Journals / Journal of International Environmental Application and Science / 2026 / Volume: 21 Issue: 2

Occurrence and Distribution of PAHs, BTEX and n-Alkanes in Surface Waters from Patos–Marinza Oilfield, Albania

Aurel Nuro(University of Tirana, Faculty of Natural Sciences)0000-0003-1875-2430
Bledar Kruja(Department of Chemistry, Faculty of Natural Sciences, University of Tirana, Albania)0009-0008-3518-4424
Elda Marku(Department of Chemistry, Faculty of Natural Sciences, University of Tirana, Albania)0000-0003-1199-8737
Pages
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Publication Date
2026-08-04
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The findings highlight the need for continued monitoring, seasonal sampling, surface/groundwater and sediment assessment, and further ecological risk evaluation in the Patos–Marinza oilfield region.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:This study investigated the occurrence and distribution of petroleum-related hydrocarbons in surface waters from the Patos–Marinza area, which is the most important oil-producing regions in Albania.
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Key Findings & Data:Surface water samples were collected in April 2026 from different water bodies (rivers, drainage channels, streams, etc), near Belin, Marinza and Zharrëz.
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Conclusion & Impact:The findings highlight the need for continued monitoring, seasonal sampling, surface/groundwater and sediment assessment, and further ecological risk evaluation in the Patos–Marinza oilfield region.
🔬Design:Research Article
📍Scope:2026 Verileri
⚙️Variables:Patos-Marinza area · Water analyze · PAH

Abstract

This study investigated the occurrence and distribution of petroleum-related hydrocarbons in surface waters from the Patos–Marinza area, which is the most important oil-producing regions in Albania. Surface water samples were collected in April 2026 from different water bodies (rivers, drainage channels, streams, etc), near Belin, Marinza and Zharrëz. Water samples were analysed for polycyclic aromatic hydrocarbons (PAHs), BTEX compounds (benzene, toluene, ethylbenzene, o-, m- and p-xylenes) and n-alkanes (C10-C26) using gas chromatography with flame ionization detection (GC/FID). The aim was to evaluate the level of hydrocarbon contamination in environmental matrices (water samples) and to identify the most impacted sites. In surface waters, total PAH concentrations ranged from 0.289 to 1.806 mg/L, total BTEX from 0.089 to 3.344 mg/L, and total n-alkanes from 0.222 to 1.557 mg/L. The higher contamination in water samples was found in Marinza, mainly due to elevated BTEX concentrations, especially benzene, toluene and ethylbenzene. The presence of BTEX, PAHs and n-alkanes in surface waters suggests mixed hydrocarbon contamination, likely associated with oil extraction, transport, runoff, atmospheric deposition and weathered petroleum residues. Surface waters were affected by recent inputs of volatile aromatic hydrocarbons because of hydrocarbon lower solubility in water. The findings highlight the need for continued monitoring, seasonal sampling, surface/groundwater and sediment assessment, and further ecological risk evaluation in the Patos–Marinza oilfield region.

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Cite This Article

Nuro, A., Kruja, B., Marku, E., Tushe, K. (2026). Occurrence and Distribution of PAHs, BTEX and n-Alkanes in Surface Waters from Patos–Marinza Oilfield, Albania. Journal of International Environmental Application and Science, Volume: 21 Issue: 2. https://ajindex.com/articles/1112203

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References (17)

  1. Akinnusotu A., Ukpebor J.E. and Okieimen F.E. (2023) Source, distribution, and risk assessment of polycyclic aromatic hydrocarbons in sediment and fish samples from River Owan, Edo State, Nigeria. Front. Toxicol. 5:1250943. https://doi.org/10.3389/ftox.2023.1250943
  2. Akkanen J, Tuikka A, Kukkonen JVK (2005) Comparative sorption and desorption of benzo[a]pyrene and 3,4,3′,4′-tetrachlorobiphenyl in natural lake water containing dissolved organic matter. Environ Sci Technol 39(19):7529–7534. doi: 10.1021/es050835f.
  3. Almuhtaseb, R.M., Bhagyaraj, S. & Krupa, I. (2024) A concise review on BTEX remediation from aqueous solutions by adsorption. Emergent mater. 7, 695–719 https://doi.org/10.1007/s42247-024-00640-1
  4. Arias-Navarro C, Vidojević D, Zdruli P, Yunta Mezquita F, Jones A, Wojda P. (2025) Addressing point source soil pollution in the Western Balkans: Challenges and opportunities for EU integration. Integr Environ Assess Manag. Aug 5:vjaf104. doi: 10.1093/inteam/vjaf104. Epub ahead of print. PMID: 40794556. https://pubmed.ncbi.nlm.nih.gov/40794556/
  5. Asejeje GI, Ipeaiyeda AR, Onianwa PC. (2024) Occurrence of BTEX from petroleum hydrocarbons in surface water, sediment, and biota from Ubeji Creek of Delta State, Nigeria. Environ Sci Pollut Res Int. 2021 Mar;28(12):15361-15379. doi: 10.1007/s11356-020-11196-y. PMID: 33231851.
  6. Bąk, J., Bielski, A., Meland, S., Pala, K., & Wassilkowska, A. (2025). An Analysis of BTEX Occurrence in Stored Rainwater and Rainwater Runoff in Urban Environment. Sustainability, 17(4), 1607. https://doi.org/10.3390/su17041607
  7. Berríos-Rolón, P. J., Cotto, M. C., & Márquez, F. (2025). Polycyclic Aromatic Hydrocarbons (PAHs) in Freshwater Systems: A Comprehensive Review of Sources, Distribution, and Ecotoxicological Impacts. Toxics, 13(4), 321. https://doi.org/10.3390/toxics13040321
  8. Borshi X., Nuro N., Macchiarelli G., Palmerini MG. (2016) Determination of PAH and BTEX in water samples of Adriatic Sea” International Journal of Current Microbiology and Applied Sciences Vol. 5/11, pp. 877-884
  9. Directive 2008/105/EC of The European Parliament and of the Council on environmental quality standards in the field of water policy, amending and subsequently repealing Council Directives 82/176/EEC, 83/513/EEC, 84/156/EEC, 84/491/EEC, 86/280/EEC and amending Directive 2000/60/EC of the European Parliament and of the Council
  10. Halo E., Tahiraj J., Murtaj B., Kane S., Marku E., Nuro A. (2023) Analyzes of hydrocarbons (PAH, alkanes and BTEX) in marine water of Vlora’s port” Zastita Materijala 64 (2) 153- 160, https://doi.org/10.5937/zasmat2302153H
  11. Hoxha, L., Beqiraj, I., Prifti, E., & Shehu, A. (2018). Monitoring Pollution of Underground Water Caused by the Oil Industry, Area Patos – Marinz. Anglisticum. Journal of the Association-Institute for English Language and American Studies, 5(3), 84–92 https://izvor.net.mk/article.php?id=55426
  12. ISO 5667-3:2018, Water quality — Sampling — Part 3: Preservation and handling of water samples. https://www.iso.org/obp/ui/#iso:std:iso:5667:-3:ed-5:v1:en
  13. Li H., Gu X., Song J., Hui K., Chen G., Tan W., Wang H., Jiang Y., Yuan Y., (2024) Effects of soil-groundwater environmental factors on BTEX transport and transformation: A review, Journal of Environmental Chemical Engineering, Vol. 12/5, 113697, ISSN 2213-3437, https://doi.org/10.1016/j.jece.2024.113697.
  14. National Agency of Natural Resources. (2019). Hydrocarbon resources of Albania. AKBN.
  15. Nuro A., Marku E., Murtaj B. (2014) Determınatıon of PAH and BTEX Levels in Water Samples usıng GC/FID Technıque. Case Study Patoku Lagoon, International Journal of Ecosystems and Ecology Science (IJEES) 4/2, pp. 195-200, https://www.researchgate.net/profile/Aurel-Nuro/publication/265787433
  16. Stogiannidis E, Laane R (2015) Source characterization of polycyclic aromatic hydrocarbons by using their molecular indices: an overview of possibilities. Rev Environ Contam Toxicol 234:49–133. doi:10.1007/978-3-319-10638-0_2. https://www.wfd.org/sites/default/files/2021-12/Mapping-of-Environmental-issues-along-the-Albanian-coastline.pdf
  17. Westminster Foundation for Democracy. (2021) Mapping of environmental issues along the Albanian coastline. WFD. https://www.wfd.org/sites/default/files/2021-12/Mapping-of-Environmental-issues-along-the-Albanian-coastline.pdf