SavedAdd your journal

Journals / Karaelmas Fen ve Mühendislik Dergisi / 2026 / Cilt: 13 Sayı: 1

Investigation of Strontium (II) Ions Adsorption onto Long Chain Quaternary Amine Cationic-Volcanite: Modeling and Optimization by RSM

Uzun Zincirli Kuaterner Amin Katyonik-Volkanit Üzerine Stronsiyum (II) İyonlarının Adsorpsiyonunun Araştırılması: RSM ile Modelleme ve Optimizasyon

Ümit Hüseyin Kaynar(IZMIR BAKIRCAY UNIVERSITY)0000-0002-3321-0341
Sermin Çam Kaynar(MANİSA CELÂL BAYAR ÜNİVERSİTESİ)0000-0002-3022-4908
Pages
72–84
Publication Date
2023-06-30
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

According to the results, it was concluded that this cheap and abundant adsorbent material can be effective in the separation and purification of radioactive wastes, and this structure can also be used in protective containers for the transport of wastes.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, kula volcanite with alkaline basaltic structure and abundant abundance was used for strontium removal by increasing its adsorption capacity with hexadecyltrimethylammonium (HDTMA) organic cation.
📊
Key Findings & Data:The theoretically adsorbed Strontium (II) at optimum values in the study was calculated as 31.978 mg/g.
💡
Conclusion & Impact:According to the results, it was concluded that this cheap and abundant adsorbent material can be effective in the separation and purification of radioactive wastes, and this structure can also be used in protective containers for the transport of wastes.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Adsorpsiyon · Stronsiyum (II) · Quaterner amin

Abstract

In this study, kula volcanite with alkaline basaltic structure and abundant abundance was used for strontium removal by increasing its adsorption capacity with hexadecyltrimethylammonium (HDTMA) organic cation. First, the adsorbent was characterized by XRF, FT-IR and SEM. Then, the adsorption of Strontium (II) ions from aqueous solutions was measured with the ICP device and the experiments were optimized by the surface response method (RSM). Central composite design (CCD) method was used for the study planning in the experiments. The theoretically adsorbed Strontium (II) at optimum values in the study was calculated as 31.978 mg/g. In addition, compatibility of various isotherms and thermodynamic parameters were evaluated in the study. According to the results, it was concluded that this cheap and abundant adsorbent material can be effective in the separation and purification of radioactive wastes, and this structure can also be used in protective containers for the transport of wastes.

Özet

Bu çalışmada, alkali bazaltik yapıda ve bol miktarda bulunan kula volkaniti, hekzadesiltrimetilamonyum (HDTMA) organik katyonu ile adsorpsiyon kapasitesi artırılarak stronsiyum gideriminde kullanılmıştır. İlk olarak, adsorban XRF, FT-IR ve SEM ile karakterize edilmiştir. Daha sonra, sulu çözeltilerden Stronsiyum (II) iyonlarının adsorpsiyonu ICP cihazı ile ölçülmüş ve deneyler yüzey yanıt metodu (YYM) ile optimize edilmiştir. Deneylerdeki çalışma planlanması için merkezi kompozit tasarım (CCD) metodu kullanılmıştır. Çalışmada optimum değerlerde teorik olarak adsorbe edilen Stronsiyum (II) 31,978 mg/g olarak hesaplanmıştır. Ayrıca çalışmada, çeşitli izotermlerin uyumluluğu ve termodinamik parametreler değerlendirilmiştir. Sonuçlara göre, ucuz ve bol miktarda olan bu adsorban malzemenin radyoaktif atıkların ayrıştırılması ve arıtılmasında etkili olabileceği ve bu yapının aynı zamanda atıkların taşınması için koruyucu kaplarda da kullanılabileceği sonucuna varılmıştır.

🔖

Cite This Article

Kaynar, Ü. H., Kaynar, S. Ç. (2023). Investigation of Strontium (II) Ions Adsorption onto Long Chain Quaternary Amine Cationic-Volcanite: Modeling and Optimization by RSM. Karaelmas Fen ve Mühendislik Dergisi, Cilt: 13 Sayı: 1, 72–84. https://doi.org/10.7212/karaelmasfen.1182259

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (35)

  1. Aghadavoud, A.; Rezaee Ebrahim Saraeea, Kh.; Shakur,H.R.; Sayyari, R. (2016) Removal of uranium ions from synthetic wastewater using ZnO/Na-clinoptilolite nanocomposites. Radiochimica Acta 104: 809-819. doi: 10.1515/ract-2016-2586
  2. Aralkumar, M.; Sathishkumar, P.; Palvannan, T. (2011) Optimization of Orange G dye adsorption by activated carbon of Thespesia populnea pods using response surface methodology. J. Hazard. Mater. 186: 827-834. doi: 10.1016/j.jhazmat.2010.11.067
  3. Bezerra, M.A.; Santelli, R.E.; Oliveria, E.P.; Villar, L.S.; Escaleira, L.A. (2008) Talanta 76: 965-977. doi: 10.1016/j.talanta.2008.05.019
  4. Boparai, H.K.; Joseph, M.; O'Carroll, D.M. (2011) Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. J. Hazard. Mater. 186: 458-465. doi:10.1016/j.jhazmat.2010.11.029
  5. Cao, J.; Wu. Y.; Jin, Y.; Yılıhan, P.; Huang, W. (2014) Response surface methodology approach for optimization of the removal of chromium (VI) by NH2-MCM-41. J. Taiwan Inst. Chem. Eng. 45: 860-868. doi: 10.1016/j.jtice.2013.09.011
  6. Cojocaru, C.; Zakrzewska-Trznadel, G. (2007) Response surface modeling and optimization of copper removal from aqua solutions using polymer assisted ultrafiltration. J. Membr. Sci. 298: 56-70. doi: 10.1016/j.memsci.2007.04.001
  7. Dos-Anjos, V.E.; Rohwedder, J.R.; Cadore, S.; Abate, G.; Grassi, M.T. (2014) Montmorillonite and vermiculite as solid phases for the preconcentration of trace elements in natural waters: Adsorption and desorption studies of As, Ba, Cu, Cd, Co, Cr, Mn, Ni, Pb, Sr, V, and Zn. Appl. Clay. Sci. 99: 289-296. doi: 10.1016/j.clay.2014.07.013
  8. Fisher, R.V. (1961) Proposed Classification of Volcaniclastic Sediments and Rocks. Geol. Soc. Am. Bull. 72: 1409-1414. doi: 10.1130/0016-7606(1961)72[1409:PCOVSA]2.0.CO;2
  9. Grahek, Z.; Mačefat, M.R. (2005) Determination of radioactive strontium in seawater. Analy. Chim. Acta. 534(2): 271-279. doi: 10.1016/j.aca.2004.11.050
  10. Haghseresht, F.; Lu, G.Q. (1998) Adsorption characteristics of phenolic compounds onto coal-reject-derived adsorbents. Energy and Fuels 12:1100-1107. doi: 10.1021/ef9801165 Hong, H.J.; Ryu, J.; Park, I.S.; Ryu, T.; Chung, K.S.; Kim, B.G. (2016) Investigation of the strontium (Sr(II)) adsorption of an alginate microsphere as a low-cost adsorbent for removal and recovery from seawater. J. Environ. Manage. 165: 263-270. doi: 10.1016/j.jenvman.2015.09.040
  11. Houhounea, F.; Niboub. D.; Chegrouchea, S.; Menacera, S. (2016) Behaviour of modified hexadecyltrimethylammonium bromide bentonite toward uranium species. J. Environ. Chem. Eng. 4: 3459-3467. doi: 10.1016/j.jece.2016.07.018
  12. Kaynar, U.H.; Sabikoglu, I.; Kaynar, S.C.; Eral, M. (2015) Removal of thorium (IV) ions from aqueous solution by a novel nanoporous ZnO: Isotherms, kinetic and thermodynamic studies. J. Environ. Radioact. 150: 145-151. doi: 10.1016/j.jenvrad.2015.08.014
  13. Kunwar, P.S.; Shikha, G.; Arun, K.S.; Sarita, S. (2011) Optimizing adsorption of crystal violet dye from water by magnetic nanocomposite using response surface modeling approach. J. Hazard. Mater. 186: 1462-1473. doi: 10.1016/j.jhazmat.2010.12.032
  14. Landstetter, C.; Wallner, G. (2006) Determination of strontium-90 in deer bones by liquid scintillation spectrometry after separation on Sr-specific ion exchange columns. J. Environ. Radioac. 87: 315-324. doi: 10.1016/j.jenvrad.2005.12.008
  15. Lee, J.J.; Choi, J.; Park, J.W. (2002) Simultaneous sorption of lead and chlorbenzene by organobentonite. Chemosphere 49: 1309-1315. doi: 10.1016/S0045-6535(02)00531-3
  16. Liu, S.; Li, S.; Zhang, H.; Wu, L.; Sun, L.; Ma, J. (2016) Removal of uranium(VI) from aqueous solution using graphene oxide and its amine-functionalized composite. J. Radioanal. Nucl. Chem. 309: 607–614. doi:10.1007/s10967-015-4654-8
  17. Majdan, M.; Pikus. S.; Gajowiak, A.; Gładysz-Płaska, A.; Krzyżanowska, H.; Żuk, J.; Bujacka, M. (2010) Characterization of uranium(VI) sorption by organobentonite. App. Surf. Sci. 256-(17): 5416-5421. doi: 10.1016/j.apsusc.2009.12.123
  18. Maranescu, B.; Popa, P.; Lupa, L.; Maranescu, V.; Visa, A. (2017) Use of chitosan complex with aminophosphonic groups and cobalt for the removal of Sr2+ ions. Separation Science And Technology, doi: 10.1080/01496395.2017.1304961
  19. Myers, R.H.; Montgomery, D.C. (2011) Response surface methodology, 2nd ed. Wiley; New York.
  20. Prakash, O.; Talat, M.; Hasan, S.H.; Pandey, R.K. (2008) Factorial design for the optimization of enzymatic detection of cadmium in aqueous solution using immobilized urease from vegetable waste. Bioresour. Technol. 99: 7565-7572. doi: 10.1016/j.biortech.2008.02.008
  21. Richards, S.; Bouazza, A. (2010) Phenol adsorption in organo-modified basaltic clay and bentonite. App. Clay Sci. 37: 133-142. doi: 10.1016/j.clay.2006.11.006
  22. Rosales-Landeros, C.; Barrera-Díaz, C.E.; Bilyeu, B.; Guerrero. V.V.; Núñez, F.U. (2013) A review on Cr (VI) adsorption using inorganic materials. Am. J. Anal. Chem. 4: 8-16. doi: 10.4236/ajac.2013.47A002
  23. Ryu, C.H.; Yeo, S.D. (2010) Vapor phase adsorption of trichloroethane using organically modified montmorillonite. J. Ind. Eng. Chem. 377: 441-449. doi: 10.1016/j.jiec.2010.01.043
  24. Saitoh, T.; Shibayama, T. (2016) Removal and degradation of β-lactam antibiotics in water using didodecyldimethylammonium bromide-modified montmorillonite organoclay. J. Hazard. Mater. 317: 677-685 doi:10.1016/j.jhazmat.2016.06.003
  25. Shakur, H.R.; Rezaee Ebrahim Saraeea, Kh.; Abdib, M.R.; Azimic, G. (2016-a) Selective removal of uranium ions from contaminated waters using modified-X nanozeolite. Appl. Radia. Iso. 118: 43-55. doi:10.1016/j.apradiso.2016.08.022
  26. Shakur, H.R.; Rezaee Ebrahim Saraeea, Kh.; Abdi, M.R.; Azimic, G. (2016-b) A novel PAN/NaX/ZnO nanocomposite absorbent: synthesis, characterization, removal of uranium anionic species from contaminated water. J. Mater. Sci. 51: 9991-10004. doi: 10.1007/s10853-016-0227-7
  27. Shakur, H.R.; Rezaee Ebrahim Saraeea, Kh.; Abdib, M.R.; Azimic, G. (2016-c) Highly selective and effective removal of uranium from contaminated drinking water using a novel PAN/AgX/ZnO nanocomposite. Micr. Mes. Mater. 234 (2016) 257-266. doi: 10.1016/j.micromeso.2016.07.034
  28. Sharma. S.; Malik, A.; Satya, S. (2009) Application of response surface methodology (RSM) for optimization of nutrient supplementation for Cr (VI) removal by Aspergillus lentulus AML05. J. Hazard. Mater. 164: 1198-1204. doi: org/10.1016/j.jhazmat.2008.09.030
  29. Smičiklas, I.; Dimović, S.; Plećaš, P. (2007) Removal of Cs1+, Sr2+ and Co2+ from aqueous solutions by adsorption on natural clinoptilolite. Appl. Clay Sci. 35: 139-144. doi: 10.1016/j.clay.2006.08.004 Sprynskyy, M.; Kowalkowskia, T.; Tutu, H.; Cukrowskab, E.M.; Buszewski, B. (2015) The separation of uranium ions by natural and modified diatomite from aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects 465: 159-167. doi: 10.1016/j.colsurfa.2014.10.042
  30. Sprynskyy, M.; Kovalchuk, I.; Buszewski, B. (2010) The separation of uranium ions by natural and modified diatomite from aqueous solution. J. Hazard. Mater. 181: 700-707. doi: 10.1016/j.jhazmat.2010.05.069
  31. Uddin, M.K. (2017) A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chem. Eng. J. 308: 438-462. doi: 10.1016/j.cej.2016.09.029
  32. Xi, Y.; Frost, R.; He, H. (2007) Modification of the surfaces of Wyoming montmorillonite by the cationic surfactants alkyl trimethyl, dialkyl dimethyl, and trialkyl methylammonium bromides. J. Colloid. Interface. Sci. 305: 150-158. doi: 10.1016/j.jcis.2006.09.033
  33. Wu, P.; Dai, Y.; Longa, H.; Zhu, N.; Li, P.; Danga, Z. (2012) Characterization of organo-montmorillonites and comparison for Sr(II) removal: Equilibrium and kinetic studies, Chem. Eng. J. 191: 288-296. doi: 10.1016/j.cej.2012.03.017
  34. Zhang, L.; Zhang, L.; Wu, T.; Jing, X.; Li, R.; Liu, J.; Liu, Q. (2015) In situ growth of ZnO nanorod arrays on cotton cloth for the removal of uranium (VI). RSC. Adv. 5: 53433-53440. doi: 10.1039/C5RA08489J
  35. Aghadavoud, A.; Rezaee Ebrahim Saraeea, Kh.; Shakur,H.R.; Sayyari, R. (2016) Removal of uranium ions from synthetic wastewater using ZnO/Na-clinoptilolite nanocomposites. Radiochimica Acta 104: 809-819. doi: 10.1515/ract-2016-2586