribometre kullanılarak aşınma performansı karşılaştırmalı bir değerlendirme yapılmıştır. Bulgular, CrCN kaplı numunelerin, kaplanmamış numunelere kıyasla artan yüzey sertliği ve azalan pürüzlülüğü sayesinde üstün aşınma direnci gösterdiğini ortaya koymuştur.

🔖

Cite This Article

Meletlioğlu, E. (2026). Tribological and Surface Enhancement of CP Titanium via PVD-Deposited CrCN Thin Films. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt: 19 Sayı: 1, 268–276. https://doi.org/10.18185/erzifbed.1713967

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (24)

  1. Mora-Sanchez, H., Sabirov, I., Monclus, M., Matykina, E., & Molina-Aldareguia, J. (2016). Ultra-fine grained pure Titanium for biomedical applications. Materials Technology, 31(13), 756-771.
  2. Marin, E., & Lanzutti, A. (2023). Biomedical applications of titanium alloys: a comprehensive review. Materials, 17(1), 114.
  3. Yang, J., Song, Y., Dong, K., & Han, E.-H. (2023). Research progress on the corrosion behavior of titanium alloys. Corrosion Reviews, 41(1), 5-20.
  4. Balakrishnan, A., Lee, B., Kim, T., & Panigrahi, B. (2008). Corrosion behaviour of ultra fine grained titanium in simulated body fluid for implant application. Trends Biomater. Artif. Organs, 22(1), 58-64.
  5. Jaquez-Munoz, J., Gaona-Tiburcio, C., Lira-Martinez, A., Zambrano-Robledo, P., Maldonado-Bandala, E., Samaniego-Gamez, O.,. Almeraya-Calderon, F. (2021). Susceptibility to pitting corrosion of Ti-CP2, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-4V alloys for aeronautical applications. Metals, 11(7), 1002. [6] Zhang, L.-C., Chen, L.-Y., & Wang, L. (2020). Surface modification of titanium and titanium alloys: technologies, developments, and future interests. Advanced Engineering Materials, 22(5), 1901258. [7] Sasikumar, Y., Indira, K., & Rajendran, N. (2019). Surface modification methods for titanium and its alloys and their corrosion behavior in biological environment: a review. Journal of Bio-and Tribo-Corrosion, 5(2), 36.
  6. Chouirfa, H., Bouloussa, H., Migonney, V.-u., & Falentin-Daudré, C. (2019). Review of titanium surface modification techniques and coatings for antibacterial applications. Acta biomaterialia, 83, 37-54.
  7. Baptista, A., Silva, F., Porteiro, J., Míguez, J., & Pinto, G. (2018). Sputtering physical vapour deposition (PVD) coatings: A critical review on process improvement and market trend demands. Coatings, 8(11), 402.
  8. Adeoye, A. E., Adeaga, O., & Ukoba, K. (2024). Chemical Vapour Deposition (CVD) and Physical Vapour Deposition (PVD) techniques: Advances in thin film solar cells. Nigerian Journal of Technology, 43(3), 479-489.
  9. Yang, T. H., Shi, Y., Janssen, A., & Xia, Y. (2020). Surface capping agents and their roles in shape‐controlled synthesis of colloidal metal nanocrystals. Angewandte Chemie International Edition, 59(36), 15378-15401.
  10. Scigala, A., Szłyk, E., Rerek, T., Wiśniewski, M., Skowronski, L., Trzcinski, M., & Szczesny, R. (2021). Copper nitride nanowire arrays—comparison of synthetic approaches. Materials, 14(3), 603.
  11. Yumusak, G., Leyland, A., & Matthews, A. (2022). A microabrasion wear study of nitrided α-Ti and β-TiNb PVD metallic thin films, pre-deposited onto titanium alloy substrates. Surface and Coatings Technology, 442, 128423.
  12. Oliveira, V., Aguiar, C., Vazquez, A., Robin, A., & Barboza, M. J. R. (2014). Improving corrosion resistance of Ti–6Al–4V alloy through plasma-assisted PVD deposited nitride coatings. Corrosion Science, 88, 317-327.
  13. Senocak, T. C. (2023). Characterization and performance of Tantalum-Tungsten based coatings deposited on Cp-Ti substrates by PVD technique. Materials Today Communications, 37, 107091.
  14. Hu, W., Wan, L., Liu, X., Li, Q., & Wang, Z. (2011). Effect of TiO2/Al2O3 film coated diamond abrasive particles by sol–gel technique. Applied Surface Science, 257(13), 5777-5783.
  15. Lugscheider, E., Knotek, O., Barimani, C., Guerreiro, S., & Zimmermann, H. (1997). Cr-CN coatings deposited with different reactive carbon carrier gases in the arc PVD process. Surface and Coatings Technology, 94, 416-421.
  16. Abdullah, M. Z. B., Ahmad, M. A., Abdullah, A. N., Othman, M. H., Hussain, P., & Zainuddin, A. (2016). Metal release of multilayer coatings by physical vapour deposition (PVD). Procedia Engineering, 148, 254-260.
  17. Warcholiński, B., Gilewicz, A., Kukliński, Z., & Myśliński, P. (2008). Arc-evaporated CrN, CrN and CrCN coatings. Vacuum, 83(4), 715-718.
  18. Warcholinski, B., & Gilewicz, A. (2013). Effect of substrate bias voltage on the properties of CrCN and CrN coatings deposited by cathodic arc evaporation. Vacuum, 90, 145-150.
  19. Aissani, L., Fellah, M., Radjehi, L., Nouveau, C., Montagne, A., & Alhussein, A. (2019). Effect of annealing treatment on the microstructure, mechanical and tribological properties of chromium carbonitride coatings. Surface and Coatings Technology, 359, 403-413.
  20. Purcek, G., Saray, O., Kul, O., Karaman, I., Yapici, G., Haouaoui, M., & Maier, H. (2009). Mechanical and wear properties of ultrafine-grained pure Ti produced by multi-pass equal-channel angular extrusion. Materials Science and Engineering: A, 517(1-2), 97-104.
  21. Harlin, P., Carlsson, P., Bexell, U., & Olsson, M. (2006). Influence of surface roughness of PVD coatings on tribological performance in sliding contacts. Surface and Coatings Technology, 201(7), 4253-4259.
  22. Saketi, S., & Olsson, M. (2017). Influence of CVD and PVD coating micro topography on the initial material transfer of 316L stainless steel in sliding contacts–A laboratory study. Wear, 388, 29-38.
  23. Gilewicz, A., Murzynski, D., Dobruchowska, E., Kwiatkowski, J., Olik, R., Ratajski, J., & Warcholinski, B. (2017). Wear and corrosion behavior of CrCN/CrN coatings deposited by cathodic arc evaporation on nitrided 42CrMo4 steel substrates. Protection of Metals and Physical Chemistry of Surfaces, 53, 312-321.
  24. Jaquez-Munoz, J., Gaona-Tiburcio, C., Lira-Martinez, A., Zambrano-Robledo, P., Maldonado-Bandala, E., Samaniego-Gamez, O.,. Almeraya-Calderon, F. (2021). Susceptibility to pitting corrosion of Ti-CP2, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-4V alloys for aeronautical applications. Metals, 11(7), 1002. [6] Zhang, L.-C., Chen, L.-Y., & Wang, L. (2020). Surface modification of titanium and titanium alloys: technologies, developments, and future interests. Advanced Engineering Materials, 22(5), 1901258. [7] Sasikumar, Y., Indira, K., & Rajendran, N. (2019). Surface modification methods for titanium and its alloys and their corrosion behavior in biological environment: a review. Journal of Bio-and Tribo-Corrosion, 5(2), 36.