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Journals / Karaelmas Fen ve Mühendislik Dergisi / 2026 / Cilt: 12 Sayı: 1

Deposition of TiO2-Doped Diamond-Like Carbon Films From a New Solution and Their Characterizations

TiO2 Katkılı Elmas-Benzeri Karbon Filmlerin Yeni Bir Çözeltiden Üretilmesi ve Karakterizasyonları

Necati Başman(İSKENDERUN TEKNİK ÜNİVERSİTESİ)0000-0002-8421-641X
Mehmet Gökçen(Zonguldak Bülent Ecevit Üniversitesi)0000-0003-3900-4626
Cengiz Temiz(Zonguldak Bülent Ecevit Üniversitesi)0000-0002-9265-7485
Pages
1–8
Publication Date
2022-06-01
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The obtained findings showed that TiO2 doped DLC nanocomposite films can be easily deposited with the solution proposed in this study.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Diamond-like carbon (DLC) films are the most studied coating materials due to their mechanical and physical properties.
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Key Findings & Data:In our previous study, we were able to produce a titanium dioxide (TiO2) doped DLC film by electrochemical method from a mixture of methanol (CH3OH) and titanium solution obtained by dissolving titanium metal in hydrogen peroxide (H2O2).
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Conclusion & Impact:The obtained findings showed that TiO2 doped DLC nanocomposite films can be easily deposited with the solution proposed in this study.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Elmas-benzeri karbon · Titanyum dioksit · Nanokompozit

Abstract

Diamond-like carbon (DLC) films are the most studied coating materials due to their mechanical and physical properties. Many studies have been conducted on the deposition methods and doping to improve the properties of these films. Among the deposition methods, the electrochemical deposition has advantages such as convenience and inexpensive equipment. In our previous study, we were able to produce a titanium dioxide (TiO2) doped DLC film by electrochemical method from a mixture of methanol (CH3OH) and titanium solution obtained by dissolving titanium metal in hydrogen peroxide (H2O2). In this study, TiO2 doped DLC films were deposited by electrolysis of solutions formed from a mixture of titanium isopropoxide (TTIP) and methanol. The films deposited at two different TTIP concentrations were characterized morphologically, structurally and elementally. Scanning electron micrographs were shown that the films are homogeneous and compact. No change was observed in the morphology of the films after annealing the films at 600 0C. Chemical analyses showed that titanium was in the form of TiO2 and the amount of titanium increased with increasing TTIP concentration. X-ray diffraction analysis revealed that TiO2 was amorphous in the DLC matrix and the film prepared with lower TTIP concentration had diamond content. After annealing at 600 0C, it was seen that this film was graphitized. The obtained findings showed that TiO2 doped DLC nanocomposite films can be easily deposited with the solution proposed in this study.

Özet

Elmas-benzeri karbon (EBK) filmler gösterdikleri mekanik ve fiziksel özelliklerinden dolayı en çok çalışılan kaplama malzemeleridir. Bu filmlerin özelliklerinin iyileştirilmesi için üretim yöntemleri ve katkılanmaları üzerine pek çok çalışma yapılmıştır. Üretim yöntemleri arasında elektrokimyasal biriktirme yöntemi, kolaylık ve ucuz ekipman gibi avantajlara sahiptir. Daha önceki bir çalışmamızda, titanyum metalini hidrojen peroksit (H2O2) içerisinde çözündürerek elde ettiğimiz titanyum çözeltisi ile metanol (CH3OH) karışımından, elektrokimyasal yöntemle titanyum dioxide (TiO2) katkılı EBK film üretmeyi başarmıştık. Bu çalışmada ise TiO2 katkılı EBK filmler titanyum isopropoxide (TTIP) ve metanol karışımından oluşturulan çözeltilerin elektrolizi ile biriktirildi. İki farklı TTIP konsantrasyonunda üretilen filmler, morfolojik, yapısal ve elementel olarak karakterize edildi. Taramalı elektron mikroskobu fotoğrafları filmlerin homojen ve kompakt olduğunu göstermiştir. Filmlerin 600 0C ‘de tavlanmasıyla filmlerin morfolojisinde bir değişiklik gözlenmemiştir. X-ışınları fotoelektron spektroskopisi analizleri, titanyumun film içerisinde TiO2 formunda olduğunu ve TTIP konsantrasyonunun artmasıyla filmdeki titanyum miktarının arttığını göstermiştir. X-ışınları kırınımı analizleri, TiO2’nin EBK matriste amorf olarak bulunduğunu ve daha düşük TTIP konsantrasyonuyla hazırlanan filmin elmas içeriğe sahip olduğunu ortaya koymuştur. 600 0C de tavlandıktan sonra ise bu filmin grafitize olduğu görülmüştür. Elde edilen bulgular, TiO2 katkılı EBK nanokompozit filmlerin bu çalışmada önerilen çözeltiyle kolaylıkla üretilebileceğini göstermiştir.

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Cite This Article

Başman, N., Gökçen, M., Temiz, C. (2022). Deposition of TiO2-Doped Diamond-Like Carbon Films From a New Solution and Their Characterizations. Karaelmas Fen ve Mühendislik Dergisi, Cilt: 12 Sayı: 1, 1–8. https://doi.org/10.7212/karaelmasfen.902067

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