Entropic competition between knots and slip-links

Abstract

Using canonical Monte Carlo simulations, we introduce a new numerical procedure for comparing the entropie exponents of polymers with different constraints and/or topologies. Setting up competitions between polymer segments which can exchange monomers according to their free energies, we obtain the universal exponents of partition functions, independently of any knowledge of the non-universal part. The method is successfully tested for closed polymer loops decorated with sliding rings. We also investigate the entropie exponents of loops with a fixed knot type, in which case we are limited by strong finite-size effects.