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Journals / Trakya University Journal of Natural Sciences / 2017 / Volume: 18 Issue: 2

Biosorption of Methylene Blue by Modified Cystoseira barbata (Stackhouse) C. Agardh

METİLEN MAVİSİNİN MODİFİYE EDİLMİŞ Cystoseira barbata (STACKHOUSE) C. AGARDH KULLANILARAK BİYOSORPSİYONU

Yeliz Özüdoğru(ÇANAKKALE ONSEKİZ MART ÜNİVERSİTESİ, DENİZ BİLİMLERİ VE TEKNOLOJİSİ FAKÜLTESİ)
Melek Merdivan(DOKUZ EYLÜL ÜNİVERSİTESİ, FEN FAKÜLTESİ, KİMYA BÖLÜMÜ)
Pages
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Publication Date
2017-06-01
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The results showed that the system reached to equilibrium in the first 50min and pH had no significant effect on adsorption capacity.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, methylene blue (MB) dye in aqueous solution was tried to be removed by using modified Cystoseira barbata (with 0.1M HNO 3 and 1M HNO 3 ).
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Key Findings & Data:The results showed that the system reached to equilibrium in the first 50min and pH had no significant effect on adsorption capacity.
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Conclusion & Impact:The changes in the algae surface caused by MB and the groups on the algae surface that the dye attached were determined in SEM and FTIR analysis.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Coloring agent · algae · biosorption

Abstract

In this study, methylene blue (MB) dye in aqueous solution was tried to be removed by using modified Cystoseira barbata (with 0.1M HNO 3 and 1M HNO 3 ). The effects of pH, contact time and different MB concentrations on adsorption were investigated. The results showed that the system reached to equilibrium in the first 50min and pH had no significant effect on adsorption capacity. In the isotherm studies, the Freundlich isotherm model was found to be more suitable and the q max value was higher in the 0,1M HNO 3 group (100.6mg/g). The changes in the algae surface caused by MB and the groups on the algae surface that the dye attached were determined in SEM and FTIR analysis.

Özet

Bu çalışmada, sulu çözeltide bulunan metilen mavisi (MM) boyar maddesinin modifiye edilmiş (0,1M HNO 3 ve 1M HNO 3 ile) Cystoseira barbata kullanılarak giderilmesine çalışılmıştır. Adsorpsiyona, pH’ın, temas süresinin, farklı derişimlerde bulunan MM çözeltisinin etkileri incelenmiştir. Çalışma sonucunda, ilk 50dk. içerisinde sistemin dengeye geldiği ve adsorpsiyon kapasitesinin pH değişiminden pek etkilenmediği gözlemlenmiştir. Yapılan izoterm çalışmalarında ise, Freundlich izoterm modeline daha çok uyduğu belirlenmiş ve q max değeri 0,1M HNO 3 grubunda daha yüksek (100,6mg/g) bulunmuştur. Yapılan SEM ve FTIR analizlerinde ise, MM boyar maddesinin alg yüzeyinde meydana getirdiği değişikler ve alg yüzeyinde hangi gruplara tutunduğu belirlenmiştir.

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Cite This Article

Özüdoğru, Y., Merdivan, M. (2017). Biosorption of Methylene Blue by Modified Cystoseira barbata (Stackhouse) C. Agardh. Trakya University Journal of Natural Sciences, Volume: 18 Issue: 2. https://doi.org/10.23902/trkjnat.300344

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References (28)

  1. Abd-El-Kareem, M. & Taha, H. 2013. Decolorization of malachite green and methylene blue by two microalgal species. International Journal of Chemical and Environmental Engineering, 3(5): 297-302.
  2. Dahri, M.K., Rahimi Kooh, M.R. & Lim, L.B.L. 2015. Application of Casuarina equisetifolia needle for the removal of methylene blue and malachite green dyes from aqueous solution. Alexandria Engineering Journal, 54(4): 1253–1263.
  3. Daneshvar, E., Kousha, M., Salar Sohrabi, M., Khataee, A. & Converti, A. 2012. Biosorption of three acid dyes by the brown macroalga Stoechospermum marginatum: Isotherm, kinetic and thermodynamic studies. Chemical Engineering Journal, (195-196): 297-306.
  4. Daneshvar, E., Vazirzadeh, A., Niazi, A., Sillanpää, M. & Bhatnagar, A. 2017. A comparative study of methylene blue biosorption using different modified brown, red and green macroalgae – Effect of pretreatment. Chemical Engineering Journal, 307(1): 435-446.
  5. Doğar, Ç., Gürses, A., Açıkyıldız, M. & Özkan, E. 2010. Thermodynamics and kinetic studies of biosorption of a basic dye from aqueous solution using gren algae Ulothrix sp. Collids and Surface B: Biointerfaces, 76: 279-285.
  6. El Jamal, M.M. & Ncibi, M.C. 2012. Biosorption of methylene blue by Chaetophora elegans algae: kinetics, equilibrium and thermodinamik studies. Acta Chimica Slovenica, 59: 24-31.
  7. El Sikaily, A., Khaled, A., El Nemr, A. & Abdelwahab, O. 2006. Removal of methylene blue from aqueous solution by marine alga Ulva lactuca. Chemistry and Ecology, 22(2): 149-157.
  8. Freundlich H. 1906. Over the adsorption in solution. The Journal of Physical Chemistry, 57: 385.
  9. İmecik, Z., Dığrak, M. & Halipçi, H.N. 2014. Metilen mavisinin sulu ortamdan Platanus orientalis L. biyoması kullanılarak giderimi. Karaelmas Science and Engineering Journal, 4(2): 64-69.
  10. Khataee, A.R., Vafaei, F. & Jannatkhah, M. 2013. Biosorption of three textile dyes from contaminated water by filamentous gren algal Spirogyra sp.: Kinetic, isotherm and thermodynamic studies. otherm and thermodynamic studies. International Biodeterioration & Biodegradation, 83: 33-40.
  11. Kushwaha, A.K., Gupta, N. & Chattopadhyaya, M.C. 2014. Removal of cationic methylene blue and malachite gren dyes from aqueous solution by waste materials of Daucus carota. Journal of Saudi Chemical Society, 18: 200-207.
  12. Langmuir, I. 1918. The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of American Chemical Society, 40: 1361–1403.
  13. Lesmana, S.O., Febriana, N., Soetaredjo, F.E., Sunarso, J. & Ismadji, S. 2009. Studies on potential applications of biomass for the separation of heavy metals from water and wastewater, Biochemical Engineering Journal, 44(1): 19–41.
  14. Lim, L.B.L., Priyantha, N., Ing, C.H., Dahri, M.K., Tennakoon, D.T.B., Zehra, T. & Sukleung, M. 2015. Artocarpus odoratissumus skin as potential low-cost biosorbent for the removal of methylene blue and methyl violet 2B. Desalination and Water Treatment, 53(4): 964–975.
  15. Marungrueng, K. & Pavasant, P. 2007. High performance biosorbent (Caulerpa lentillifera) for basic dye removal. Biorescource Technology, 98: 1567-1572.
  16. Me´tivier-Pignon, H., Faur-Brasquet, C. & Le Cloirec, P. 2003. Adsorption of dyes onto activated carbon cloths: approach of adsorption mechanisms and coupling of ACC with ultrafiltration to treat coloured wastewaters. Separation and Purification Technology, 31: 3-11.
  17. Mikati, F. & El Jamal, M. 2013. Biosorption of methylene blue on chemically modified Chaetophora elegans algae by carboxylic acids. Journal of Scientific & Industrial Research, 72: 428-434.
  18. Mikati, F.M., Saade, N.A, Slim, K.A. & El Jamal, M.M. 2013. Biosorption of methylene blue on chemically modified Chaetophora elegans alga by HCl and citric acid. Journal of Chemical Technology and Metallurgy, 48(1): 61-71.
  19. Ncibi, M.C., Mahjoub, B. & Mongi, S. 2007. Kinetic and equilibrium studies of methylene blue biosorption by Posidonia oceanica (L.) fibres. Journal of Hazardous Materials, 139(2): 280-285.
  20. Ncibi, M.C., Hamissa, A.M.B., Fathallah, A., Kortas, M. H., Baklouti, T., Mahjoub, B. & Seffen, M. 2009. Biosorptive uptake of methylene blue using Mediterranean green alga Enteromorpha spp. Journal of Hazardous Materials, 170(2–3): 1050-1055. 21. Ozudogru, Y., Merdivan, M. & Goksan, T. 2017. Removal of methylene blue from aqueous solutions by Brown alga Cystoseira barbata. Desalination and Water Treatment, 1-6.
  21. Padmesh, T.V.N., Vijayaraghavan, K., Sekaran, G. & Velan, M. 2005. Batch and column studies on biosorption of acid dyes on fresh water macro alga Azolla Filiculoides. Journal of Hazardous Materials B, 125: 121–129.
  22. Rafatullah, M., Sulaiman, O., Hashim, R. & Ahmad, A. 2010. Adsorption of methlene blue on low-cost adsorbents: A review. Journal of Hazardous Materials, 177: 70-80.
  23. Rubin, E., Rodriguez, P., Herrero, R., Cremades, J., Barbara, J. & Sastre de Vicente, M.E. 2005. Removal of Methylene Blue from aqueous solutions using as biosorbent Sargassum muticum: an invasive macroalga in Europe. Journal of Chemical Technology and Biotechnology, 80: 291-298.
  24. Rubin, E., Rodriguez, P., Herrero, R. & Sastre de Vicente, M.E. 2010. Adsorption of Methylene Blue on Chemically Modified Algal Biomass: Equilibrium, Dynamic, and Surface Data. Journal of Chemical Engineering Data, 55: 5707-5714.
  25. Tsai, W., Chen, H. & Kuo, K. 2011. Surface characterization of dead microalgae-based biomass using methylene blue adsorption. Surface and Interface Analysis, 43(6): 959–963.
  26. Vijayaraghavan, J., Bhagavathi Pushpa, T., Sardhar Basha, S.J., Vijayaraghavan, K. & Jegan, J. 2015. Evaluation of red marine alga Kappaphycus alvarezii as biosorbents for methylene blue: isotherm, kinetic, and mechanism studies, Separation Science and Technology, 50: 1120–1126.
  27. Vijayaraghavan, J., Bhagavathi Pushpa, T., Sardhar Basha, S.J & Jegan, J. 2016. Isotherm, kinetics and mechanistic studies of methylene blue biosorption onto red seaweed Gracilaria corticata. Desalination and Water Treatment, 57(29): 13540- 13548.
  28. Zazouli, M.A. & Moradi, E. 2015. Adsorption acid red 18 dye using Sargassum glaucescens biomass from aqueous solutions, Iranian Journal of Health Sciences, 3(2): 7-13.