Journals / Celal Bayar Üniversitesi Fen Bilimleri Dergisi / 2017 / Cilt: 13 - Sayı: 4

The Investigation of Kinetic Characterization of Sea Salt via Thermoluminescence Method

Pages
845–849
Publication Date
2017-12-29
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The b = 1.5, E = 0.88 eV and s = 1.7x1011 s-1 values were calculated using the peak shape method.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The calculation of the kinetic parameters of a thermoluminescence material (kinetic order (b), activation energy (E) and frequency factor (s)) by using the thermoluminescence (TL) method is extremely important in determining the kinetic characterization of the materials.
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Key Findings & Data:It is a crystal well known for its luminescent properties, with a simple cubic structure and its band gap is rather large (~ 8.5 eV).
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Conclusion & Impact:The b = 1.5, E = 0.88 eV and s = 1.7x1011 s-1 values were calculated using the peak shape method.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:NaCl · Thermoluminescence · Kinetic Parameters

Abstract

The calculation of the kinetic parameters of a thermoluminescence material (kinetic order (b), activation energy (E) and frequency factor (s)) by using the thermoluminescence (TL) method is extremely important in determining the kinetic characterization of the materials. Sodium Chloride (NaCl) is an inorganic salt. It is a crystal well known for its luminescent properties, with a simple cubic structure and its band gap is rather large (~ 8.5 eV). In this work, it was reported the TL response of the material in the range of 50– 400 oC and calculated kinetic parameters of sea salt. Two glow peaks were observed at 100 oC and 235 oC in the TL glow curve of sea salt with a heating rate 2 oC/s after X-ray irradiation. The Tm-Tstop method was used to determine the overlapping peaks under the main peak at 100 oC. With the computerized glow curve deconvolution (CGCD) method, the peak analysis was performed. In addition, kinetic parameters were calculated using various heating rates and peak shape. The b = 1.5, E = 0.88 eV and s = 1.7x1011 s-1 values were calculated using the peak shape method.

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Cite This Article

Çetin, A., Türemiş, M., Keskin, İ. Ç., Kati, M. İ., Taştekin, B., Çipiloğlu, M. A., Kibar, R. (2017). The Investigation of Kinetic Characterization of Sea Salt via Thermoluminescence Method. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, Cilt: 13 - Sayı: 4, 845–849. https://ajindex.com/articles/111213

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References (13)

  1. Katı, M.İ.; Türemis, M.; Keskin, İ.Ç.; Tastekin, B.; Kibar, R.; Çetin, A.; Can, N. Luminescence behaviour of beryl (aquama-rine variety) from Turkey. Journal of Luminescence, 2012;132,2599-2602
  2. Akın, A.; Ekdal, E.; Tuncer Arslanlar, Y.; Ayvacıklı, M.; Karalı, T.; Can, N. Thermally Stimulated Luminescence Glow Curve Structure of β-Irradiated CaB4O7:Dy. Luminescence, 2015; 30,830-834
  3. Katı, M.İ.; Sam, G.;Keskin, İ.Ç.;Türemiş, M.; Çetin, A.;Kibar, R. Pembe Spodümenin Termolüminesans Özelliklerinin İncelenmesi ve Kinetik Parametrelerinin Hesaplanması. El-Cezeri Journal of Science and Engineering, 2016;3,258-271
  4. Keskin, İ.Ç.; Türemiş, M.; Katı, M.İ.; Kibar, R.; Şirin, K.; Çipiloğlu, M.A.; Kuş, M.; Büyükçelebi,S.;Çetin, A. Theradio-luminescence and optical behaviour of nanocomposites with CdSeS quantum dot. Journal of Luminescence, 2017;185,48-54
  5. Katı, M.İ.; Kadiroğulları, K.; Türemiş, M.; Keskin, İ.Ç.; Çetin, A.; Kibar, R. The Investigation of Thermoluminescence Prop-erties of Tooth Enamel. El-Cezeri Journal of Science and Engi-neering, 2016;3,297-303
  6. Murthy,D.E.K.V.R.; Pallavi, S.P.; Rahul, G.; Patel, Y.S.; SaiPra-sad,A.S. Thermoluminescence dosimetric characteristics of be-ta irradiated salt. Radiation Protection Dosimetry, 2006;119,350-352
  7. Ortega, X.; Dies, X. Study of TL response in heavily irradiated rock salt. Radiation Protection Dosimetry, 1193;47,575-579
  8. Purohit, R.U.; Joshi, T.R. Development of NaCl:Tb(T) as gam-ma and beta radiation dosimetry material, Journal of Lumines-cence, 2000; 2313(99),87-89
  9. Randall, J.T.; Wilkins, M.H.F. Phosphorescence and Electron Traps. I. The Study of Trap Distributions, Proceedings of the Royal Socşety of London. Series A Mathematical and Physical Sciences, 1945;184,365-389
  10. Rey, L. Thermoluminescence of ultra-high dilutions of lithium chloride and sodium chloride. Physica A: Statistical Mechanics and its Applications, 2003;323,67-74
  11. Zych, A.; De Mello Donegá C.; Meijerink, A.; Luminescent salt. Journal of Luminescence, 2009;129,1535-1537
  12. Jose, M.T.; Anishia, S.R.; Annalakshmi, O.; Ramasamy, V. Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate. Radiation Measure-ments, 2011; 46(10), 1026–1032 13. McKeever SWS. On the analysis of complex thermolumines-cence. Glow-curves: resolution into individual peaks. Physica Status Solidi A, 1980;62:331–340
  13. Furetta, C. Handbook of Thermoluminescence, World Science, Singapore, 2003