Journals / Environmental Research and Technology / 2023 / Cilt: 6 Sayı: 4

The effect of physicochemical properties on paracetamol photodegradation in cuboid bubble column

Pages
347–358
Publication Date
2023-12-31
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The experimental results show that the maximum %COD removal was 78% at pH=7, 1L/min, and 0mg/L of NaCl.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Paracetamol is one of the most anthropogenic micropollutants, and their removal from the environment often requires a specialized method of remediation.
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Key Findings & Data:The experiments were carried out in a semi-batch rectangular bubble column with dimensions of 1500 mm height, 30 mm depth, and 200 mm width under UV light.
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Conclusion & Impact:The experimental results show that the maximum %COD removal was 78% at pH=7, 1L/min, and 0mg/L of NaCl.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Pharmaceuticals · photocatalyst · response surface modelin

Abstract

Paracetamol is one of the most anthropogenic micropollutants, and their removal from the environment often requires a specialized method of remediation. In this study, a photocatalyst technique aided with air bubbles was used to degrade the pharmaceutical pollutant paracetamol (PCT) from the water via the COD test and HPLC analysis under different operating conditions. The experiments were carried out in a semi-batch rectangular bubble column with dimensions of 1500 mm height, 30 mm depth, and 200 mm width under UV light. Titanium oxide (TiO2) was used as a source of catalyst. The effect of operating conditions of pH (3-10), air flow rate (0-2) L/min, salinity of solution represented by NaCl concentration (0-1000) mg/L, and 240 min irradiation time on the paracetamol removal were studied. The Box–Behnken design was adopted to study the individual effects of pH (A), air flow rate (B), and salinity (C) and their interactive effects. From the experimental and regression data, a second-order polynomial regression model is predicted, and the variance analysis of the regressions shows that the linear terms (A and B), and all quadratic terms (A, B, and C) have significant effects on the removal percentage of COD. According to numerical optimization, the greatest %COD removal is 76.7 in the process conditions of 5.3 pH, 1L/min, and 269 mg/L of NaCl. The experimental results show that the maximum %COD removal was 78% at pH=7, 1L/min, and 0mg/L of NaCl. HPLC analysis shows 91.2% of paracetamol degradation.

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Cite This Article

KHALİL, A. H., ALWASİTİ, A., ABDULRZAAK, J. (2023). The effect of physicochemical properties on paracetamol photodegradation in cuboid bubble column. Environmental Research and Technology, Cilt: 6 Sayı: 4, 347–358. https://ajindex.com/articles/1020925

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References (1)

  1. C. Gadipelly, A. Pérez-González, G. D. Yadav, I. Ortiz, R. Ibáñez, V. K. Rathod, and K. V. Marathe, “Pharmaceutical ındustry wastewater: Review of the technologies for water treatment and reuse,” Industrial & Engineering Chemistry Research, Vol. 53(29), pp. 11571-11592, 2014. [CrossRef] A. R. Ribeiro, O. C. Nunes, M. F. R. Pereira, and A. M. T. Silva, “An overview of the advanced oxidation processes applied for the treatment of water pollutants defined in the recently launched directive 2013/39/EU,” Environmental International, Vol. 75, pp. 33-51, 2015. [CrossRef] T. Heberer, “Tracking persistent pharmaceutical residues from municipal sewage to drinking water,” Journal of Hydrology, Vol. 266(3–4), pp. 175–189, 2002. [CrossRef] C. Tixier, H. P. Singer, S. Oellers, and S. R. Müller, “Occurrence and fate of carbamazepine, clofibric acid, diclofenac, ıbuprofen, ketoprofen, and naproxen in surface waters,” Environmental Science & Technology, Vol. 37(6), pp. 1061–1068, 2003. [CrossRef] K. Fent, A. A. Weston, and D. Caminada, “Ecotoxicology of human pharmaceuticals,” Aquatic Toxicology, Vol. 76(2), pp. 122–159, 2006. [CrossRef] C. Miege, J. M. Choubert, L. Ribeiro, M. Eusebe, and M. Coquery, “Fate of pharmaceuticals and personal care products in wastewater treatment plants—conception of a database and first results,” Environmental Pollution, Vol. 157(5), pp. 1721–1726, 2008. [CrossRef] K. Kümmerer, “The presence of pharmaceuticals in the environment due to human use-present knowledge and future challenges,” Journal of Environmental Management, Vol. 90(8), pp. 2354–2366, 2009. [CrossRef] S. Mompelat, B. Le Bot, and O. Thomas, “Occurrence and fate of pharmaceutical products and by-products, from resource to drinking water,” Environmental International, Vol. 35(5), pp. 803–814, 2009. [CrossRef] I. M. Sebastine, and R. J. Wakeman, “Consumption and environmental hazards of pharmaceutical substances in the UK,” Process Safety and Environmental Protection, Vol. 81(B4), pp. 229-235, 2003. [CrossRef] L. Yang, L. E. Yu, and M. B. Ray, “Degradation of paracetamol in aqueous solutions by TiO2 photocatalysis,” Water Research, Vol. 42(13), pp. 3480-3488, 2008. [CrossRef] B. C. Lourenção, R. A. Medeiros, R. C. Rocha-Filho, L. H. Mazo, and O. Fatibello-Filho, “Simultaneous voltammetric determination of paracetamol and caffeine in pharmaceutical formulations using a boron-doped diamond electrode,” Talanta, Vol. 78(3), pp. 748–752, 2009. [CrossRef] M. Solé, J. P. Shaw, P. E. Frick